Wis. Admin. Code Department of Natural Resources NR 445.07

Current through October 28, 2024
Section NR 445.07 - Emission thresholds, standards, control requirements and exemptions
(1) ALL SOURCES OF HAZARDOUS AIR CONTAMINANTS. Except as provided in sub. (5), the following requirements apply:
(a) No owner or operator of a source may cause, allow or permit emissions of a hazardous air contaminant listed in Table A in such quantity or concentration or for such duration as to cause an ambient air concentration of the contaminant off the source property that exceeds the concentration in column (g) of Table A for the contaminant.

Note: Owners and operators of facilities emitting less than 3 tons of volatile organic compounds and 5 tons particulate matter on an annual basis, or who engage in limited or no manufacturing activities, should refer to s. NR 445.11 prior to determining applicable requirements under this section.

(b) The owner or operator of a source may request approval of an alternative to the emission limitation in par. (a). The alternative emission limitation is 10% of the threshold limit value - time weighted average established by the American Conference of Governmental Industrial Hygienists, in the Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices for 2000, incorporated by reference in s. NR 484.11(2) (c), for any contaminant with a 24-hour averaging period in column (h) of Table A. The department may approve the alternative emission limitation if both of the following criteria are met:
1. The hazardous air contaminant is emitted no more than 5 days in any consecutive 30-day period.
2. The department determines, after consultation with the department of health services, that the alternative emission limitation will not pose a threat to public health or welfare.
(c) The owner or operator of a source that emits a hazardous air contaminant for which a control requirement is identified in column (i) of Table A in a quantity greater than the amount listed in column (c), (d), (e) or (f) of Table A for the contaminant shall control emissions of the contaminant to the level identified in column (i) of the table. The control requirement shall be applied according to the procedure in s. NR 445.08(2) (f).
(2) SOURCES OF HAZARDOUS AIR CONTAMINANTS FROM THE MANUFACTURE OR TREATMENT OF PESTICIDES, RODENTICIDES, INSECTICIDES, HERBICIDES OR FUNGICIDES. Except as provided in sub. (5) (c) and (d), in addition to the requirements of sub. (1), the owner or operator of a source that manufactures or treats pesticides, rodenticides, insecticides, herbicides or fungicides may not cause, allow or permit emissions of a hazardous air contaminant listed in Table B in a quantity or concentration or for a duration as to cause an ambient air concentration off the source property that exceeds the concentration in column (g) of Table B for the contaminant. For any hazardous air contaminant for which a control requirement is identified in column (i) of Table B that is emitted in an amount greater than the amount listed in column (c), (d), (e) or (f) of Table B for the contaminant, the owner or operator shall control emissions of the contaminant to the level identified in column (i) of the table. The control requirement shall be applied according to the procedure in s. NR 445.08(2) (f).
(3) SOURCES OF HAZARDOUS AIR CONTAMINANTS FROM THE MANUFACTURE OR TREATMENT OF PHARMACEUTICALS. Except as provided in sub. (5) (c) and (d), in addition to meeting the requirements of sub. (1), the owner or operator of a source that manufactures or treats pharmaceuticals and that emits a hazardous air contaminant for which a control requirement is identified in column (i) of Table C in an amount greater than the amount listed in column (c), (d), (e) or (f) of Table C for the contaminant shall control emissions of the contaminant to the level identified in column (i) of the table. The control requirement shall be applied according to the procedure in s. NR 445.08(2) (f).
(4) MUNICIPAL SOLID WASTE AND INFECTIOUS WASTE INCINERATORS.
(a) Except as provided for in par. (b), the owner or operator of a source that combusts municipal solid waste, as defined in s. NR 500.03(150), or infectious waste shall comply with sub. (1), and shall control emissions of hazardous air contaminants having a control requirement identified in column (i) in Table A, B or C to a level that is the lowest achievable emission rate. The control requirement shall be applied according to the procedure in s. NR 445.08(2) (f).
(b) A source that combusts no infectious waste and that combusts no municipal solid waste other than refuse derived fuel in a boiler is not subject to this subsection unless 50% or more of the boiler's heat input is obtained from the refuse derived fuel.
(5) EXEMPT EMISSIONS. Emissions from all of the following are exempt from the requirements of sub. (1) and emissions identified in pars. (c) and (d) are also exempt from the requirements of subs. (2) and (3):
(a) The combustion of group 1 virgin fossil fuels.
(b) The combustion of group 2 virgin fossil fuels vented from a stack that has downwash minimization stack height or a height approved by the department.
(c) A laboratory.
(d)
1. Indoor fugitive sources that emit any hazardous air contaminant with a concentration having a 1-hour or 24-hour average time period in column (h) in Table A, B or C.
2. Indoor fugitive sources that emit any hazardous air contaminant with a control requirement in column (i) or a concentration having an annual time period in column (h) in Table A, B or C that meet all of the following requirements:
a. The contaminant is exhausted to the ambient air through general building ventilation.
b. The contaminant has a threshold limit value established by the American Conference of Governmental Industrial Hygienists, in the Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices for 2000, incorporated by reference in s. NR 484.11(2) (c).
c. The owner or operator of the source demonstrates to the department that the source is in compliance with applicable occupational safety and health administration requirements.
(e) Gasoline dispensing for any hazardous air contaminant with a control requirement in column (i) of Table A provided that one of the following applies:
1. The gasoline dispensing facility meets the requirements of s. NR 420.04(3) (b) to (i) and dispenses less than 2 million gallons of gasoline in any 12 consecutive month period.
2. The gasoline dispensing facility dispenses less than 1.25 million gallons of gasoline in any 12 consecutive month period.
(f) Combustion of wood in combustion units that operate with good combustion technology and that were constructed or last modified prior to October 1, 1988 for any hazardous air contaminant with a control requirement in column (i) of Table A. Good combustion technology means technology that provides for a minimization of hazardous air contaminants with control requirements in column (i). Good combustion technology will be determined on a case-by-case basis by the department, taking into account the type of fuel to be burned, the economic and environmental impacts of the combustion, and other costs related to the source. Good combustion technology may include consideration of factors such as temperature, residence time, carbon monoxide emissions, excess oxygen, and turbulence.

Note: See department draft memo dated July 7, 1999, Wood Combustion and Compliance with Chapter NR 445, for further information regarding the use of this exemption. The draft memo may obtained by contacting the Compliance and Enforcement Section of the Bureau of Air Management at 608-266-7718.

(6) USE REQUIREMENTS FOR TABLES A, B AND C.
(a) The emission thresholds in columns (c) to (f) in Tables A, B and C for any hazardous air contaminant may only be used if emissions from the source are vented to the atmosphere in a manner that meets both of the following:
1. The emissions are from an unobstructed discharge point.

Note: Valves designed to open and close at the point of discharge are not considered to be obstructions if they are open at time of emission.

2. The emissions are from a stack that is within 10 degrees of vertical.
(b) For purposes of calculating non-exempt, potential to emit emissions for comparison with the threshold rates in column (c), (d), (e) or (f) in the tables the owner or operator of a source shall do all of the following:
1. Combine non-exempt, potential to emit emissions for each contaminant for all stacks within each of the 4 stack categories.
2. Compare each group of non-exempt, potential to emit emissions against the respective threshold found in column (c), (d), (e) or (f) in the table.
(c) For any group of non-exempt, potential to emit emissions that exceeds the respective threshold in column (c), (d), (e) or (f), consider all non-exempt, potential emissions from the source in determining compliance with the applicable standard or control requirement.

Hazardous Air Contaminant

CAS Number

Thresholds for Emission Points1

(expressed as lbs/hr or lbs/yr)

Ambient Air Standard

(per time period in column (h) expressed as micrograms per cubic meter)

Time Period for Standard and Threshold

Control

Requirement

Emissions from Stacks

<25 ft

Emissions from Stacks

25 to <40 ft

Emissions from Stacks

40 to <75 ft

Emissions from Stacks

>=75 ft

(a)

(b)

(c)

(d)

(e)

(f)

(g)

(h)

(i)

1.

Acetaldehyde

75-07-0

3.36

10.7

20.6

55.3

4,504

1 Hr

N/A

808

3,318

7,900

27,845

N/A

Annual

BACT

2.

Acetic acid

64-19-7

1.32

5.12

10.3

39.8

589

24 Hr Avg

N/A

3.

Acetic anhydride

108-24-7

1.12

4.36

8.79

33.9

501

24 Hr Avg

N/A

4.

Acetonitrile

75-05-8

3.61

14

28.3

109

1,612

24 Hr Avg

N/A

5.

Acetophenone

98-86-2

2.64

10.3

20.7

79.7

1,179

24 Hr Avg

N/A

6.

Acrolein

107-02-8

0.0171

0.0545

0.105

0.281

22.9

1 Hr

N/A

7.

Acrylamide

79-06-1

0.00161

0.00626

0.0126

0.0486

0.72

24 Hr Avg

N/A

1.37

5.62

13.4

47.1

N/A

Annual

BACT

8.

Acrylic acid

79-10-7

178

730

1,738

6,126

1

Annual

N/A

0.317

1.23

2.48

9.56

141

24 Hr Avg

N/A

9.

Acrylonitrile

107-13-1

26.1

107

256

901

N/A

Annual

BACT

10.

Adipic acid

124-04-9

0.269

1.04

2.11

8.11

120

24 Hr Avg

N/A

11.

Adiponitrile

111-69-3

0.475

1.85

3.72

14.3

212

24 Hr Avg

N/A

12.

Aflatoxins

1402-68-2

2.43

10

23.8

83.9

N/A

Annual

LAER

13.

Allyl alcohol

107-18-6

0.0638

0.248

0.5

1.93

28.5

24 Hr Avg

N/A

14.

Allyl chloride

107-05-1

0.168

0.653

1.32

5.07

75.1

24 Hr Avg

N/A

15.

Allyl glycidyl ether

106-92-3

0.251

0.974

1.97

7.57

112

24 Hr Avg

N/A

16.

Aluminum alkyls and soluble salts, as Al

7429-90-5

0.107

0.417

0.842

3.24

48

24 Hr Avg

N/A

17.

Aluminum pyro powders, as Al

7429-90-5

0.269

1.04

2.11

8.11

120

24 Hr Avg

N/A

18.

o-Aminoazotoluene (2-Aminoazotoluene)

97-56-3

1.62

6.64

15.8

55.7

N/A

Annual

BACT

19.

4-Aminobiphenyl

92-67-1

0.296

1.22

2.9

10.2

N/A

Annual

LAER

20.

Ammonia

7664-41-7

17,769

73,000

173,810

612,587

100

Annual

N/A

0.935

3.63

7.33

28.2

418

24 Hr Avg

N/A

21.

Ammonium perfluoroocta-noate

3825-26-1

0.000537

0.00209

0.00421

0.0162

0.24

24 Hr Avg

N/A

22.

Aniline

62-53-3

0.409

1.59

3.21

12.4

183

24 Hr Avg

N/A

23.

o-Anisidine and o-anisidine hydrochloride (mixtures and isomers)

29191-52-4

44.4 0.0271

183 0.105

435 0.212

1,531 0.817

N/A 12.1

Annual 24 Hr Avg

BACT N/A

24.

Antimony and compounds, as Sb

7440-36-0

0.0269

0.104

0.211

0.811

12

24 Hr Avg

N/A

25.

Antimony trioxide

1309-64-4

35.5

146

348

1,225

0.2

Annual

N/A

26.

Arsenic, elemental and inorganic compounds, as As

7440-38-2

0.413

1.7

4.04

14.2

N/A

Annual

LAER

27.

Arsine

7784-42-1

0.00856

0.0333

0.0671

0.258

3.83

24 Hr Avg

N/A

8.88

36.5

86.9

306

0.05

Annual

N/A

28.

Asbestos, all forms

1332-21-4

2.43

10

23.8

83.9

N/A

Annual

LAER

29.

Aziridine (Ethylenimine)

151-56-4

0.0473

0.184

0.371

1.43

21.1

24 Hr Avg

N/A

30.

Barium, soluble compounds, as Ba

7440-39-3

0.0269

0.104

0.211

0.811

12

24 Hr Avg

N/A

31.

Benz(a)anthracene

56-55-3

16.2

66.4

158

557

N/A

Annual

BACT

32.

Benzene

71-43-2

228

936

2,228

7,854

N/A

Annual

LAER

33.

Benzidine

92-87-5

0.0265

0.109

0.259

0.914

N/A

Annual

LAER

34.

Benzo(b)fluoranthene

205-99-2

2.43

10

23.8

83.9

N/A

Annual

BACT

35.

Benzo(j)fluoranthene

205-82-3

2.43

10

23.8

83.9

N/A

Annual

BACT

36.

Benzo(k)fluoranthene

207-08-9

2.43

10

23.8

83.9

N/A

Annual

BACT

37.

Benzo(a)pyrene

50-32-8

1.62

6.64

15.8

55.7

N/A

Annual

BACT

38.

Benzotrichloride

98-07-7

2.43

10

23.8

83.9

N/A

Annual

BACT

39.

Benzoyl chloride

98-88-4

0.215

0.684

1.31

3.53

287

1 Hr

N/A

40.

Benzoyl peroxide

94-36-0

0.269

1.04

2.11

8.11

120

24 Hr Avg

N/A

41.

Benzyl acetate

140-11-4

3.3

12.8

25.9

99.6

1,474

24 Hr Avg

N/A

42.

Benzyl chloride

100-44-7

0.278

1.08

2.18

8.4

124

24 Hr Avg

N/A

43.

Beryllium and beryllium compounds, as Be

7440-41-7

0.74 3.55

3.04 14.6

7.24 34.8

25.5 123

N/A 0.02

Annual Annual

BACT N/A

44.

Biphenyl

92-52-4

0.0678

0.263

0.531

2.05

30.3

24 Hr Avg

N/A

45.

Bis(2-chloroethyl)ether (Dichloroethyl ether)

111-44-4

1.57

6.1

12.3

47.4

702

24 Hr Avg

N/A

46.

Bis(2-dimethylaminoethyl) ether (DMAEE)

3033-62-3

0.0176

0.0684

0.138

0.531

7.87

24 Hr Avg

N/A

47.

Bis(2-ethyl hexyl) phthalate (Diethyl hexyl phthalate)

117-81-7

0.269

1.04

2.11

8.11

120

24 Hr Avg

N/A

48.

Bismuth telluride, as Bi2Te3: Se-doped

1304-82-1

0.269

1.04

2.11

8.11

120

24 Hr Avg

N/A

49.

Borates, tetra, sodium salts, decahydrate

1303-96-4

0.269

1.04

2.11

8.11

120

24 Hr Avg

N/A

50.

Borates, tetra, sodium salts, pentahydrate

1303-96-4

0.0537

0.209

0.421

1.62

24

24 Hr Avg

N/A

51.

Boron tribromide

10294-33-4

0.765

2.44

4.69

12.6

1,025

1 Hr

N/A

52.

Boron trifluoride

7637-07-2

0.207

0.66

1.27

3.4

277

1 Hr

N/A

53.

Bromine

7726-95-6

0.0351

0.136

0.275

1.06

15.7

24 Hr Avg

N/A

54.

Bromine pentafluoride

7789-30-2

0.0384

0.149

0.301

1.16

17.2

24 Hr Avg

N/A

55.

Bromodichloromethane

75-27-4

48

197

470

1,656

N/A

Annual

BACT

56.

Bromodiphenyls (Polybro-minated biphenyls; PBBs)

59536-65-1

0.207

0.849

2.02

7.12

N/A

Annual

BACT

57.

Bromoform

75-25-2

0.278

1.08

2.18

8.38

124

24 Hr Avg

N/A

58.

1,3-Butadiene

106-99-0

6.35

26.1

62.1

219

N/A

Annual

BACT

59.

2-Butoxyethanol (Ethylene glycol monobutyl ether; EGBE; Butyl Cellosolve)

111-76-2

2,309,939 5.19

9,490,000 20.2

22,595,238 40.7

79,636,364 157

13,000 2,320

Annual 24 Hr Avg

N/A

60.

n-Butyl acrylate

141-32-2

0.563

2.19

4.41

17

252

24 Hr Avg

N/A

61.

n-Butylamine

109-73-9

1.12

3.56

6.84

18.4

1,496

1 Hr

N/A

62.

n-butyl alcohol (n-Butanol)

71-36-3

11.3

36

69.3

186

15,157

1 Hr

N/A

63.

Butylated hydroxyanisole (BHA)

25013-16-5

31,173

128,070

304,929

1,074,715

N/A

Annual

BACT

64.

Butyl Cellosolve (2-But-oxyethanol; ethylene glycol monobutyl ether; EGBE)

111-76-2

2,309,939 5.19

9,490,000 20.2

22,595,238 40.7

79,636,364 157

13,000 2,320

Annual 24 Hr Avg

N/A

65.

tert-Butyl chromate, as Cr

1189-85-1

0.00747

0.0238

0.0457

0.123

10

1 Hr

N/A

0.148

0.608

1.45

5.1

N/A

Annual

LAER

66.

n-Butyl glycidyl ether (BGE)

2426-08-6

7.15

27.8

56.1

216

3,195

24 Hr Avg

N/A

67.

n-Butyl lactate

138-22-7

1.61

6.24

12.6

48.5

717

24 Hr Avg

N/A

68.

o-sec-Butylphenol

89-72-5

1.65

6.41

12.9

49.8

737

24 Hr Avg

N/A

69.

p-tert-Butyltoluene

98-51-1

0.326

1.26

2.55

9.83

145

24 Hr Avg

N/A

70.

C.I. Basic Red 9 monohy-drochloride

569-61-9

25

103

245

863

N/A

Annual

BACT

71.

Cadmium and cadmium compounds, as Cd

7440-43-9

0.987

4.06

9.66

34

N/A

Annual

LAER

72.

Calcium cyanamide

156-62-7

0.0269

0.104

0.211

0.811

12

24 Hr Avg

N/A

73.

Calcium hydroxide

1305-62-0

0.269

1.04

2.11

8.11

120

24 Hr Avg

N/A

74.

Calcium oxide

1305-78-8

0.107

0.417

0.842

3.24

48

24 Hr Avg

N/A

75.

Camphor (synthetic)

76-22-2

0.669

2.6

5.24

20.2

299

24 Hr Avg

N/A

76.

Caprolactam (aerosol and vapor)

105-60-2

1.24

4.83

9.74

37.5

555

24 Hr Avg

N/A

77.

Carbon black

1333-86-4

0.188

0.73

1.47

5.68

84

24 Hr Avg

N/A

78.

Carbon disulfide

75-15-0

124,381

511,000

1,216,667

4,288,112

700

Annual

N/A

1.67

6.5

13.1

50.5

747

24 Hr Avg

N/A

79.

Carbon tetrabromide

558-13-4

0.0729

0.283

0.571

2.2

32.6

24 Hr Avg

N/A

80.

Carbon tetrachloride

56-23-5

118

487

1,159

4,084

N/A

Annual

BACT

81.

Carbonyl fluoride

353-50-4

0.29

1.13

2.27

8.76

130

24 Hr Avg

N/A

82.

Catechol (Pyrocatechol)

120-80-9

1.21

4.7

9.48

36.5

540

24 Hr Avg

N/A

83.

Cellosolve (2-Ethoxyetha-nol; EGEE)

110-80-5

0.99 35,538

3.85 146,000

7.76 347,619

29.9

1,225,175

442 200

24 Hr Avg Annual

N/A N/A

84.

Cellosolve acetate (2-Eth-oxyethyl acetate; EGEEA)

111-15-9

1.45

5.64

11.4

43.8

649

24 Hr Avg

N/A

85.

Refractory ceramic fibers (respirable size)

2.43

10

23.8

83.9

N/A

Annual

BACT

86.

Cesium hydroxide

21351-79-1

0.107

0.417

0.842

3.24

48

24 Hr Avg

N/A

87.

Chlordecone (Kepone)

143-50-0

0.386

1.59

3.78

13.3

N/A

Annual

BACT

88.

Chlorendic acid

115-28-6

68.3

281

668

2,356

N/A

Annual

BACT

89.

Chlorinated diphenyl oxide

55720-99-5

0.0269

0.104

0.211

0.811

12

24 Hr Avg

N/A

90.

Chlorinated paraffins (C12; 60% chlorine)

108171-26-2

71.1

292

695

2,450

N/A

Annual

BACT

91.

Chlorine

7782-50-5

0.0779

0.303

0.611

2.35

34.8

24 Hr Avg

N/A

92.

Chlorine dioxide

10049-04-4

0.0148

0.0576

0.116

0.447

6.62

24 Hr Avg

N/A

93.

Chlorine trifluoride

7790-91-2

0.0282

0.0899

0.173

0.464

37.8

1 Hr

N/A

94.

2-Chloroacetophenone

532-27-4

0.017

0.066

0.133

0.513

7.59

24 Hr Avg

N/A

95.

Chlorobenzene (Mono-chlorobenzene)

108-90-7

2.47

9.61

19.4

74.7

1,105

24 Hr Avg

N/A

96.

o- Chlorobenzylidene mal-ononitrile

2698-41-1

0.0288

0.0917

0.176

0.473

38.6

1 Hr

N/A

97.

1-Chloro-1,1-difluoro-ethane (Hydrochlorofluoro-carbon-142b; HCFC-142b;

R-142b)

75-68-3

8,884,381

36,500,000

86,904,762

306,293,706

50,000

Annual

N/A

98.

Chlorodifluoromethane (Hydrochlorofluorocar-

bon-22; HCFC-22; R-22)

75-45-6

8,884,381

36,500,000

86,904,762

306,293,706

50,000

Annual

N/A

99.

Chlorodiphenyls (Polychlo-rinated biphenyls; PCBs)

1336-36-3

0.0269 0.1

0.104 0.1

0.211 0.1

0.811 0.1

12

N/A

24 Hr Avg Annual

N/A BACT

100.

1-Chloro-2,3-epoxypro-pane (Epichlorohydrin)

106-89-8

0.102 178

0.395 730

0.797 1,738

3.07 6,126

45.4 1

24 Hr Avg Annual

N/A N/A

1,481

6,083

14,484

51,049

N/A

Annual

BACT

101.

Chloroethane (Ethyl chloride)

75-00-3

14.2

1,776,876

55.1

7,300,000

111

17,380,952

428

61,258,741

6,333 10,000

24 Hr Avg Annual

N/A N/A

102.

Chloroform

67-66-3

2.62

10.2

20.6

79.2

1,172

24 Hr Avg

N/A

77.3

317

756

2,663

N/A

Annual

BACT

103.

Chloromethane (Methyl chloride)

74-87-3

5.55

21.5

43.5

167

2,478

24 Hr Avg

N/A

104.

p-Chloroprene

126-99-8

2.43

10

23.8

83.9

N/A

Annual

LAER

1.95

7.56

15.2

58.7

869

24 Hr Avg

N/A

105.

o-Chlorostyrene

2039-87-4

15.2

59.2

119

460

6,802

24 Hr Avg

N/A

106.

o-Chlorotoluene

95-49-8

13.9

54

109

420

6,213

24 Hr Avg

N/A

107.

Chromium (metal) and compounds other than chromium (VI), as Cr

7440-47-3

0.0269

0.104

0.211

0.811

12

24 Hr Avg

N/A

108.

Chromium (VI): chromic acid mists and dissolved Cr (VI) aerosols, as Cr

7440-47-3

1.42 0.148

5.84 0.608

13.9 1.45

49 5.1

0.008

N/A

Annual Annual

N/A LAER

109.

Chromium (VI): compounds and particulates, as Cr

7440-47-3

17.8 0.148

73 0.608

174 1.45

613 5.1

0.1

N/A

Annual Annual

N/A LAER

110.

Chromyl chloride, as Cr

14977-61-8

0.148

0.608

1.45

5.1

N/A

Annual

LAER

0.00851

0.0331

0.0667

0.257

3.8

24 Hr Avg

N/A

111.

Cobalt, elemental, and inorganic compounds, as Co

7440-48-4

0.00107

0.00417

0.00842

0.0324

0.48

24 Hr Avg

N/A

112.

Coke oven emissions

2.87

11.8

28

98.8

N/A

Annual

LAER

113.

Copper and compounds, dusts and mists, as Cu

7440-50-8

0.0537

0.209

0.421

1.62

24

24 Hr Avg

N/A

114.

Copper and compounds, fume, as Cu

7440-50-8

0.0107

0.0417

0.0842

0.324

4.8

24 Hr Avg

N/A

115.

p-Cresidine

120-71-8

41.3

170

404

1,425

N/A

Annual

BACT

116.

Cresol (mixtures and isomers)

1319-77-3

1.19

4.62

9.31

35.9

531

24 Hr Avg

N/A

117.

Crotonaldehyde

4170-30-3

0.0642

0.205

0.393

1.06

86

1 Hr

N/A

118.

Cumene (Isopropyl benzene)

98-82-8

13.2

51.3

103

399

5,899

24 Hr Avg

N/A

119.

Cyanamide

420-04-2

0.107

0.417

0.842

3.24

48

24 Hr Avg

N/A

120.

Cyanides, (inorganics), as CN

143-33-9

0.373

1.19

2.29

6.13

500

1 Hr

N/A

121.

Cyanogen

460-19-5

1.14

4.44

8.96

34.5

511

24 Hr Avg

N/A

122.

Cyanogen chloride

506-77-4

0.0563

0.179

0.345

0.926

75.4

1 Hr

N/A

123.

Cyclohexanol

108-93-0

11

42.7

86.2

332

4,916

24 Hr Avg

N/A

124.

Cyclohexanone

108-94-1

5.17

20.1

40.5

156

2,311

24 Hr Avg

N/A

125.

Cyclohexylamine

108-91-8

2.18

8.46

17.1

65.8

973

24 Hr Avg

N/A

126.

Cyclonite

121-82-4

0.0269

0.104

0.211

0.811

12

24 Hr Avg

N/A

127.

Cyclopentadiene

542-92-7

10.9

42.3

85.4

329

4,866

24 Hr Avg

N/A

128.

Danthron (1,8-Dihydroxy-anthroquinone)

117-10-2

80.8

332

790

2,784

N/A

Annual

BACT

129.

DBCP

(1,2-Dibromo-3-chloropr-opane)

96-12-8

0.935

3.84

9.15

32.2

N/A

Annual

BACT

130.

DDT (Dichlorodiphenyltri-chloroethane)

50-29-3

0.0537 18.3

0.209 75.3

0.421 179

1.62 632

24

N/A

24 Hr Avg Annual

N/A BACT

131.

Diacetone alcohol

123-42-2

12.8

49.6

100

385

5,701

24 Hr Avg

N/A

132.

2,4-Diaminoanisole sulfate

39156-41-7

480

1,973

4,698

16,556

N/A

Annual

BACT

133.

2,4-Diaminotoluene (Tolu-ene-2,4-diamine)

95-80-7

1.62

6.64

15.8

55.7

N/A

Annual

BACT

134.

Diazomethane

334-88-3

0.0185

0.0718

0.145

0.558

8.25

24 Hr Avg

N/A

135.

Dibenz(a,h)acridine

226-36-8

16.2

66.4

158

557

N/A

Annual

BACT

136.

Dibenz(a,j)acridine

224-42-0

16.2

66.4

158

557

N/A

Annual

BACT

137.

Dibenz(a,h)anthracene

53-70-3

1.48

6.08

14.5

51

N/A

Annual

BACT

138.

7H-Dibenzo(c,g)carbazole

194-59-2

1.62

6.64

15.8

55.7

N/A

Annual

BACT

139.

Dibenzo(a,e)pyrene

192-65-4

1.62

6.64

15.8

55.7

N/A

Annual

BACT

140.

Dibenzo(a,h)pyrene

189-64-0

0.162

0.664

1.58

5.57

N/A

Annual

BACT

141.

Dibenzo(a,i)pyrene

189-55-9

0.162

0.664

1.58

5.57

N/A

Annual

BACT

142.

Dibenzo(a,l)pyrene

191-30-0

0.162

0.664

1.58

5.57

N/A

Annual

BACT

143.

Diborane

19287-45-7

0.00608

0.0236

0.0477

0.184

2.72

24 Hr Avg

N/A

144.

1,2-Dibromo-3-chloropr-opane (DBCP)

96-12-8

0.935

3.84

9.15

32.2

N/A

Annual

BACT

145.

1,2-Dibromoethane (Ethyl-ene dibromide; EDB)

106-93-4

8.08

33.2

79

278

N/A

Annual

BACT

146.

2-N-Dibutylaminoethanol

102-81-8

0.19

0.74

1.49

5.75

85.1

24 Hr Avg

N/A

147.

Dibutylphenyl phosphate

2528-36-1

0.189

0.733

1.48

5.7

84.3

24 Hr Avg

N/A

148.

Dibutyl phthalate (Di-n-bu-tyl phthalate)

84-74-2

0.269

1.04

2.11

8.11

120

24 Hr Avg

N/A

149.

o-Dichlorobenzene (1,2-Dichlorobenzene)

95-50-1

8.07

31.4

63.3

244

3,608

24 Hr Avg

N/A

150.

p-Dichlorobenzene (1,4-Dichlorobenzene)

106-46-7

162

142,150

664

584,000

1,580 1,390,476

5,569 4,900,699

N/A 800

Annual Annual

BACT N/A

3.23

12.5

25.3

97.5

1,443

24 Hr Avg

N/A

151.

3,3'-Dichlorobenzidine

91-94-1

5.23

21.5

51.1

180

N/A

Annual

BACT

152.

1,3-Dichloro-5,5-dimethyl hydantoin

118-52-5

0.0107

0.0417

0.0842

0.324

4.8

24 Hr Avg

N/A

153.

Dichlorodiphenyltrichloro-ethane (DDT)

50-29-3

18.3 0.0537

75.3 0.209

179 0.421

632 1.62

N/A 24

Annual 24 Hr Avg

BACT N/A

154.

1,1-Dichloroethane (Ethyli-dene dichloride)

75-34-3

21.7

84.5

170

656

9,715

24 Hr Avg

N/A

155.

1,2-Dichloroethane (Ethylene dichloride; EDC)

107-06-2

68.3 2.17

281 8.45

668 17

2,356 65.6

N/A 971

Annual 24 Hr Avg

BACT N/A

156.

Dichloroethyl ether (Bis(2-chloroethyl)ether)

111-44-4

1.57

6.1

12.3

47.4

702

24 Hr Avg

N/A

157.

1,1-Dichloroethylene (Vinylidene chloride)

75-35-4

1.06

4.14

8.35

32.2

476

24 Hr Avg

N/A

158.

1,2-Dichloroethylene

540-59-0

42.6

166

334

1,286

19,033

24 Hr Avg

N/A

158m.

Dichloromethane (Methyl-ene chloride)

75-09-2

9.33 3,781

36.2 15,532

73.1 36,981

282

130,338

4,168

N/A

24 Hr Avg Annual

N/A BACT

159.

1,1-Dichloro-1-nitroethane

594-72-9

0.633

2.46

4.96

19.1

283

24 Hr Avg

N/A

160.

1,2-Dichloropropane (Pro-pylene dichloride)

78-87-5

18.6 711

72.3 2,920

146

6,952

562 24,503

8,318 4

24 Hr Avg Annual

N/A N/A

161.

Dicyclopentadiene

77-73-6

1.45

5.64

11.4

43.8

649

24 Hr Avg

N/A

162.

Diethanolamine

111-42-2

0.107

0.417

0.842

3.24

48

24 Hr Avg

N/A

163.

Diethylamine

109-89-7

0.803

3.12

6.3

24.3

359

24 Hr Avg

N/A

164.

2-Diethylaminoethanol

100-37-8

0.515

2

4.04

15.5

230

24 Hr Avg

N/A

165.

Diethylene triamine

111-40-0

0.227

0.881

1.78

6.84

101

24 Hr Avg

N/A

166.

Diethyl hexyl phthalate (Bis(2-ethyl hexyl) phthalate; Di-sec-octyl phthalate; DEHP)

117-81-7

0.269

1.04

2.11

8.11

120

24 Hr Avg

N/A

167.

Diethyl phthalate

84-66-2

0.269

1.04

2.11

8.11

120

24 Hr Avg

N/A

168.

Diethyl sulfate

64-67-5

2.43

10

23.8

83.9

N/A

Annual

BACT

169.

1,4-Diethylene oxide (1,4-Dioxane)

123-91-1

3.87 231

15 948

30.3 2,257

117

7,956

1,730 N/A

24 Hr Avg Annual

N/A BACT

170.

1,1-Difluoroethane

75-37-6

7,107,505

29,200,000

69,523,810

245,034,965

40,000

Annual

N/A

171.

Diglycidyl ether (DGE)

2238-07-5

0.0286

0.111

0.224

0.863

12.8

24 Hr Avg

N/A

172.

Diglycidyl resorcinol ether

101-90-6

3.63

14.9

35.5

125

N/A

Annual

BACT

173.

1,8-Dihydroxyanthroqui-none (Danthron)

117-10-2

80.8

332

790

2,784

N/A

Annual

BACT

174.

Diisobutyl ketone

108-83-8

7.81

30.4

61.2

236

3,490

24 Hr Avg

N/A

175.

Diisopropylamine

108-18-9

1.11

4.32

8.71

33.6

497

24 Hr Avg

N/A

176.

NjN-Dimethyl acetamide

127-19-5

1.91

7.44

15

57.8

855

24 Hr Avg

N/A

177.

Dimethylamine

124-40-3

0.495

1.92

3.88

14.9

221

24 Hr Avg

N/A

178.

4-Dimethylaminoazoben-zene

60-11-7

1.37

5.62

13.4

47.1

N/A

Annual

BACT

179.

Dimethylaniline (N,N-Di-methylaniline)

121-69-7

1.33

5.17

10.4

40.2

595

24 Hr Avg

N/A

180.

Dimethyl benzene (Xylene (mixtures and isomers);

Xylol)

1330-20-7

23.3

90.6

183

704

10,421

24 Hr Avg

N/A

181.

3,3'-Dimethylbenzidine (o-Tolidine)

119-93-7

2.43

10

23.8

83.9

N/A

Annual

BACT

182

Dimethyl carbamoyl chloride

79-44-7

0.48

1.97

4.7

16.6

N/A

Annual

BACT

183.

Dimethylethoxysilane

14857-34-2

0.114

0.445

0.897

3.46

51.1

24 Hr Avg

N/A

184.

N,N-Dimethylformamide

68-12-2

1.61

6.24

12.6

48.5

717

24 Hr Avg

N/A

5,331

21,900

52,143

183,776

30

Annual

N/A

185.

1,1-Dimethylhydrazine

57-14-7

2.43

10

23.8

83.9

N/A

Annual

BACT

186.

Dimethylphthalate

131-11-3

0.269

1.04

2.11

8.11

120

24 Hr Avg

N/A

187.

Dimethyl sulfate

77-78-1

2.43

10

23.8

83.9

N/A

Annual

BACT

0.0277

0.108

0.217

0.836

12.4

24 Hr Avg

N/A

188.

Dinitolmide

148-01-6

0.269

1.04

2.11

8.11

120

24 Hr Avg

N/A

189.

Dinitrobenzene (mixtures and isomers)

528-29-0

0.0554

0.215

0.434

1.67

24.8

24 Hr Avg

N/A

190.

Dinitrotoluene (mixtures and isomers)

25321-14-6

0.0107

0.0417

0.0842

0.324

4.8

24 Hr Avg

N/A

191.

1,4-Dioxane (1,4-Diethyl-ene oxide)

123-91-1

231 3.87

948 15

2,257 30.3

7,956 117

N/A 1,730

Annual 24 Hr Avg

BACT N/A

192.

Dioxins and Furans, chlorinated (2,3,7,8-Tetrachloro-dibenzo-p-dioxin), as equivalents

1746-01-6

0.0001

0.0001

0.0001

0.0001

N/A

Annual

LAER

193.

Direct Black 38 (benzi-dine-based dye)

1937-37-7

0.846

3.48

8.28

29.2

N/A

Annual

BACT

194.

Direct Blue 6 (benzidine-based dye)

2602-46-2

0.846

3.48

8.28

29.2

N/A

Annual

BACT

195.

Disperse Blue 1

2475-45-8

1,367

5,615

13,370

47,122

N/A

Annual

BACT

196.

Disulfiram

97-77-8

0.107

0.417

0.842

3.24

48

24 Hr Avg

N/A

197.

Divinyl benzene (mixtures and isomers)

1321-74-0

2.86

11.1

22.4

86.3

1,278

24 Hr Avg

N/A

198.

EGBE (2-Butoxyethanol; Ethylene glycol monobutyl ether; Butyl cellosolve)

111-76-2

2,309,939 5.19

9,490,000 20.2

22,595,238 40.7

79,636,364 157

13,000 2,320

Annual 24 Hr Avg

N/A

199.

EGEE (2-Ethoxyethanol; Ethylene glycol monoethyl ether; Cellosolve)

110-80-5

0.99 35,538

3.85 146,000

7.76 347,619

29.9

1,225,175

442 200

24 Hr Avg Annual

N/A N/A

200.

EGEEA (2-Ethoxyethyl acetate; Ethylene glycol monoethyl ether acetate; Cellosolve acetate)

111-15-9

1.45

5.64

11.4

43.8

649

24 Hr Avg

N/A

201.

EGME (2-Methoxyethanol; Methyl Cellosolve)

109-86-4

0.836

3.25

6.55

25.2

373

24 Hr Avg

N/A

202.

EGMEA (2-Methoxyethyl acetate; Methyl Cellosolve acetate)

110-49-6

1.3

5.04

10.2

39.2

580

24 Hr Avg

N/A

203.

Epichlorohydrin

(1-Chloro-2,3-epoxypro-

pane)

106-89-8

178 0.102

1,481

730 0.395

6,083

1,738 0.797

14,484

6,126 3.07

51,049

1

45.4

N/A

Annual 24 Hr Avg Annual

N/A N/A

BACT

204.

1,2-Epoxybutane (1,2-Butylene oxide)

106-88-7

3,554

14,600

34,762

122,517

20

Annual

N/A

205.

Erionite (Zeolites)

66733-21-9

2.43

10

23.8

83.9

N/A

Annual

LAER

206.

Ethanamine (Ethylamine)

75-04-7

0.495

1.92

3.88

14.9

221

24 Hr Avg

N/A

207.

Ethanolamine

141-43-5

0.403

1.56

3.16

12.2

180

24 Hr Avg

N/A

208.

2-Ethoxyethanol (Ethylene glycol monoethyl ether;

EGEE; Cellosolve)

110-80-5

35,538 0.99

146,000 3.85

347,619 7.76

1,225,175 29.9

200 442

Annual 24 Hr Avg

N/A N/A

209.

2-Ethoxyethyl acetate (Ethylene glycol monoethyl ether acetate; EGEEA; Cel-losolve acetate)

111-15-9

1.45

5.64

11.4

43.8

649

24 Hr Avg

N/A

210.

Ethyl acrylate

140-88-5

1.1

4.27

8.62

33.2

491

24 Hr Avg

N/A

211.

Ethylamine (Ethanamine)

75-04-7

0.495

1.92

3.88

14.9

221

24 Hr Avg

N/A

212.

Ethyl amyl ketone

541-85-5

7.04

27.4

55.2

213

3,146

24 Hr Avg

N/A

213.

Ethyl benzene

100-41-4

23.3

90.6

183

704

10,421

24 Hr Avg

N/A

177,688

730,000

1,738,095

6,125,874

1,000

Annual

N/A

214.

Ethyl bromide

74-96-4

1.2

4.65

9.38

36.1

535

24 Hr Avg

N/A

215.

Ethyl tert-butyl ether (ETBE)

637-92-3

1.12

4.36

8.8

33.9

501

24 Hr Avg

N/A

216.

Ethyl butyl ketone

106-35-4

12.5

48.7

98.3

379

5,604

24 Hr Avg

N/A

217.

Ethyl carbamate (Urethane)

51-79-6

6.13

25.2

59.9

211

N/A

Annual

BACT

218.

Ethyl chloride (Chloroethane)

75-00-3

1,776,876 14.2

7,300,000 55.1

17,380,952 111

61,258,741 428

10,000 6,333

Annual 24 Hr Avg

N/A N/A

219.

Ethyl cyanoacrylate

7085-85-0

0.055

0.214

0.431

1.66

24.6

24 Hr Avg

N/A

220.

Ethylene chlorohydrin

107-07-3

0.246

0.783

1.51

4.04

329

1 Hr

N/A

221.

Ethylenediamine

107-15-3

1.32

5.13

10.3

39.9

590

24 Hr Avg

N/A

222.

Ethylene dibromide (EDB; 1,2-Dibromoethane)

106-93-4

8.08

33.2

79

278

N/A

Annual

BACT

223.

Ethylene dichloride (EDC; 1,2-Dichloroethane)

107-06-2

2.17 68.3

8.45 281

17

668

65.6 2,356

971

N/A

24 Hr Avg Annual

N/A BACT

224.

Ethylene glycol monobutyl ether (2-Butoxyethanol; EGBE; Butyl cellosolve)

111-76-2

2,309,939 5.19

9,490,000 20.2

22,595,238 40.7

79,636,364 157

13,000 2,320

Annual 24 Hr Avg

N/A N/A

225.

Ethylene glycol monoethyl ether (2-Ethoxyethanol; EGEE; Cellosolve)

110-80-5

35,538 0.99

146,000 3.85

347,619 7.76

1,225,175 29.9

200 442

Annual 24 Hr Avg

N/A N/A

226.

Ethylene glycol monoethyl ether acetate (2-Ethoxy-ethyl acetate; EGEEA; Cellosolve acetate)

111-15-9

1.45

5.64

11.4

43.8

649

24 Hr Avg

N/A

227.

Ethylene glycol vapor and aerosol

107-21-1

7.47

23.8

45.7

123

10,000

1 Hr

N/A

228.

Ethylene oxide

75-21-8

20.2

83

198

696

N/A

Annual

LAER

229.

Ethylene thiourea

96-45-7

137

562

1,337

4,712

N/A

Annual

BACT

230.

Ethylenimine (Aziridine)

151-56-4

0.0473

0.184

0.371

1.43

21.1

24 Hr Avg

N/A

231.

Ethylidene dichloride (1,1-Dichloroethane)

75-34-3

21.7

84.5

170

656

9,715

24 Hr Avg

N/A

232.

Ethylidene norbornene

16219-75-3

1.84

5.85

11.2

30.2

2,458

1 Hr

N/A

233.

N-Ethylmorpholine

100-74-3

1.27

4.92

9.92

38.2

565

24 Hr Avg

N/A

234.

Ethyl silicate

78-10-4

4.58

17.8

35.9

138

2,045

24 Hr Avg

N/A

235.

Fenamiphos

22224-92-6

0.00537

0.0209

0.0421

0.162

2.4

24 Hr Avg

N/A

236.

Flour dust (inhalable fraction)

0.0269

0.104

0.211

0.811

12

24 Hr Avg

N/A

237.

Fluorides, (inorganics), as F

0.134

0.522

1.05

4.05

60

24 Hr Avg

N/A

238.

Fluorine

7782-41-4

0.0835

0.324

0.654

2.52

37.3

24 Hr Avg

N/A

239.

Formaldehyde

50-00-0

137

562

1,337

4,712

N/A

Annual

BACT

240.

Formamide

75-12-7

0.99

3.84

7.76

29.9

442

24 Hr Avg

N/A

241.

Formic acid

64-18-6

0.506

1.96

3.96

15.3

226

24 Hr Avg

N/A

242.

Furan

110-00-9

2.43

10

23.8

83.9

N/A

Annual

BACT

243.

Furfural

98-01-1

0.422

1.64

3.31

12.7

189

24 Hr Avg

N/A

244.

Furfuryl alcohol

98-00-0

2.16

8.37

16.9

65.1

963

24 Hr Avg

N/A

245.

Germanium tetrahydride

7782-65-2

0.0337

0.131

0.264

1.02

15

24 Hr Avg

N/A

246.

Glutaraldehyde

111-30-8

0.0153

0.0487

0.0936

0.251

20.5

1 Hr

N/A

247.

Glycidol

556-52-5

0.325

1.26

2.55

9.83

145

24 Hr Avg

N/A

2.43

10

23.8

83.9

N/A

Annual

BACT

248.

Graphite (all forms except graphite fiber)

7782-42-5

0.107

0.417

0.842

3.24

48

24 Hr Avg

N/A

249.

Hexachlorobenzene (HCB)

118-74-1

0.000107

0.000417

0.000842

0.00324

0.048

24 Hr Avg

N/A

3.86

15.9

37.8

133

N/A

Annual

BACT

250.

Hexachloroethane

67-72-1

0.52

2.02

4.08

15.7

232

24 Hr Avg

N/A

444

1,825

4,345

15,315

N/A

Annual

BACT

251.

Hexachloronaphthalene

1335-87-1

0.0107

0.0417

0.0842

0.324

4.8

24 Hr Avg

N/A

252.

Hexamethyl phosphoramide

680-31-9

2.43

10

23.8

83.9

N/A

Annual

BACT

253.

Hexamethylene-1,6-diiso-cyanate (HDI)

822-06-0

1.78 0.00185

7.3

0.00718

17.4 0.0145

61.3 0.0558

0.01 0.826

Annual 24 Hr Avg

N/A N/A

254.

n-Hexane

110-54-3

35,538

146,000

347,619

1,225,175

200

Annual

N/A

9.47

36.8

74.2

286

4,230

24 Hr Avg

N/A

255.

1,6- Hexanediamine

124-09-4

0.128

0.496

1

3.85

57

24 Hr Avg

N/A

256.

1-Hexene

592-41-6

5.55

21.6

43.5

167

2,478

24 Hr Avg

N/A

257.

Hexone (Methyl isobutyl ketone; MIBk)

108-10-1

11

42.7

86.2

332

4,916

24 Hr Avg

N/A

258.

sec-Hexyl acetate

108-84-9

15.8

61.5

124

478

7,078

24 Hr Avg

N/A

259.

Hexylene glycol

107-41-5

9.02

28.7

55.2

148

12,083

1 Hr

N/A

260.

Hydrazine and hydrazine sulfate

302-01-2

0.363 0.000704

1.49 0.00274

3.55 0.00552

12.5 0.0213

N/A 0.315

Annual 24 Hr Avg

BACT N/A

261.

Hydrochloric acid (Hydrogen chloride; Muriatic acid)

7647-01-0

0.557 3,554

1.77 14,600

3.41

34,762

9.15 122,517

746 20

1 Hr Annual

N/A N/A

262.

Hydrogenated terphenyls

61788-32-7

0.265

1.03

2.08

7.99

118

24 Hr Avg

N/A

263

Hydrogen bromide

10035-10-6

0.741

2.36

4.54

12.2

993

1 Hr

N/A

264.

Hydrogen chloride (Hydrochloric acid; Muriatic acid)

7647-01-0

3,554 0.557

14,600 1.77

34,762 3.41

122,517 9.15

20 746

Annual 1 Hr

N/A N/A

265.

Hydrogen cyanide

74-90-8

0.388

1.24

2.38

6.38

520

1 Hr

N/A

266.

Hydrogen fluoride (Hydrofluoric acid)

7664-39-3

0.183

0.584

1.12

3.01

246

1 Hr

N/A

267.

Hydrogen peroxide

7722-84-1

0.0747

0.29

0.586

2.26

33.4

24 Hr Avg

N/A

268.

Hydrogen sulfide

7783-06-4

0.749

2.91

5.87

22.6

335

24 Hr Avg

N/A

269.

Hydroquinone

123-31-9

0.107

0.417

0.842

3.24

48

24 Hr Avg

N/A

270.

2-Hydroxypropyl acrylate

999-61-1

0.143

0.555

1.12

4.32

63.9

24 Hr Avg

N/A

271.

Indeno(1,2,3-cd)pyrene

193-39-5

16.2

66.4

158

557

N/A

Annual

BACT

272.

Indium

7440-74-6

0.00537

0.0209

0.0421

0.162

2.4

24 Hr Avg

N/A

273.

Iodine

7553-56-2

0.0775

0.247

0.475

1.27

104

1 Hr

N/A

274.

lodomethane (Methyl iodide)

74-88-4

0.624

2.42

4.89

18.8

279

24 Hr Avg

N/A

275.

Iron oxide dust and fume, as Fe

1309-37-1

0.269

1.04

2.11

8.11

120

24 Hr Avg

N/A

276.

Iron salts, soluble, as Fe

0.0537

0.209

0.421

1.62

24

24 Hr Avg

N/A

277.

Isobutyl alcohol

78-83-1

8.14

31.6

63.8

246

3,638

24 Hr Avg

N/A

278.

Isooctyl alcohol

26952-21-6

14.3

55.6

112

432

6,392

24 Hr Avg

N/A

279.

Isophorone

78-59-1

2.11

6.72

12.9

34.7

2,826

1 Hr

N/A

280.

Isophorone diisocyanate

4098-71-9

0.00244

0.00949

0.0191

0.0737

1.09

24 Hr Avg

N/A

281.

Isoprene

78-79-5

2.43

10

23.8

83.9

N/A

Annual

BACT

282.

2-Isopropoxyethanol

109-59-1

5.72

22.2

44.8

173

2,556

24 Hr Avg

N/A

283.

Isopropylamine

75-31-0

0.649

2.52

5.09

19.6

290

24 Hr Avg

N/A

284.

Isopropyl benzene (Cumene)

98-82-8

13.2

51.3

103

399

5,899

24 Hr Avg

N/A

285.

Isopropyl glycidyl ether

4016-14-2

12.8

49.6

100

385

5,702

24 Hr Avg

N/A

286.

N-Isopropylaniline

768-52-5

0.594

2.31

4.66

17.9

265

24 Hr Avg

N/A

287.

Kaolin

1332-58-7

0.107

0.417

0.842

3.24

48

24 Hr Avg

N/A

288.

Kepone (Chlordecone)

143-50-0

0.386

1.59

3.78

13.3

N/A

Annual

BACT

289.

Ketene

463-51-4

0.0462

0.179

0.362

1.39

20.6

24 Hr Avg

N/A

290.

Lead acetate, as Pb

301-04-2

22.2

91.3

217

766

N/A

Annual

BACT

291.

Lead phosphate, as Pb

7446-27-7

148

608

1,448

5,105

N/A

Annual

BACT

292.

Maleic anhydride

108-31-6

0.0215

0.0837

0.169

0.65

9.63

24 Hr Avg

N/A

293.

Manganese, elemental and inorganic compounds, as

Mn

7439-96-5

0.0107

0.0417

0.0842

0.324

4.8

24 Hr Avg

N/A

294.

Mercury, as Hg, alkyl compounds

7439-97-6

0.000537

0.00209

0.00421

0.0162

0.24

24 Hr Avg

N/A

295.

Mercury, as Hg, aryl compounds

7439-97-6

0.00537

0.0209

0.0421

0.162

2.4

24 Hr Avg

N/A

296.

Mercury, as Hg, inorganic forms including metallic mercury

7439-97-6

53.3

219

521

1,838

0.3

Annual

N/A

0.00134

0.00522

0.0105

0.0405

0.6

24 Hr Avg

N/A

297.

Mesityl oxide

141-79-7

3.23

12.6

25.4

97.6

1,445

24 Hr Avg

N/A

298.

Methacrylic acid

79-41-4

3.78

14.7

29.7

114

1,690

24 Hr Avg

N/A

299.

2-Methoxyethanol (Methyl cellosolve; EGME)

109-86-4

0.836

3.25

6.55

25.2

373

24 Hr Avg

N/A

300.

2-Methoxyethyl acetate (Methyl Cellosolve acetate;

EGMEA)

110-49-6

1.3

5.04

10.2

39.2

580

24 Hr Avg

N/A

301.

4-Methoxyphenol

150-76-5

0.269

1.04

2.11

8.11

120

24 Hr Avg

N/A

302.

Methyl acrylate

96-33-3

0.378

1.47

2.97

11.4

169

24 Hr Avg

N/A

303.

Methylacrylonitrile

126-98-7

0.147

0.573

1.16

4.45

65.9

24 Hr Avg

N/A

304.

Methylamine

74-89-5

0.341

1.33

2.67

10.3

152

24 Hr Avg

N/A

305.

Methyl n-amyl ketone

110-43-0

12.5

48.7

98.3

379

5,604

24 Hr Avg

N/A

306.

N-Methyl aniline

100-61-8

0.118

0.457

0.923

3.55

52.6

24 Hr Avg

N/A

307.

2-Methyl aziridine (Propy-lenimine; Propylene imine)

75-55-8

0.251 2.43

0.975 10

1.97 23.8

7.57 83.9

112

N/A

24 Hr Avg Annual

N/A BACT

308.

Methyl n-butyl ketone

591-78-6

1.1

4.27

8.62

33.2

492

24 Hr Avg

N/A

309.

Methyl cellosolve (2-Methoxyethanol;

EGME)

109-86-4

0.836

3.25

6.55

25.2

373

24 Hr Avg

N/A

310.

Methyl cellosolve acetate (2-Methoxyethyl acetate;

EGMEA)

110-49-6

1.3

5.04

10.2

39.2

580

24 Hr Avg

N/A

311.

Methyl chloride (Chloro-methane)

74-87-3

5.55

21.5

43.5

167

2,478

24 Hr Avg

N/A

312.

5-Methyl chrysene

3697-24-3

1.62

6.64

15.8

55.7

N/A

Annual

BACT

313.

Methyl 2-cyanoacrylate

137-05-3

0.0488

0.19

0.383

1.47

21.8

24 Hr Avg

N/A

314.

Methylcyclohexanol

25639-42-3

12.5

48.7

98.3

379

5,604

24 Hr Avg

N/A

315.

o-Methylcyclohexanone

583-60-8

12.3

47.9

96.6

372

5,505

24 Hr Avg

N/A

316.

Methylene bisphenyl isocy-anate (Methylene diphenyl isocyanate; MDI)

101-68-8

0.00275 107

0.0107 438

0.0215 1,043

0.083 3,676

1.23 0.6

24 Hr Avg Annual

N/A N/A

317.

Methylene chloride (Dichloromethane)

75-09-2

9.33 3,781

36.2 15,532

73.1 36,981

282

130,338

4,168

N/A

24 Hr Avg Annual

N/A BACT

318.

4,4'-Methylene bis(2-chlo-roaniline) (MOCA)

101-14-4

4.13

17

40.4

142

N/A

Annual

BACT

319.

Methylene bis(4-cyclohexy-lisocyanate)

5124-30-1

0.00288

0.0112

0.0226

0.087

1.29

24 Hr Avg

N/A

320.

4,4'-Methylenedianiline (and dihydrochloride)

101-77-9

0.0436 3.86

0.169 15.9

0.341 37.8

1.31 133

19.5

N/A

24 Hr Avg Annual

N/A BACT

321.

Methyl ethyl ketone peroxide

1338-23-4

0.108

0.343

0.659

1.77

144

1 Hr

N/A

322.

Methyl formate

107-31-3

14.3

55.5

112

431

6,385

24 Hr Avg

N/A

323.

Methyl hydrazine

60-34-4

0.00101

0.00393

0.00793

0.0306

0.452

24 Hr Avg

N/A

324.

Methyl iodide (lodome-thane)

74-88-4

0.624

2.42

4.89

18.8

279

24 Hr Avg

N/A

325.

Methyl isoamyl ketone

110-12-3

12.5

48.7

98.3

379

5,605

24 Hr Avg

N/A

326.

Methyl isobutyl carbinol

108-11-2

5.61

21.8

44

169

2,507

24 Hr Avg

N/A

327.

Methyl isobutyl ketone (MIBK; Hexone)

108-10-1

11

42.7

86.2

332

4,916

24 Hr Avg

N/A

328.

Methyl isocyanate

624-83-9

0.00251

0.00974

0.0196

0.0757

1.12

24 Hr Avg

N/A

329.

Methyl methacrylate

80-62-6

124,381

511,000

1,216,667

4,288,112

700

Annual

N/A

11

42.7

86.2

332

4,914

24 Hr Avg

N/A

330.

a-Methyl styrene

98-83-9

13

50.4

102

392

5,800

24 Hr Avg

N/A

331.

Methyl tert-butyl ether (MTBE)

1634-04-4

7.75 533,063

30.1

2,190,000

60.7

5,214,286

234

18,377,622

3,462 3,000

24 Hr Avg Annual

N/A N/A

332.

MIBK (Methyl isobutyl ketone; Hexone)

108-10-1

11

42.7

86.2

332

4,916

24 Hr Avg

N/A

333.

Mirex

2385-85-5

0.348

1.43

3.41

12

N/A

Annual

BACT

334.

Molybdenum, as Mo, metal and insoluble compounds

7439-98-7

0.537

2.09

4.21

16.2

240

24 Hr Avg

N/A

335.

Molybdenum, as Mo, soluble compounds

7439-98-7

0.269

1.04

2.11

8.11

120

24 Hr Avg

N/A

336.

Monochlorobenzene (Chlorobenzene)

108-90-7

2.47

9.61

19.4

74.7

1,105

24 Hr Avg

N/A

337.

Morpholine

110-91-8

3.83

14.9

30

116

1,710

24 Hr Avg

N/A

338.

MTBE (Methyl tert-butyl ether)

1634-04-4

533,063 7.75

2,190,000 30.1

5,214,286 60.7

18,377,622 234

3,000 3,462

Annual 24 Hr Avg

N/A N/A

339.

Muriatic acid (Hydrogen chloride; Hydrochloric acid)

7647-01-0

3,554 0.557

14,600 1.77

34,762 3.41

122,517 9.15

20 746

Annual 1 Hr

N/A N/A

340.

Mustard gas

505-60-2

2.43

10

23.8

83.9

N/A

Annual

LAER

341.

Naphthalene

91-20-3

2.82

10.9

22.1

85

1,258

24 Hr Avg

N/A

342.

2-Naphthylamine

91-59-8

2.43

10

23.8

83.9

N/A

Annual

LAER

343.

Nickel and compounds, as Ni

7440-02-0

6.83

28.1

66.8

236

N/A

Annual

BACT

344.

Nickel carbonyl, as Ni

13463-39-3

6.83

28.1

66.8

236

N/A

Annual

BACT

0.0188

0.0729

0.147

0.566

8.38

24 Hr Avg

N/A

345.

Nickel subsulfide, as Ni

12035-72-2

3.7

15.2

36.2

128

N/A

Annual

LAER

346.

Nitric acid

7697-37-2

0.277

1.08

2.17

8.36

124

24 Hr Avg

N/A

347.

Nitrilotriacetic acid

139-13-9

1,185

4,867

11,587

40,839

N/A

Annual

BACT

348.

p-Nitroaniline

100-01-6

0.161

0.626

1.26

4.86

72

24 Hr Avg

N/A

349.

Nitrobenzene

98-95-3

0.27

1.05

2.12

8.17

121

24 Hr Avg

N/A

350.

p-Nitrochlorobenzene

100-00-5

0.0346

0.134

0.271

1.05

15.5

24 Hr Avg

N/A

351.

Nitroethane

79-24-3

16.5

64.1

129

498

7,369

24 Hr Avg

N/A

352.

Nitrogen mustards

(2,2'-Dichloro-N-methyl-

diethylamine)

51-75-2

2.43

10

23.8

83.9

N/A

Annual

BACT

353.

Nitromethane

75-52-5

2.68

10.4

21

81

1,198

24 Hr Avg

N/A

354.

1-Nitropropane

108-03-2

4.89

19

38.4

148

2,186

24 Hr Avg

N/A

355.

2-Nitropropane

79-46-9

2.43

10

23.8

83.9

N/A

Annual

BACT

1.96

7.6

15.3

59.1

875

24 Hr Avg

N/A

356.

1-Nitropyrene

5522-43-0

16.2

66.4

158

557

N/A

Annual

BACT

357.

N-Nitrosodi-n-butylamine

924-16-3

1.11

4.56

10.9

38.3

N/A

Annual

BACT

358.

N-Nitrosodiethanolamine

1116-54-7

2.22

9.13

21.7

76.6

N/A

Annual

BACT

359.

N-Nitrosodiethylamine

55-18-5

0.0413

0.17

0.404

1.42

N/A

Annual

BACT

360.

N-Nitrosodimethylamine

62-75-9

0.127

0.521

1.24

4.38

N/A

Annual

BACT

361.

N-Nitrosodi-n-propyla-mine

621-64-7

0.888

3.65

8.69

30.6

N/A

Annual

BACT

362.

N-Nitroso-N-ethylurea

759-73-9

0.231

0.948

2.26

7.96

N/A

Annual

BACT

363.

N-Nitroso-N-methylurea

684-93-5

0.0523

0.215

0.511

1.8

N/A

Annual

BACT

364.

N-Nitrosomethylvinyla-mine

4549-40-0

2.43

10

23.8

83.9

N/A

Annual

BACT

365.

N-Nitrosomorpholine

59-89-2

0.935

3.84

9.15

32.2

N/A

Annual

BACT

366.

N'-Nitrosonornicotine

16543-55-8

2.43

10

23.8

83.9

N/A

Annual

BACT

367.

N-Nitrosopiperidine

100-75-4

0.658

2.7

6.44

22.7

N/A

Annual

BACT

368.

N-Nitrosopyrrolidine

930-55-2

2.91

12

28.5

100

N/A

Annual

BACT

369.

N-Nitrososarcosine

13256-22-9

2.43

10

23.8

83.9

N/A

Annual

BACT

370.

Nitrotoluene (mixtures and isomers)

88-72-2

0.603

2.34

4.72

18.2

269

24 Hr Avg

N/A

371.

Nitrous oxide

10024-97-2

4.84

18.8

37.9

146

2,160

24 Hr Avg

N/A

372.

Octachloronaphthalene

2234-13-1

0.00537

0.0209

0.0421

0.162

2.4

24 Hr Avg

N/A

373.

Oxalic acid

144-62-7

0.0537

0.209

0.421

1.62

24

24 Hr Avg

N/A

374.

p,p'-Oxybis(benzenesulfo-nyl hydrazide)

80-51-3

0.00537

0.0209

0.0421

0.162

2.4

24 Hr Avg

N/A

375.

Pentachloronaphthalene

1321-64-8

0.0269

0.104

0.211

0.811

12

24 Hr Avg

N/A

376.

Pentachloronitrobenzene (Quintobenzene; PCNB)

82-68-8

0.0269

0.104

0.211

0.811

12

24 Hr Avg

N/A

377.

Pentachlorophenol (PCP)

87-86-5

0.0269

0.104

0.211

0.811

12

24 Hr Avg

N/A

378.

Pentyl Acetate (mixtures and isomers)

628-63-7

14.3

55.6

112

432

6,390

24 Hr Avg

N/A

379.

Perchloroethylene (Tetra-chloroethylene)

127-18-4

301 9.11

1,237 35.4

2,946 71.4

10,383 275

N/A 4,069

Annual 24 Hr Avg

BACT N/A

380.

Perchloromethyl mercaptan

594-42-3

0.0408

0.159

0.32

1.23

18.2

24 Hr Avg

N/A

381.

Perfluoroisobutylene

382-21-8

0.00611

0.0195

0.0374

0.1

8.18

1 Hr

N/A

382.

Persulfates (ammonium, potassium, sodium)

7727-54-0

0.00537

0.0209

0.0421

0.162

2.4

24 Hr Avg

N/A

383.

PGME (Propylene glycol monomethyl ether)

107-98-2

355,375

1,460,000

3,476,190

12,251,748

2,000

Annual

N/A

384.

Phenol

108-95-2

1.03

4.02

8.1

31.2

462

24 Hr Avg

N/A

385.

Phenolphthalein

77-09-8

2.43

10

23.8

83.9

N/A

Annual

BACT

386.

Phenylenediamine (mixtures and isomers)

106-50-3

0.00537

0.0209

0.0421

0.162

2.4

24 Hr Avg

N/A

387.

Phenyl ether vapor

101-84-8

0.374

1.45

2.93

11.3

167

24 Hr Avg

N/A

388.

Phenyl glycidyl ether (PGE)

122-60-1

0.033

0.128

0.259

0.996

14.7

24 Hr Avg

N/A

389.

Phenylhydrazine

100-63-0

0.0238

0.0923

0.186

0.717

10.6

24 Hr Avg

N/A

390.

Phenyl mercaptan

108-98-5

0.121

0.47

0.949

3.65

54.1

24 Hr Avg

N/A

391.

Phosgene

75-44-5

0.0217

0.0844

0.17

0.656

9.71

24 Hr Avg

N/A

392.

Phosphine

7803-51-2

0.0224

0.0871

0.176

0.677

10

24 Hr Avg

N/A

393.

Phosphoric acid

7664-38-2

0.0537

0.209

0.421

1.62

24

24 Hr Avg

N/A

1,777

7,300

17,381

61,259

10

Annual

N/A

394.

Phosphorus (yellow)

7723-14-0

0.00544

0.0212

0.0427

0.164

2.43

24 Hr Avg

N/A

395.

Phosphorus oxychloride

10025-87-3

0.0337

0.131

0.264

1.02

15.1

24 Hr Avg

N/A

396.

Phosphorus pentachloride

10026-13-8

0.0457

0.178

0.359

1.38

20.4

24 Hr Avg

N/A

397.

Phosphorus pentasulfide

1314-80-3

0.0537

0.209

0.421

1.62

24

24 Hr Avg

N/A

398.

Phosphorus trichloride

7719-12-2

0.0604

0.234

0.473

1.82

27

24 Hr Avg

N/A

399.

Phthalic anhydride

85-44-9

0.325

1.26

2.55

9.82

145

24 Hr Avg

N/A

400.

Picric acid

88-89-1

0.00537

0.0209

0.0421

0.162

2.4

24 Hr Avg

N/A

401.

Platinum (metal)

7440-06-4

0.0537

0.209

0.421

1.62

24

24 Hr Avg

N/A

402.

Platinum, soluble salts, as Pt

7440-06-4

0.000107

0.000417

0.000842

0.00324

0.048

24 Hr Avg

N/A

403.

Polybrominated biphenyls (PBBs; Bromodiphenyls)

59536-65-1

0.207

0.849

2.02

7.12

N/A

Annual

BACT

404.

Polychlorinated biphenyls (PCBs; Chlorodiphenyls; Arochlor)

1336-36-3

0.0269 0.1

0.104 0.1

0.211 0.1

0.811 0.1

12

N/A

24 Hr Avg Annual

N/A BACT

405.

Potassium hydroxide

1310-58-3

0.149

0.476

0.914

2.45

200

1 Hr

N/A

406.

1,3-Propane sultone

1120-71-4

2.58

10.6

25.2

88.8

N/A

Annual

BACT

407.

Propargyl alcohol

107-19-7

0.123

0.479

0.965

3.72

55

24 Hr Avg

N/A

408.

P-Propiolactone

57-57-8

0.444

1.83

4.35

15.3

N/A

Annual

BACT

0.0792

0.308

0.62

2.39

35.4

24 Hr Avg

N/A

409.

Propionic acid

79-09-4

1.63

6.32

12.8

49.1

727

24 Hr Avg

N/A

410.

Propylene dichloride (1,2-Dichloropropane)

78-87-5

711 18.6

2,920 72.3

6,952 146

24,503 562

4

8,318

Annual 24 Hr Avg

N/A N/A

411.

Propylene glycol mono-methyl ether (PGME)

107-98-2

355,375

1,460,000

3,476,190

12,251,748

2,000

Annual

N/A

412.

Propylene oxide

75-56-9

5,331

21,900

52,143

183,776

30

Annual

N/A

2.55

9.91

20

77

1,140

24 Hr Avg

N/A

480

1,973

4,698

16,556

N/A

Annual

BACT

413.

Propylenimine (2-Methyl aziridine; Propylene imine)

75-55-8

0.251 2.43

0.975 10

1.97 23.8

7.57 83.9

112

N/A

24 Hr Avg Annual

N/A BACT

414.

Pyridine

110-86-1

0.77

2.99

6.04

23.2

344

24 Hr Avg

N/A

415.

Pyrocatechol (Catechol)

120-80-9

1.21

4.7

9.48

36.5

540

24 Hr Avg

N/A

416.

Quintobenzene (Penta-chloronitrobenzene)

82-68-8

0.0269

0.104

0.211

0.811

12

24 Hr Avg

N/A

417.

Resorcinol

108-46-3

2.42

9.4

19

73

1,081

24 Hr Avg

N/A

418.

Rhodium (metal) and insoluble compounds, as Rh

7440-16-6

0.0537

0.209

0.421

1.62

24

24 Hr Avg

N/A

419.

Rhodium, soluble compounds, as Rh

7440-16-6

0.000537

0.00209

0.00421

0.0162

0.24

24 Hr Avg

N/A

420.

Safrole

94-59-7

28.2

116

276

972

N/A

Annual

BACT

421.

Selenium and compounds, as Se

7782-49-2

0.0107

0.0417

0.0842

0.324

4.8

24 Hr Avg

N/A

422.

Silicon tetrahydride (Silane)

7803-62-5

0.353

1.37

2.77

10.7

158

24 Hr Avg

N/A

423.

Sodium azide, as sodium azide or hydrazoic acid vapor

26628-22-8

0.0218

0.0696

0.134

0.359

29.3

1 Hr

N/A

424.

Sodium bisulfite

7631-90-5

0.269

1.04

2.11

8.11

120

24 Hr Avg

N/A

425.

Sodium hydroxide

1310-73-2

0.149

0.476

0.914

2.45

200

1 Hr

N/A

426.

Sodium metabisulfite

7681-57-4

0.269

1.04

2.11

8.11

120

24 Hr Avg

N/A

427.

Stoddard solvent (Mineral spirits)

8052-41-3

30.8

119

241

929

13,742

24 Hr Avg

N/A

428.

Strong inorganic acid mists containing sulfuric acid (>35% by weight)

7664-93-9

2.43

10

23.8

83.9

N/A

Annual

BACT

429.

Styrene, monomer

100-42-5

4.58

17.8

35.9

138

2,045

24 Hr Avg

N/A

177,688

730,000

1,738,095

6,125,874

1,000

Annual

N/A

430.

Sulfometuron methyl

74222-97-2

0.269

1.04

2.11

8.11

120

24 Hr Avg

N/A

431.

Sulfur monochloride

10025-67-9

0.412

1.31

2.53

6.78

552

1 Hr

N/A

432.

Sulfur tetrafluoride

7783-60-0

0.033

0.105

0.202

0.542

44.2

1 Hr

N/A

433.

Sulfuric acid

7664-93-9

0.0537

0.209

0.421

1.62

24

24 Hr Avg

N/A

434.

Sulprofos

35400-43-2

0.0537

0.209

0.421

1.62

24

24 Hr Avg

N/A

435.

Talc, containing no asbestos fibers

14807-96-6

0.107

0.417

0.842

3.24

48

24 Hr Avg

N/A

436.

Tantalum, metal and oxide dusts, as Ta

7440-25-7

0.269

1.04

2.11

8.11

120

24 Hr Avg

N/A

437.

TCDD (2,3,7,8-Tetrachloro-dibenzo-p-dioxin), as equivalents

1746-01-6

0.0001

0.0001

0.0001

0.0001

N/A

Annual

LAER

438.

Tellurium and compounds, except hydrogen telluride, as Te

13494-80-9

0.00537

0.0209

0.0421

0.162

2.4

24 Hr Avg

N/A

439.

Terphenyls

26140-60-3

0.373

1.19

2.29

6.13

500

1 Hr

N/A

440.

2,3,7,8-Tetrachlorodiben-zo-p-dioxin (Dioxin; 2,3,7,8-TCDD), as dioxin equivalents

1746-01-6

0.0001

0.0001

0.0001

0.0001

N/A

Annual

LAER

441.

1,1,2,2-Tetrachloroethane

79-34-5

0.369

1.43

2.89

11.1

165

24 Hr Avg

N/A

442.

Tetrachloroethylene (Per-chloroethylene)

127-18-4

9.11 301

35.4 1,237

71.4

2,946

275 10,383

4,069 N/A

24 Hr Avg Annual

N/A BACT

443.

Tetrachloronaphthalene

1335-88-2

0.107

0.417

0.842

3.24

48

24 Hr Avg

N/A

444.

1,1,1,2-Tetrafluoroethane

811-97-2

14,215,010

58,400,000

139,047,619

490,069,930

80,000

Annual

N/A

445.

Tetrafluoroethylene

116-14-3

0.44

1.71

3.45

13.3

197

24 Hr Avg

N/A

2.43

10

23.8

83.9

N/A

Annual

BACT

446.

Tetrahydrofuran

109-99-9

31.7

123

248

956

14,155

24 Hr Avg

N/A

447.

Tetranitromethane

509-14-8

0.00215

0.00837

0.0169

0.065

0.962

24 Hr Avg

N/A

2.43

10

23.8

83.9

N/A

Annual

BACT

448.

Thallium, elemental and soluble compounds, as Tl

7440-28-0

0.00537

0.0209

0.0421

0.162

2.4

24 Hr Avg

N/A

449.

Thionyl chloride

7719-09-7

0.363

1.16

2.23

5.97

487

1 Hr

N/A

450.

Thiourea

62-56-6

84.6

348

828

2,917

N/A

Annual

BACT

451.

Tin organic compounds, as Sn

7440-31-5

0.00537

0.0209

0.0421

0.162

2.4

24 Hr Avg

N/A

452.

Tin, metal, oxides and inorganic compounds, except tin hydride, as Sn

7440-31-5

0.107

0.417

0.842

3.24

48

24 Hr Avg

N/A

453.

o-Tolidine (3,3'-Dimethyl-benzidine)

119-93-7

2.43

10

23.8

83.9

N/A

Annual

BACT

454.

Toluene (Toluol)

108-88-3

71,075

292,000

695,238

2,450,350

400

Annual

N/A

10.1

39.3

79.3

306

4,522

24 Hr Avg

N/A

455.

2,4-/2,6-Toluene diisocya-nate (mixtures and isomers) (TDI)

584-84-9

162 0.00191 12.4

664 0.00743 51.1

1,580

0.015 122

5,569

0.0578 429

N/A 0.855 0.07

Annual 24 Hr Avg Annual

BACT N/A N/A

456.

Toluene-2,4-diamine (2,4-Diaminotoluene)

95-80-7

1.62

6.64

15.8

55.7

N/A

Annual

BACT

457.

m- and p-Toluidine

108-44-1

0.471

1.83

3.69

14.2

210

24 Hr Avg

N/A

458.

o-Toluidine and o-toluidine hydrochloride and mixed isomers

95-53-4

34.8 0.471

143 1.83

341 3.69

1,201 14.2

N/A 210

Annual 24 Hr Avg

BACT N/A

459.

Toluol (Toluene)

108-88-3

71,075

292,000

695,238

2,450,350

400

Annual

N/A

10.1

39.3

79.3

306

4,522

24 Hr Avg

N/A

460.

Tributyl phosphate

126-73-8

0.117

0.455

0.917

3.53

52.3

24 Hr Avg

N/A

461.

1,2,4-Trichlorobenzene

120-82-1

2.77

8.82

17

45.5

3,711

1 Hr

N/A

462.

1,1,2-Trichloroethane

79-00-5

2.93

11.4

23

88.5

1,310

24 Hr Avg

N/A

463.

Trichloroethylene (Tri-chloroethene)

79-01-6

888 14.4

3,650 56.1

8,690 113

30,629 436

N/A 6,449

Annual 24 Hr Avg

BACT N/A

464.

Trichloronaphthalene

1321-65-9

0.269

1.04

2.11

8.11

120

24 Hr Avg

N/A

465.

2,4,6-Trichlorophenol

88-06-2

573

2,355

5,607

19,761

N/A

Annual

BACT

466.

1,2,3-Trichloropropane

96-18-4

2.43

10

23.8

83.9

N/A

Annual

BACT

3.24

12.6

25.4

97.8

1,447

24 Hr Avg

N/A

467.

Triethanolamine

102-71-6

0.269

1.04

2.11

8.11

120

24 Hr Avg

N/A

468.

Triethylamine

121-44-8

0.222

0.864

1.74

6.71

99.3

24 Hr Avg

N/A

469.

1,3,5-Triglycidyl-s-triazi-netrione

2451-62-9

0.00269

0.0104

0.0211

0.0811

1.2

24 Hr Avg

N/A

470.

Trimellitic anhydride

552-30-7

0.00299

0.00951

0.0183

0.0491

4

1 Hr

N/A

471.

Trimethyl benzene (mixtures and isomers)

25551-13-7

6.6

25.6

51.7

199

2,949

24 Hr Avg

N/A

472.

Trimethylamine

75-50-3

0.649

2.52

5.09

19.6

290

24 Hr Avg

N/A

473.

2,4,6-Trinitrotoluene (TNT)

118-96-7

0.00537

0.0209

0.0421

0.162

2.4

24 Hr Avg

N/A

474.

Triorthocresyl phosphate

78-30-8

0.00537

0.0209

0.0421

0.162

2.4

24 Hr Avg

N/A

475.

Triphenyl phosphate

115-86-6

0.161

0.626

1.26

4.86

72

24 Hr Avg

N/A

476.

Tris(2,3-dibromopropyl phosphate)

126-72-7

2.69

11.1

26.3

92.8

N/A

Annual

BACT

477.

Tungsten, as W, metal and insoluble compounds

7440-33-7

0.269

1.04

2.11

8.11

120

24 Hr Avg

N/A

478.

Tungsten, as W, soluble compounds

7440-33-7

0.0537

0.209

0.421

1.62

24

24 Hr Avg

N/A

479.

Uranium (natural), soluble and insoluble compounds,

as U

7440-61-1

0.0107

0.0417

0.0842

0.324

4.8

24 Hr Avg

N/A

480.

Urethane (Ethyl carbamate)

51-79-6

6.13

25.2

59.9

211

N/A

Annual

BACT

481.

n-Valeraldehyde

110-62-3

9.46

36.8

74.2

286

4,227

24 Hr Avg

N/A

482.

Vanadium pentoxide, as V2O5, respirable dust and fume

1314-62-1

0.00269

0.0104

0.0211

0.0811

1.2

24 Hr Avg

N/A

483.

Vinyl acetate

108-05-4

35,538

146,000

347,619

1,225,175

200

Annual

N/A

1.89

7.35

14.8

57.1

845

24 Hr Avg

N/A

484.

Vinyl bromide

593-60-2

0.117

0.456

0.921

3.55

52.5

24 Hr Avg

N/A

485.

Vinyl chloride

75-01-4

17,769

73,000

173,810

612,587

100

Annual

N/A

202

830

1,975

6,961

N/A

Annual

LAER

486.

Vinyl cyclohexene dioxide

(4-Vinyl-1-cyclohexene

diepoxide)

106-87-6

2.43 0.0308

10 0.12

23.8 0.241

83.9 0.93

N/A 13.8

Annual 24 Hr Avg

BACT N/A

487.

4-Vinyl cyclohexene

100-40-3

0.0238

0.0923

0.186

0.717

10.6

24 Hr Avg

N/A

488.

Vinyl fluoride

75-02-5

0.101

0.393

0.793

3.05

45.2

24 Hr Avg

N/A

489.

Vinylidene chloride (1,1-Dichloroethylene)

75-35-4

1.06

4.14

8.35

32.2

476

24 Hr Avg

N/A

490.

Vinyl toluene

25013-15-4

13

50.4

102

392

5,800

24 Hr Avg

N/A

491.

Xylene (mixtures and isomers) (Xylol; Dimethyl benzene)

1330-20-7

23.3

90.6

183

704

10,421

24 Hr Avg

N/A

492.

m-Xylene-([ALPHA], [ALPHA]'-diamine

1477-55-0

0.00747

0.0238

0.0457

0.123

10

1 Hr

N/A

493.

Xylidine (mixtures and isomers)

1300-73-8

0.133

0.517

1.04

4.02

59.5

24 Hr Avg

N/A

494.

Yttrium metal and compounds, as Y

7440-65-5

0.0537

0.209

0.421

1.62

24

24 Hr Avg

N/A

495.

Zeolites (Erionite)

66733-21-9

2.43

10

23.8

83.9

N/A

Annual

LAER

496.

Zirconium and compounds, as Zr

7440-67-7

0.269

1.04

2.11

8.11

120

24 Hr Avg

N/A

Note: The emission rates in columns (c) to (f) in Table A for any hazardous air contaminant may only be used if emissions are from an unobstructed vertical discharge point. Owners and operators of sources unable to use this table should refer to s. NR 445.08(2).

1 For purposes of calculating non-exempt, potential to emit emissions for comparison with the threshold value in column (c), (d), (e) or (f) in the table the owner or operator of a source would:

- combine non-exempt, potential to emit emissions for each contaminant for all stacks within each of the 4 stack categories,

- compare each group of non-exempt, potential to emit emissions against the respective threshold found in column (c), (d), (e) or (f) in the table

- if any group exceeds it's respective threshold in column (c), (d), (e) or (f), consider all non-exempt, potential to emit emissions from the source in determining compliance with the applicable standard or control requirement.

Hazardous Air Contaminant

CAS Number

Thresholds for Emission Points1

(expressed as lbs/hr or lbs/yr)

Ambient Air Standard

(per time period in

Time Period for Standard and Threshold

Control

Requirement

Emissions from Stacks

<25 ft

Emissions from Stacks

25 to <40 ft

Emissions from Stacks

40 to <75 ft

Emissions from Stacks

>=75 ft

column (h) expressed as micrograms per cubic meter)

(a)

(b)

(c)

(d)

(e)

(f)

(g)

(h)

(i)

1.

Aldrin

309-00-2

0.0134

0.0522

0.105

0.405

6

24 Hr Avg

N/A

2.

Amitrole

61-82-5

6.58

27

64.4

227

N/A

Annual

BACT

0.0107

0.0417

0.0842

0.324

4.8

24 Hr Avg

N/A

3.

Antimony hydride (Stibine)

7803-52-3

0.0274

0.107

0.215

0.828

12.2

24 Hr Avg

N/A

4.

ANTU

86-88-4

0.0161

0.0626

0.126

0.486

7.2

24 Hr Avg

N/A

5.

Atrazine

1912-24-9

0.269

1.04

2.11

8.11

120

24 Hr Avg

N/A

6.

Azinphos-methyl

86-50-0

0.0107

0.0417

0.0842

0.324

4.8

24 Hr Avg

N/A

7.

Baygon (Propoxur)

114-26-1

0.0269

0.104

0.211

0.811

12

24 Hr Avg

N/A

8.

Benomyl

17804-35-2

0.537

2.09

4.21

16.2

240

24 Hr Avg

N/A

9.

Bromacil

314-40-9

0.537

2.09

4.21

16.2

240

24 Hr Avg

N/A

10.

Bromomethane (Methyl bromide)

74-83-9

888

3,650

8,690

30,629

5

Annual

N/A

0.209

0.81

1.64

6.3

93.2

24 Hr Avg

N/A

11.

Captafol

2425-06-1

0.00537

0.0209

0.0421

0.162

2.4

24 Hr Avg

N/A

12.

Captan

133-06-2

0.269

1.04

2.11

8.11

120

24 Hr Avg

N/A

13.

Carbaryl

63-25-2

0.269

1.04

2.11

8.11

120

24 Hr Avg

N/A

14.

Carbofuran

1563-66-2

0.00537

0.0209

0.0421

0.162

2.4

24 Hr Avg

N/A

15.

Chlordane

57-74-9

0.0269

0.104

0.211

0.811

12

24 Hr Avg

N/A

16.

Chlorinated camphene (Toxaphene)

8001-35-2

5.55

22.8

54.3

191

N/A

Annual

BACT

0.0269

0.104

0.211

0.811

12

24 Hr Avg

N/A

17.

1-Chloro-1-nitropropane

600-25-9

0.543

2.11

4.25

16.4

243

24 Hr Avg

N/A

18.

Chloropicrin (Trichloro-nitromethane)

76-06-2

0.0361

0.14

0.283

1.09

16.1

24 Hr Avg

N/A

19.

Chlorpyrifos

2921-88-2

0.0107

0.0417

0.0842

0.324

4.8

24 Hr Avg

N/A

20.

Crufomate

299-86-5

0.269

1.04

2.11

8.11

120

24 Hr Avg

N/A

21.

Cyhexatin

13121-70-5

0.269

1.04

2.11

8.11

120

24 Hr Avg

N/A

22.

Demeton

8065-48-3

0.00568

0.0221

0.0445

0.171

2.54

24 Hr Avg

N/A

23.

Diazinon

333-41-5

0.00537

0.0209

0.0421

0.162

2.4

24 Hr Avg

N/A

24.

1,3-Dichloropropene

542-75-6

444

1,825

4,345

15,315

N/A

Annual

BACT

0.244

0.947

1.91

7.36

109

24 Hr Avg

N/A

3,554

14,600

34,762

122,517

20

Annual

N/A

25.

2,2-Dichloropropionic acid

75-99-0

0.269

1.04

2.11

8.11

120

24 Hr Avg

N/A

26.

Dichlorvos

62-73-7

88.8

365

869

3,063

0.5

Annual

N/A

0.0483

0.188

0.379

1.46

21.6

24 Hr Avg

N/A

27.

Dicrotophos

141-66-2

0.0134

0.0522

0.105

0.405

6

24 Hr Avg

N/A

28.

Dieldrin

60-57-1

0.0134

0.0522

0.105

0.405

6

24 Hr Avg

N/A

29.

Dinitro-o-cresol (4,6-Dinitro-o-cresol)

534-52-1

0.0107

0.0417

0.0842

0.324

4.8

24 Hr Avg

N/A

30.

Dioxathion

78-34-2

0.0107

0.0417

0.0842

0.324

4.8

24 Hr Avg

N/A

31.

Diquat, respirable dust (various compounds) (Diquat dibromide)

2764-72-9

0.00537

0.0209

0.0421

0.162

2.4

24 Hr Avg

N/A

32.

Diquat, total dust (various compounds) (Diquat dibro-mide)

2764-72-9

0.0269

0.104

0.211

0.811

12

24 Hr Avg

N/A

33.

Disulfoton

298-04-4

0.00537

0.0209

0.0421

0.162

2.4

24 Hr Avg

N/A

34.

Endosulfan

115-29-7

0.00537

0.0209

0.0421

0.162

2.4

24 Hr Avg

N/A

35.

Endrin

72-20-8

0.00537

0.0209

0.0421

0.162

2.4

24 Hr Avg

N/A

36.

EPN

2104-64-5

0.00537

0.0209

0.0421

0.162

2.4

24 Hr Avg

N/A

37.

Ethion

563-12-2

0.0215

0.0835

0.168

0.649

9.6

24 Hr Avg

N/A

38.

Fensulfothion

115-90-2

0.00537

0.0209

0.0421

0.162

2.4

24 Hr Avg

N/A

39.

Fenthion

55-38-9

0.0107

0.0417

0.0842

0.324

4.8

24 Hr Avg

N/A

40.

Fonofos

944-22-9

0.00537

0.0209

0.0421

0.162

2.4

24 Hr Avg

N/A

41.

Heptachlor and heptachlor epoxide

76-44-8

0.00269

0.0104

0.0211

0.0811

1.2

24 Hr Avg

N/A

42.

Hexachlorobutadiene

87-68-3

0.0115

0.0445

0.0898

0.346

5.12

24 Hr Avg

N/A

43.

Hexachlorocyclohexane and isomers (Lindane and isomers)

58-89-9

0.0269

0.104

0.211

0.811

12

24 Hr Avg

N/A

5.73

23.5

56.1

198

N/A

Annual

BACT

44.

Hexachlorocyclopenta-diene

77-47-4

0.00599

0.0233

0.047

0.181

2.68

24 Hr Avg

N/A

45.

Lindane and other hexa-chlorocyclohexane isomers

58-89-9

5.73

23.5

56.1

198

N/A

Annual

BACT

0.0269

0.104

0.211

0.811

12

24 Hr Avg

N/A

46.

Methomyl

16752-77-5

0.134

0.522

1.05

4.05

60

24 Hr Avg

N/A

47.

Methyl bromide (Bromo-methane)

74-83-9

888

3,650

8,690

30,629

5

Annual

N/A

0.209

0.81

1.64

6.3

93.2

24 Hr Avg

N/A

48.

Methyl demeton

8022-00-2

0.0269

0.104

0.211

0.811

12

24 Hr Avg

N/A

49.

Methyl parathion

298-00-0

0.0107

0.0417

0.0842

0.324

4.8

24 Hr Avg

N/A

50.

Metribuzin

21087-64-9

0.269

1.04

2.11

8.11

120

24 Hr Avg

N/A

51.

Mevinphos (Phosdrin)

7786-34-7

0.00483

0.0188

0.0379

0.146

2.16

24 Hr Avg

N/A

52.

Monocrotophos

6923-22-4

0.0134

0.0522

0.105

0.405

6

24 Hr Avg

N/A

53.

Naled

300-76-5

0.161

0.626

1.26

4.86

72

24 Hr Avg

N/A

54.

Paraquat (respirable sizes) (Paraquat chloride)

1910-42-5

0.00537

0.0209

0.0421

0.162

2.4

24 Hr Avg

N/A

55.

Parathion

56-38-2

0.00537

0.0209

0.0421

0.162

2.4

24 Hr Avg

N/A

56.

Phenothiazine

92-84-2

0.269

1.04

2.11

8.11

120

24 Hr Avg

N/A

57.

Phorate

298-02-2

0.00269

0.0104

0.0211

0.0811

1.2

24 Hr Avg

N/A

58.

Pindone

83-26-1

0.00537

0.0209

0.0421

0.162

2.4

24 Hr Avg

N/A

59.

Propoxur (Baygon)

114-26-1

0.0269

0.104

0.211

0.811

12

24 Hr Avg

N/A

60.

Pyrethrum

8003-34-7

0.269

1.04

2.11

8.11

120

24 Hr Avg

N/A

61.

Quinone

106-51-4

0.0237

0.0923

0.186

0.717

10.6

24 Hr Avg

N/A

62.

Rotenone (commercial)

83-79-4

0.269

1.04

2.11

8.11

120

24 Hr Avg

N/A

63.

Sodium fluoroacetate

62-74-8

0.00269

0.0104

0.0211

0.0811

1.2

24 Hr Avg

N/A

64.

Stibine (Antimony hydride)

7803-52-3

0.0274

0.107

0.215

0.828

12.2

24 Hr Avg

N/A

65.

Strychnine

57-24-9

0.00806

0.0313

0.0632

0.243

3.6

24 Hr Avg

N/A

66.

Sulfotep (TEDP)

3689-24-5

0.0107

0.0417

0.0842

0.324

4.8

24 Hr Avg

N/A

67.

Sulfuryl fluoride

2699-79-8

1.12

4.36

8.79

33.8

501

24 Hr Avg

N/A

68.

TEPP

107-49-3

0.00269

0.0104

0.0211

0.0811

1.2

24 Hr Avg

N/A

69.

Thiram

137-26-8

0.0537

0.209

0.421

1.62

24

24 Hr Avg

N/A

70.

Toxaphene (Chlorinated camphene)

8001-35-2

5.55

22.8

54.3

191

N/A

Annual

BACT

0.0269

0.104

0.211

0.811

12

24 Hr Avg

N/A

71.

Trichloronitromethane (Chloropicrin)

76-06-2

0.0361

0.14

0.283

1.09

16.1

24 Hr Avg

N/A

72.

Warfarin

81-81-2

0.00537

0.0209

0.0421

0.162

2.4

24 Hr Avg

N/A

Note:The emission rates in columns (c) to (f) in Table B for any hazardous air contaminant may only be used if emissions are from an unobstructed vertical discharge point. Owners and operators of sources unable to use this table should refer to s. NR 445.08(2).

1For purposes of calculating non-exempt, potential to emit emissions for comparison with the threshold value in column (c), (d), (e) or (f) in the table the owner or operator of a source would:

-combine non-exempt, potential to emit emissions for each contaminant for all stacks within each of the 4 stack categories,

-compare each group of non-exempt, potential to emit emissions against the respective threshold found in column (c), (d), (e) or (f) in the table,

-if any group exceeds it's respective threshold in column (c), (d), (e) or (f), consider all non-exempt, potential to emit emissions from the source in determining compliance with the applicable or control requirement

Hazardous Air Contaminant

CAS Number

Thresholds for Emission Points1

(expressed as lbs/hr or lbs/yr)

Ambient Air Standard

(per time period in column (h) expressed as micrograms per cubic meter)

Time Period for Standard and Threshold

Control

Requirement

Emissions from Stacks

<25 ft

Emissions from Stacks

25 to <40 ft

Emissions from Stacks

40 to <75 ft

Emissions from Stacks

>=75 ft

(a)

(b)

(c)

(d)

(e)

(f)

(g)

(h)

(i)

1.

Adriamycin

23214-92-8

2.43

10

23.8

83.9

N/A

Annual

BACT

2.

Azathioprine

446-86-6

3.48

14.3

34.1

120

N/A

Annual

LAER

3.

Bischloroethyl nitrosourea

154-93-8

2.43

10

23.8

83.9

N/A

Annual

BACT

4.

N,N-Bis (2-chloro- ethyl)-2-naphthylamine (Chlornaphazine)

494-03-1

2.43

10

23.8

83.9

N/A

Annual

LAER

5.

Bis(chloromethyl) ether (BCME) and technical grade

542-88-1

2.43

10

23.8

83.9

N/A

Annual

LAER

6.

1,4-Butanediol dimethane-sulphonate (Myleran; busul-phan)

55-98-1

2.43

10

23.8

83.9

N/A

Annual

LAER

7.

Chlorambucil

305-03-3

0.0137

0.0562

0.134

0.471

N/A

Annual

LAER

8.

Chlornaphazine (N,N-Bis (2-chloroethyl)-2-naphthyl- amine)

494-03-1

2.43

10

23.8

83.9

N/A

Annual

LAER

9.

1-(2-Chloroethyl)-3-cyclo-hexyl-1-nitrosourea (CCNU)

13010-47-4

2.43

10

23.8

83.9

N/A

Annual

BACT

10.

Chloromethyl methyl ether (CMME)

107-30-2

2.43

10

23.8

83.9

N/A

Annual

LAER

11.

Cyclophosphamide

50-18-0

10.5

42.9

102

360

N/A

Annual

LAER

12.

Dacarbazine

4342-03-4

0.127

0.521

1.24

4.38

N/A

Annual

BACT

13.

Diethylstilbestrol (DES)

56-53-1

0.0178

0.073

0.174

0.613

N/A

Annual

LAER

14.

Estradiol (Oestradiol)

50-28-2

0.162

0.664

1.58

5.57

N/A

Annual

BACT

15.

Iron dextran complex

9004-66-4

2.43

10

23.8

83.9

N/A

Annual

BACT

16.

Melphalan

148-82-3

0.048

0.197

0.47

1.66

N/A

Annual

LAER

17.

Mestranol

72-33-3

2.43

10

23.8

83.9

N/A

Annual

BACT

18.

N-Methyl-N'-nitro-N-nitro-soguanidine (MNNG)

70-25-7

0.74

3.04

7.24

25.5

N/A

Annual

BACT

19.

Myleran (1,4-Butanediol dimethanesulphonate; Busul-phan)

55-98-1

2.43

10

23.8

83.9

N/A

Annual

LAER

20.

Oestradiol (Estradiol)

50-28-2

0.162

0.664

1.58

5.57

N/A

Annual

BACT

21.

Phenazopyridine and phena-zopyridine hydrochloride

136-40-3

36.3

149

355

1250

N/A

Annual

BACT

22.

Phenytoin and sodium salt of phenytoin

57-41-0

2.43

10

23.8

83.9

N/A

Annual

BACT

23.

Procarbazine and procarbazine hydrochloride

366-70-1

0.444

1.83

4.35

15.3

N/A

Annual

BACT

24.

Propylthiouracil

51-52-5

6.13

25.2

59.9

211

N/A

Annual

BACT

25.

Streptozotocin

18883-66-4

0.0573

0.235

0.561

1.98

N/A

Annual

BACT

26.

Thiotepa (Tris(1-aziri-dinyl)phosphine sulfide)

52-24-4

0.523

2.15

5.11

18

N/A

Annual

LAER

27.

Tris(1-aziridinyl)phosphine sulfide (Thiotepa)

52-24-4

0.523

2.15

5.11

18

N/A

Annual

LAER

The emission rates in columns (c) to (f) in Table C for any hazardous air contaminant may only be used if emissions are from an unobstructed vertical discharge point. Owners and operators of sources unable to use this table should refer to s. NR 445.08(2).

1For purposes of calculating non-exempt, potential to emit emissions for comparison with the threshold value in column (c), (d), (e) or (f) in the table the owner or operator of a source would:

-combine non-exempt, potential to emit emissions for each contaminant for all stacks within each of the 4 stack categories,

-compare each group of non-exempt, potential to emit emissions against the respective threshold found in column (c), (d), (e) or (f) in the table

-if any group exceeds its respective threshold in column (c), (d), (e) or (f), consider all non-exempt, potential to emit emissions from the source in determining compliance with the applicable standard or control requirement

Wis. Admin. Code Department of Natural Resources NR 445.07

CR 02-097: cr. Register June 2004 No. 582, eff. 7-1-04; CR 07-076: am. Tables A, B and C Register July 2008 No. 631, eff. 8-1-08; correction in (1) (b) 2. made under s. 13.92(4) (b) 6, Stats., Register August 2008 No. 632.