(Note: All references to ASTM in this chapter refers to the American Society for Testing Materials. Copies of methods are available for purchase by writing to ASTM, 1916 Race Street, Philadelphia, PA 19103 or by writing to the Tennessee Division of Air Pollution Control, 701 Broadway, 4th Floor Customs House, Nashville, TN 37219. Be sure and specify which method is desired).
Sample and velocity traverses shall be determined by Method 1 outlined in the Federal Register, Vol. 42, No. 160, August 18, 1977, beginning on page 41755, as amended in the Federal Register, Vol. 43, No. 57, March 23, 1978, on page 11984, and as amended in the Federal Register, Vol. 48, No. 191, September 30, 1983, beginning on page 45035, and as amended in the Federal Register, Vol. 51, No. 107, June 4, 1986, beginning on page 20288, and as amended in the Federal Register, Vol. 51, No. 157, August 14, 1986, on page 29104.
Stack gas velocity and volumetric flow rate shall be determined with a type S pitot tube by Method 2 outlined in the Federal Register, Vol. 42, No. 160, August 18, 1977, beginning on page 41758, and as amended in the Federal Register, Vol. 43, No. 57, March 23, 1978, on page 11984, or by one of the following alternative methods:
Gas volume through pipes and small ducts shall be determined by direct measurement by Method 2A outlined in the Federal Register, Vol. 48, No. 161, August 18, 1983, beginning on page 37592.
Exhaust gas volume flow rate from gasoline vapor incinerators shall be determined by Method 2B outlined in the Federal Register, Vol. 48, No. 161, August 18, 1983, beginning on page 37594.
Oxygen and carbon dioxide concentrations in emissions from stationary sources shall be determined by an instrument analyzer procedure by Method 3A outlined in the Federal Register, Vol. 49, No. 248, December 24, 1984, beginning on page 49964, as amended in the Federal Register, Vol. 51, No. 112, June 11, 1986, beginning on page 21166.
Moisture content in stack gases shall be determined by Method 4 outlined in the Federal Register, Vol. 42, No. 160, August 18, 1977, beginning on page 41771, as amended in the Federal Register, Vol. 43, No. 57, March 23, 1978, beginning on page 11984, and as amended in the Federal Register, Vol. 48, No. 241, December 14, 1983, on page 55671.
Particulate emissions from stationary sources shall be determined by Method 5 outlined in the Federal Register, Vol. 42, No. 160, August 18, 1977, beginning on page 41776, as amended in the Federal Register, Vol. 43, No. 57, March 23, 1978, on page 11985, as amended in the Federal Register, Vol. 45, No. 196, October 7, 1980, on page 66752, as amended in the Federal Register, Vol. 48, No. 167, August 26, 1983, beginning on page 39011, as amended in the Federal Register, Vol. 48, No. 241, December 14, 1983, on page 55671, and as amended in the Federal Register, Vol. 50, No. 6, January 9, 1985, beginning on page 1165; or by one of the following alternative methods:
Particulate Emissions from the asphalt processing and asphalt roofing industry shall be determined by Method 5A outlined in the Federal Register, Vol. 47, No. 153, August 6, 1982, beginning on page 34145, and as amended in the Federal Register, Vol. 51, No. 177, September 12, 1986 on page 32455.
Particulate Matter from Stationary Sources. Particulate matter emissions from Nonsulfuric Acid from stationary sources shall be determined by Method 5B outlined in the Federal Register, Vol. 51, No. 228, November 26, 1986, beginning on page 42842.
Particulate matter emissions from positive pressure fabric filters shall be determined by Method 5D outlined in the Federal Register, Vol. 49, No. 212, October 31, 1984, beginning on page 43847, and as amended in the Federal Register, Vol. 51, No. 177, September 12, 1986, on page 32455.
Particulate emission from the wool fiberglass insulation manufacturing industry shall be determined by Method 5E outlined in the Federal Register, Vol. 50, No. 37, February 25, 1985, beginning on page 7701.
Non-sulfate particulate matter from stationary sources shall be determined by Method 5F outlined in the Federal Register, Vol. 51, No. 228, November 26, 1986, on page 42842.
Sulfur dioxide emissions from stationary sources shall be determined by Method 6 outlined in the Federal Register, Vol. 42, No. 160, August 18, 1977, beginning on page 41783, as amended in the Federal Register, Vol. 43, No. 57, March 23, 1978, on page 11985, as amended in the Federal Register, Vol. 48, No. 167, August 26, 1983, on page 39013, and as amended in the Federal Register, Vol. 49, No. 125, June 27, 1984, on page 26524, or by one of the following alternative methods:
Sulfur dioxide, moisture, and carbon dioxide emissions from fossil fuel combustion sources shall be determined by Method 6A outlined in the Federal Register, Vol. 47, No. 231, December 1, 1982, beginning on page 54079, and as amended in the Federal Register, Vol. 49, No. 51, March 14, 1984, beginning on page 9684, and as amended in the Federal Register, Vol. 51, No. 177, September 12, 1986, on page 32455.
Sulfur dioxide and carbon dioxide daily average emissions from fossil fuel combustion sources shall be determined by Method 6B outlined in the Federal Register, Vol. 47, No. 231, December 1, 1982, beginning on page 54079, and as amended in the Federal Register, Vol. 49, No. 51, March 14, 1984, beginning on page 9685, and as amended in the Federal Register, Vol. 51, No. 177, September 12, 1986, beginning on page 32455.
Sulfur dioxide emissions from stationary source shall be determined by an instrumental analyzer procedure by Method 6C outlined in the Federal Register, Vol. 49, No. 248, December 24, 1984, beginning on page 49965, and as amended in the Federal Register, Vol. 51, No. 112, June 11, 1986, beginning on page 21167.
Nitrogen oxide emissions from stationary sources shall be determined by Method 7 outline in the Federal Register, Vol. 42, No. 160, August 18, 1977, as amended in the Federal Register, Vol. 43, No. 57, March 23, 1978, beginning on page 11985, and as amended in the Federal Register, Vol. 49, No. 125, June 27, 1984, beginning on page 26524, or by one of the following alternative methods:
Nitrogen oxide emissions from stationary sources shall be determined by an ion chromatographic method by Method 7A outlined in the Federal Register, Vol. 48, No. 237, December 8, 1983, beginning on page 55073.
Nitrogen oxide emissions from stationary sources shall be determined by an ultraviolet spectrophotometric method by Method 7B outlined in the Federal Register, Vol. 50, No. 78, April 23, 1985, beginning on page 15894.
Nitrogen oxide emissions from stationary sources shall be determined by an alkaline-permanganate/colormetric method by Method 7C outlined in the Federal Register, Vol. 49, No. 189, September 27, 1984, beginning on page 38234.
Nitrogen oxide emissions from stationary sources shall be determined by alkaline-permanganate/ion chromatographic method by Method 7D outlined in the Federal Register, Vol. 49, No. 189, September 27, 1984, beginning on page 38237.
Nitrogen oxides emissions from stationary sources shall be determined by an instrumental analyzer procedure by Method 7E outlined in the Federal Register, Vol. 49, No. 248, December 24, 1984, beginning on page 49971, and as amended in the Federal Register, Vol. 51, No. 112, June 11, 1986, beginning on page 21171.
Sulfuric acid mist and sulfur dioxide emissions from stationary sources shall be determined by Method 8 outlined in the Federal Register, Vol. 42, No. 160, August 18, 1977, beginning on page 41786, and as amended in the Federal Register, Vol. 43, No. 57, March 25, 1978, on page 11986.
The opacity of emissions from stationary sources shall be determined either visually by Method 9 outlined in the Federal Register, Vol. 39, No. 219, November 12, 1974, beginning on page 39874, or by the following alternative methods:
The opacity of emissions from stationary sources shall be determined remotely by a mobile lidar system (laser radar; Light Detection and Ranging) by Alternate Method 1 to Method 9 outlined in the Federal Register, Vol. 46, No. 208, October 28, 1981, beginning on page 53144, and as amended in the Federal Register, Vol. 47, No. 127, July 1, 1982, beginning on page 28624.
Carbon monoxide emissions from stationary sources shall be determined by Method 10 outlined in the Federal Register, Vol. 39, No. 47, March 8, 1974, beginning on page 9319.
Hydrogen sulfide content of fuel gas streams in petroleum refineries shall be determined by Method 11 outlined in the Federal Register, Vol. 43, No. 6, January 10, 1978, beginning on page 1494.
Inorganic lead emissions from stationary sources shall be determined by Method 12 outlined in the Federal Register, Vol. 47, No. 74, April 16, 1982, beginning on page 16564, as amended in the Federal Register, Vol. 49, No. 166, August 24, 1984, beginning on page 33842, and as amended in the Federal Register, Vol. 49, No. 186, September 24, 1984, on page 37384.
Total fluoride emissions from stationary sources shall be determined by either one of the following methods:
Total fluoride emissions from stationary sources shall be determined by the SPADNS Zirconium Lake method by Method 13A outlined in the Federal Register, Vol. 45, No. 121, June 20, 1980, beginning on page 41852, and as amended in the Federal Register, Vol. 45, No. 249, December 24, 1980, on page 85016, or
Total Fluoride emissions from stationary sources shall be determined by the specific ion electrode method by Method 13B outlined in the Federal Register, Vol. 45, No. 121, June 20, 1980, beginning on page 41852, and as amended in the Federal Register, Vol. 45, No. 249, December 24, 1980, on page 85016.
Fluoride emissions from potroom roof monitors for primary aluminum plants shall be determined by Method 14 outlined in the Federal Register, Vol. 45, No. 127, June 30, 1980, beginning on page 44202.
Hydrogen sulfide, carbonyl sulfide, and carbon disulfide emissions from stationary sources shall be determined by either Method 15 outlined in the Federal Register, Vol. 43, No. 51, March 15, 1978, beginning on page 10866, or by the following alternative method:
Nonsulfate particulate matter emissions from stationary sources shall be determined by Method 5F outlined in the Federal Register, Vol. 51, No. 228, November 26, 1986, beginning on page 42842.
Sulfur emissions from stationary sources shall be determined by either a semicontinuous procedure by Method 16 outlined in the Federal Register, Vol. 43, No. 37, February 23, 1978 beginning on page 7575, as amended in the Federal Register, Vol. 43, No. 152, August 7, 1978, beginning on page 34785, and as amended in the Federal Register, Vol. 44, No. 9, January 12, 1979, beginning on page 2579, or by the following alternative method:
Total reduced sulfur emissions from stationary sources shall be determined by an impinger technique by Method 16A outlined in the Federal Register, Vol. 50, No. 46, March 8, 1985, beginning on page 9597.
Particulate emissions from stationary sources shall be determined by an in-stack filtration method by Method 17 outlined in the Federal Register, Vol. 43, No. 37, February 23, 1978, beginning on page 7568.
Gaseous organic compound emissions shall be determined by gas chromatography by Method 18 outlined in the Federal Register, Vol. 48, No. 202, October 18, 1983, beginning on page 48344, and as amended in the Federal Register, Vol. 49, No. 105, May 30, 1984, on page 22608, and as amended in the Federal Register, Vol. 52, No. 33, February 19, 1987 beginning on page 5105.
Sulfur dioxide removal efficiency and particulate, sulfur dioxide, and nitrogen oxides emission rates from electric utility steam generators shall be determined by Method 19 outlined in the Federal Register, Vol. 44, No. 113, June 11, 1979, beginning on page 33580, and as amended in the Federal Register, Vol. 48, No. 207, October 25, 1983, on page 49460.
Nitrogen oxides, sulfur dioxide, and oxygen emissions from stationary gas turbines shall be determined by Method 20 outlined in the Federal Register, Vol. 44, No. 176, September 10, 1979, beginning on page 52792, and as amended in the Federal Register, Vol. 47, No. 135, July 14, 1982, beginning on page 30480, and as amended in the Federal Register, Vol. 51, No. 177, September 12, 1986, beginning on page 32456.
Volatile organic compound leaks shall be determined by Method 21 outlined in the Federal Register, Vol. 48, No. 161, August 18, 1983, beginning on page 37600, and as amended in the Federal Register, Vol. 48, No. 247, December 22, 1983, beginning on page 56580.
Fugitive emissions from material sources and smoke emissions from flares shall be determined by Method 22 outlined in the Federal Register, vol. 47, No. 152, August 5, 1982, beginning on page 84146, and as amended in the Federal Register, Vol. 48, No. 202, October 18, 1983, beginning on page 48360.
Volatile matter content, water content, density, volume solids, and weight solids of surface coatings shall be determined by either Method 24 outlined in the Federal Register, Vol. 45, No. 194, October 3, 1980, beginning on page 65958, or by the following alternative method:
Volatile matter content and density of printing inks and related coatings shall be determined by Method 24A outlined in the Federal Register, Vol. 47, No. 216, November 8, 1982, on page 50655, and as amended in the Federal Register, Vol. 48, No. 6, January 10, 1983, on page 1056.
Total gaseous nonmethane organic emissions shall be determined as carbon by Method 25 outlined in the Federal Register, Vol. 45, No. 194, October 3, 1980, beginning on page 65959, or by one of the following alternative methods:
Total gaseous organic concentration shall be determined using a flame ionization analyzer by Method 25A outlined in the Federal Register, Vol. 48, No. 161, August 18, 1983, beginning on page 37595.
Total gaseous organic concentration shall be determined using a nondispersive infrared analyzer by Method 25B outlined in the Federal Register, Vol. 48, No. 161, August 18, 1983, on page 37597.
The gases may be analyzed at less frequent intervals if longer shelf lives are guaranteed by the manufacturer.
This paragraph contains requirements for control devices used to comply with applicable rules of Chapter 0400-30-38 and this chapter. The requirements are placed here for administrative convenience and only apply to facilities covered by rules referring to this paragraph.
Subparagraphs (c) through (f) of this paragraph apply to flares.
Where:
HT = Net heating value of the sample, MJ/scm; where the net enthalpy per mole of offgas is based on combustion at 25°C and 760 mm Hg, but the standard temperature for determining the volume corresponding to one mole is 20°C;
n = Number of components in the sample;
Ci = Concentration of sample component i in ppm on a wet basis, as measured for organics by Reference Method 18 (as specified in rule 1200-03-16-.01(5)(g) 18.) and measured for hydrogen and carbon monoxide by ASTM D1946-77; and
Hi = Net heat of combustion of sample component i, kcal/g mole at 25°C and 760 mm Hg. The heat of combustion may be determined using ASTM D2382-76 if published values are not available or cannot be calculated.
(Note: All references to ASTM in this rule refers to the American Society for Testing Materials. Copies of methods are available for purchase by writing to ASTM, 1916 Race Street, Philadelphia, PA 19103 or by writing to the Tennessee Division of Air Pollution Control, 701 Broadway, 4th Floor Customs House, Nashville, TN 37219. Be sure and specify which method is desired).
Log10 (Vmax) = (HT + 28.8)/31.7
Vmax = Maximum permitted velocity, M/sec
28.8 = Constant
31.7 = Constant
HT = The net heating value as determined in part (f)3.
Vmax = Maximum permitted velocity, m/sec
8.706 = Constant
0.7084 = Constant
HT = The net heating value as determined in part (f)3 of his paragraph.
Tenn. Comp. R. & Regs. 1200-03-16-.01
Authority: T.C.A. §§ 4-5-201, et seq.; 4-5-202; 68-25-105; and 68-201-101, et seq.