Wis. Admin. Code Department of Natural Resources NR 140.10

Current through October 28, 2024
Section NR 140.10 - Public health related groundwater standards

The groundwater quality standards for substances of public health concern are listed in Table 1.

Note: For all substances that have carcinogenic, mutagenic or teratogenic properties or interactive effects, the preventive action limit is 10% of the enforcement standard. The preventive action limit is 20% of the enforcement standard for all other substances that are of public health concern. Enforcement standards and preventive action limits for additional substances will be added to Table I as recommendations are developed pursuant to ss. 160.07, 160.13 and 160.15, Stats.

Table 1

Public Health Groundwater Quality Standards

Substance1

Enforcement Standard (micrograms per liter - except as noted)

Preventive Action Limit (micrograms per liter - except as noted)

Acetochlor

7

0.7

Acetochlor ethane sulfonic acid + oxanilic acid (Acetochlor - ESA + OXA)

230

46

Acetone

9 milligrams/liter (mg/1)

1.8 mg/1

Alachlor

2

0.2

Alachlor ethane sulfonic acid

20

4

(Alachlor - ESA)

Aldicarb

10

2

Aluminum

200

40

Ammonia (as N)

9.7 mg/l

0.97 mg/l

Anthracene

3000

600

Antimony

6

1.2

Arsenic

10

1

Asbestos

7 million fibers per liter (MFL)

0.7 MFL

Atrazine, total chlorinated residues

32

0.32

Bacteria, E. coli

0

0

Barium

2 mg/l

0.4 mg/l

Bentazon

300

60

Benzene

5

0.5

Benzo(b)fluoranthene

0.2

0.02

Benzo(a)pyrene

0.2

0.02

Beryllium

4

0.4

Boron

1000

200

Bromodichloromethane

0.6

0.06

Bromoform

4.4

0.44

Bromomethane

10

1

Butylate

400

80

Cadmium

5

0.5

Carbaryl

40

4

Carbofuran

40

8

Carbon disulfide

1000

200

Carbon tetrachloride

5

0.5

Chloramben

150

30

Chlordane

2

0.2

Chlorodifluoromethane

7 mg/l

0.7 mg/l

Chloroethane

400

80

Chloroform

6

0.6

Chlorpyrifos

2

0.4

Chloromethane

30

3

Chromium (total)

100

10

Chrysene

0.2

0.02

Cobalt

40

8

Copper

1300

130

Cyanazine

1

0.1

Cyanide, free3

200

40

Dacthal

70

14

1,2-Dibromoethane (EDB)

0.05

0.005

Dibromochloromethane

60

6

1,2-Dibromo-3-chloropropane (DBCP)

0.2

0.02

Dibutyl phthalate

1000

100

Dicamba

300

60

1,2-Dichlorobenzene

600

60

1,3-Dichlorobenzene

600

120

1,4-Dichlorobenzene

75

15

Dichlorodifluoromethane

1000

200

1,1-Dichloroethane

850

85

1,2-Dichloroethane

5

0.5

1,1-Dichloroethylene

7

0.7

1,2-Dichloroethylene (cis)

70

7

1,2-Dichloroethylene (trans)

100

20

2,4-Dichlorophenoxyacetic Acid (2,4-D)

70

7

1,2-Dichloropropane

5

0.5

1,3-Dichloropropene (cis/trans)

0.4

0.04

Di (2-ethylhexyl) phthalate

6

0.6

Dimethenamid/Dimethenamid-P

50

5

Dimethoate

2

0.4

2,4-Dinitrotoluene

0.05

0.005

2,6-Dinitrotoluene

0.05

0.005

Dinitrotoluene, Total Residues4

0.05

0.005

Dinoseb

7

1.4

1,4-Dioxane

3

0.3

Dioxin (2, 3, 7, 8-TCDD)

0.00003

0.000003

Endrin

2

0.4

EPTC

250

50

Ethylbenzene

700

140

Ethyl ether

1000

100

Ethylene glycol

14 mg/l

2.8 mg/l

Fluoranthene

400

80

Fluorene

400

80

Fluoride

4 mg/l

0.8 mg/l

Fluorotrichloromethane

3490

698

Formaldehyde

1000

100

Heptachlor

0.4

0.04

Heptachlor epoxide

0.2

0.02

Hexachlorobenzene

1

0.1

N-Hexane

600

120

Hydrogen sulfide

30

6

Lead

15

1.5

Lindane

0.2

0.02

Manganese

300

60

Mercury

2

0.2

Methanol

5000

1000

Methoxychlor

40

4

Methylene chloride

5

0.5

Methyl ethyl ketone (MEK)

4 mg/l

0.8 mg/l

Methyl isobutyl ketone (MIBK)

500

50

Methyl tert-butyl ether (MTBE)

60

12

Metolachlor/s-Metolachlor

100

10

Metolachlor ethane sulfonic acid + oxanilic acid (Metolachlor - ESA + OXA)

1.3 mg/l

0.26 mg/l

Metribuzin

70

14

Molybdenum

40

8

Monochlorobenzene

100

20

Naphthalene

100

10

Nickel

100

20

Nitrate (as N)

10 mg/l

2 mg/l

Nitrate + Nitrite (as N)

10 mg/l

2 mg/l

Nitrite (as N)

1 mg/1

0.2 mg/l

N-Nitrosodiphenylamine

7

0.7

Pentachlorophenol (PCP)

1

0.1

Perchlorate

1

0.l

Phenol

2 mg/l

0.4 mg/l

Picloram

500

100

Polychlorinated biphenyls (PCBs)

0.03

0.003

Prometon

100

20

Propazine

10

2

Pyrene

250

50

Pyridine

10

2

Selenium

50

10

Silver

50

10

Simazine

4

0.4

Styrene

100

10

Tertiary Butyl Alcohol (TBA)

12

1.2

1,1,1,2-Tetrachloroethane

70

7

1,1,2,2-Tetrachloroethane

0.2

0.02

Tetrachloroethylene

5

0.5

Tetrahydrofuran

50

10

Thallium

2

0.4

Toluene

800

160

Toxaphene

3

0.3

1,2,4-Trichlorobenzene

70

14

1,1,1-Trichloroethane

200

40

1,1,2-Trichloroethane

5

0.5

Trichloroethylene (TCE)

5

0.5

2,4,5-Trichlorophenoxy-propionic acid (2,4,5-TP)

50

5

1,2,3-Trichloropropane

60

12

Trifluralin

7.5

0.75

Trimethylbenzenes( 1,2,4- and 1,3,5- combined)

480

96

Vanadium

30

6

Vinyl chloride

0.2

0.02

Xylene5

2 mg/l

0.4 mg/l

1 Appendix I contains Chemical Abstract Service (CAS) registry numbers, common synonyms and trade names for most substances listed in Table 1.

2 Total chlorinated atrazine residues includes parent compound and the following metabolites of health concern: 2-chloro-4-amino-6-isopropylamino-s-triazine (formerly deethylatrazine), 2-chloro-4-amino-6-ethylamino-s-triazine (formerly deisopropylatrazine) and 2-chloro-4,6-diamino-s-triazine (formerly diaminoa-trazine).

3 "Cyanide, free" refers to the simple cyanides (HCN, CN-) and /or readily dissociable metal-cyanide complexes. Free cyanide is regulatorily equivalent to cyanide quantified by approved analytical methods for "amenable cyanide" or "available cyanide".

4 Dinitrotoluene, Total Residues includes the dinitrotoluene (DNT) isomers: 2,3-DNT, 2,4-DNT, 2,5-DNT, 2,6-DNT, 3,4-DNT and 3,5-DNT.

5 Xylene includes meta-, ortho-, and para-xylene combined.

Note: Consistent with the Department of Health Services' recommendation for the NR 140 ammonia standard, the department will use total ammonia, which is the sum of ionized ammonia and un-ionized ammonia in groundwater, in applying groundwater ammonia standards.

Wis. Admin. Code Department of Natural Resources NR 140.10

Cr. Register, September, 1985, No. 357, eff. 10-1-85; am. table 1, Register, October, 1988, No. 394, eff. 11-1-88; am. table 1, Register, September, 1990, No. 417, eff. 10-1-90; am. Register, January, 1992, No. 433, eff. 2-1-92; am. Table 1, Register, March, 1994, No. 459, eff. 4-1-94; am. Table 1, Register, August, 1995, No. 476, eff. 9-1-95; am. Table 1, Register, December, 1998, No. 516, eff. 1-1-99; am. Table 1, boron, Register, December, 1998, No. 516, eff. 12-31-99; am. Table 1, Register, March, 2000, No. 531, eff. 4-1-00; CR 03-063: am Table 1, Register February 2004 No. 578, eff. 3-1-04; CR 02-095: am. Table 1, Register November 2006 No. 611, eff. 12-1-06; reprinted to correct errors in Table 1, Register January 2007 No. 613; CR 07-034: am. Table 1 Register January 2008 No. 625, eff. 2-1-08; CR 09-102: am. Table 1 Register December 2010 No. 660, eff. 1-1-11.
Amended by, correction in Table 1 (Note). made under s. 13.92(4) (b) 7, Stats., Register January 2020 No. 769, eff. 2/1/2020
Amended by, correction in (Note [2]) made under s. 13.92 (4) (b) 7, Stats., Register March 2023 No. 807, eff. 4/1/2023
Amended by, CR 22-061: am. Table 1 Register July 2023 No. 811, eff. 8/1/2023

Acronyms in common use for oxanilic acid (for the pesticide metabolites acetochlor oxanilic acid and metolachlor oxanilic acid in Table 1 above) include both "OA" and "OXA."