Section NR 440.54 - Phosphate rock plants(1) APPLICABILITY AND DESIGNATION OF AFFECTED FACILITY.(a) The provisions of this section are applicable to the following affected facilities used in phosphate rock plants which have a maximum plant production capacity greater than 3.6 megagrams per hour (4 tons/hr): dryers, calciners, grinders, and ground rock handling and storage facilities, except those facilities producing or preparing phosphate rock solely for consumption in elemental phosphorus production.(b) Any facility under par. (a) which commences construction, modification or reconstruction after September 21, 1979, is subject to the requirements of this section. (2) DEFINITIONS. As used in this section, terms not defined in this subsection have the meanings given in s. NR 440.02. (a) "Beneficiation" means the process of washing the rock to remove impurities or to separate size fractions.(b) "Calciner" means a unit in which the moisture and organic matter of phosphate rock is reduced within a combustion chamber.(c) "Dryer" means a unit in which the moisture content of phosphate rock is reduced by contact with a heated gas stream.(d) "Grinder" means a unit which is used to pulverize dry phosphate rock to the final product size used in the manufacture of phosphate fertilizer and does not include crushing devices used in mining.(e) "Ground phosphate rock handling and storage system" means a system which is used for the conveyance and storage of ground phosphate rock from grinders at phosphate rock plants.(f) "Phosphate rock feed" means all material entering the process unit including moisture and extraneous material as well as the following ore minerals: fluorapatite, hydroxylapatite, chlorapatite and carbonateapatite.(g) "Phosphate rock plant" means any plant which produces or prepares phosphate rock product by any or all of the following processes: mining, beneficiation, crushing, screening, cleaning, drying, calcining and grinding.(3) STANDARD FOR PARTICULATE MATTER. (a) On and after the date on which the performance test required to be conducted by s. NR 440.08 is completed, no owner or operator subject to the provisions of this section may cause to be discharged into the atmosphere: 1. From any phosphate rock dryer any gases which:a. Contain particulate matter in excess of 0.030 kilogram per megagram of phosphate rock feed (0.060 lb/ton), orb. Exhibit greater than 10% opacity.2. From any phosphate rock calciner processing unbeneficiated rock or blends of beneficiated and unbeneficiated rock, any gases which: a. Contain particulate matter in excess of 0.12 kilogram per megagram of phosphate rock feed (0.23 lb/ton), orb. Exhibit greater than 10% opacity.3. From any phosphate rock calciner processing beneficiated rock any gases which: a. Contain particulate matter in excess of 0.055 kilogram per megagram of phosphate rock feed (0.11 lb/ton), orb. Exhibit greater than 10% opacity.4. From any phosphate rock grinder any gases which:a. Contain particulate matter in excess of 0.006 kilogram per megagram of phosphate rock feed (0.012 lb/ton), orb. Exhibit greater than zero percent opacity.5. From any ground phosphate rock handling and storage system any gases which exhibit greater than zero percent opacity.(4) MONITORING OF EMISSIONS AND OPERATIONS. (a) Any owner or operator subject to the provisions of this section shall install, calibrate, maintain and operate a continuous monitoring system, except as provided in pars. (b) and (c), to monitor and record the opacity of the gases discharged into the atmosphere from any phosphate rock dryer, calciner or grinder. The span of this system shall be set at 40% opacity.(b) For ground phosphate rock storage and handling systems, continuous monitoring systems for measuring opacity are not required.(c) The owner or operator of any affected phosphate rock facility using a wet scrubbing emission control device will not be subject to the requirements in par. (a), but shall install, calibrate, maintain and operate the following continuous monitoring devices: 1. A monitoring device for the continuous measurement of the pressure loss of the gas stream through the scrubber. The monitoring device shall be certified by the manufacturer to be accurate within "250 pascals ("one inch water) gauge pressure.2. A monitoring device for the continuous measurement of the scrubbing liquid supply pressure to the control device. The monitoring device shall be accurate within " 5% of design scrubbing liquid supply pressure.(d) For the purpose of conducting a performance test under s. NR 440.08, the owner or operator of any phosphate rock plant subject to the provisions of this section shall install, calibrate, maintain and operate a device for measuring the phosphate rock feed to any affected dryer, calciner or grinder. The measuring device used shall be accurate to within " 5% of the mass rate over its operating range.(e) For the purpose of reports required under s. NR 440.07(3), periods of excess emissions that shall be reported are defined as all 6-minute periods during which the average opacity of the plume from any phosphate rock dryer, calciner or grinder subject to par. (a) exceeds the applicable opacity limit. (f) Any owner or operator subject to the requirements under par. (c) shall report on a frequency specified in s. NR 440.07(3) all measurement results that are less than 90% of the average levels maintained during the most recent performance test conducted under s. NR 440.08 in which the affected facility demonstrated compliance with the standard under sub. (3).(5) TEST METHODS AND PROCEDURES. (a) In conducting the performance tests required in s. NR 440.08, the owner or operator shall use as reference methods and procedures the test methods in Appendix A of 40 CFR part 60, incorporated by reference in s. NR 440.17, or other methods and procedures as specified in this subsection, except as provided for in s. NR 440.08(2).(b) The owner or operator shall determine compliance with the particulate matter standards in sub. (3) as follows: 1. The emission rate (E) of particulate matter shall be computed for each run using the following equation: See PDF for diagram
where:
E is the emission rate of particulate matter kg/Mg (lb/ton) of phosphate rock feed
cs is the concentration of particulate matter, g/dscm (g/dscf)
Qsd is the volumetric flow rate of effluent gas, dscm/hr (dscf/hr)
P is the phosphate rock feed rate, Mg/hr (ton/hr)
K is the conversion factor, 1000 g/kg (453.6 g/lb)
2. Method 5 shall be used to determine the particulate matter concentration (cs) and volumetric flow rate (Qsd) of the effluent gas. The sampling time and sample volume for each run shall be at least 60 minutes and 0.85 dscm (30 dscf).3. The device of sub. (4) (d) shall be used to determine the phosphate rock feed rate (P) for each run.4. Method 9 and the procedures in s. NR 440.11 shall be used to determine opacity.(c) To comply with sub. (4) (f), if applicable, the owner or operator shall use the monitoring devices in sub. (4) (c) 1. and 2. to determine the average pressure loss of the gas stream through the scrubber and the average scrubbing supply pressure during the particulate matter runs.Wis. Admin. Code Department of Natural Resources NR 440.54
Cr. Register, January, 1984, No. 337, eff. 2-1-84; am. (2) (intro.) and (3) (a) 1. a., Register, September, 1990, No. 417, eff. 10-1-90; r. and recr. (5), Register, July, 1993, No. 451, eff. 8-1-93; CR 06-109: am. (4) (f) Register May 2008 No. 629, eff. 6-1-08.