The requirements also contain analytical method requirements and monitoring requirements referenced in 41.5(1)"b" and"c." Best available technology (BAT) for control of these organic contaminants is referenced in 567-paragraph 43.3(10)"a. "
ORGANIC CHEMICAL CONTAMINANTS, CODES, MCLS, ANALYTICAL METHODS, AND DETECTION LIMITS
Contaminant | EPA Contaminant Code | MCL (mg/L) | Methodology1 | Detection Limit (mg/L) |
Volatile Organic Chemicals (VOCs): | ||||
Benzene | 2990 | 0.005 | 502.2, 524.2, 524.3, 524.47 | 0.0005 |
Carbon tetrachloride | 2982 | 0.005 | 502.2, 524.2, 524.3, 524.47, 551.1 | 0.0005 |
Chlorobenzene (mono) | 2989 | 0.1 | 502.2, 524.2, 524.3, 524.47 | 0.0005 |
1,2-Dichlorobenzene (ortho) | 2968 | 0.6 | 502.2, 524.2, 524.3, 524.47 | 0.0005 |
1,4-Dichlorobenzene (para) | 2969 | 0.075 | 502.2, 524.2, 524.3, 524.47 | 0.0005 |
1,2-Dichloroethane | 2980 | 0.005 | 502.2, 524.2, 524.3, 524.47 | 0.0005 |
1,1-Dichloroethylene | 2977 | 0.007 | 502.2, 524.2, 524.3, 524.47 | 0.0005 |
cis- 1,2-Dichloroethylene | 2380 | 0.07 | 502.2, 524.2,524.3, 524.47 | 0.0005 |
trans-1,2-Dichloroethylene | 2979 | 0.1 | 502.2, 524.2,524.3, 524.47 | 0.0005 |
Dichloromethane | 2964 | 0.005 | 502.2, 524.2, 524.3, 524.47 | 0.0005 |
1,2-Dichloropropane | 2983* | 0.005 | 502.2, 524.2,524.3, 524.47 | 0.0005 |
Ethylbenzene | 2992 | 0.7 | 502.2, 524.2,524.3, 524.47 | 0.0005 |
Styrene | 2996 | 0.1 | 502.2, 524.2, 524.3, 524.47 | 0.0005 |
Tetrachloroethylene | 2987 | 0.005 | 502.2, 524.2, 524.3,524.47, 551.1 | 0.0005 |
Toluene | 2991 | 1 | 502.2, 524.2,524.3, 524.47 | 0.0005 |
1,1,1-Trichloroethane | 2981 | 0.2 | 502.2, 524.2, 524.3, 524.47, 551.1 | 0.0005 |
Trichloroethylene | 2984 | 0.005 | 502.2, 524.2, 524.3, 524.47, 551.1 | 0.0005 |
1,2,4-Trichlorobenzene | 2378 | 0.07 | 502.2, 524.2, 524.3, 524.47 | 0.0005 |
1,1,2-Trichloroethane | 2985 | 0.005 | 502.2, 524.2, 524.3, 524.47, 551.1 | 0.0005 |
Vinyl chloride | 2976 | 0.002 | 502.2, 524.2, 524.3, 524.47 | 0.0005 |
Xylenes (total) | 2955* | 10 | 502.2, 524.2, 524.3, 524.47 | 0.0005 |
Synthetic Organic Chemicals (SOCs): | ||||
Alachlor3 | 2051 | 0.002 | 505, 507, 508.1, 525.2, 525.3,551.1 | 0.0002 |
Aldicarb | 2047 | 0.003 | 531.1,6610 | 0.0005 |
Aldicarb sulfone | 2044 | 0.002 | 531.1,6610 | 0.0008 |
Aldicarb sulfoxide | 2043 | 0.004 | 531.1,6610 | 0.0005 |
Atrazine3 | 2050 | 0.003 | 505, 507, 508.1, 523, 525.2,525.3,536,551.1, Syngenta AG-6255 | 0.0001 |
Benzo(a)pyrene | 2306 | 0.0002 | 525.2,525.3,550,550.1 | 0.00002 |
Carbofuran | 2046 | 0.04 | 531.1, 531.2, 6610, 6610B, 6610 B-042 | 0.0009 |
Chlordane3 | 2959 | 0.002 | 505, 508, 508.1, 525.2, 525.3 | 0.0002 |
2,4-D6(as acids, salts, and esters) | 2105 | 0.07 | 515.1, 515.2, 515.3, 515.4, 555, D5317-93, 98 (Reapproved 2003), 6610B, 6640-B, 6640 B-01, 6640 B-06 | 0.0001 |
Dalapon | 2031 | 0.2 | 515.1, 515.3, 515.4, 552.1,552.2,552.3,557, 6640, 6610B, 6640-B, 6640 B-01, 6640 B-06 | 0.001 |
1,2-Dibromo-3-chloropropane (DBCP) | 2931 | 0.0002 | 504.1,524.3, 551.1 | 0.00002 |
Di(2-ethylhexyl)adipate | 2035 | 0.4 | 506, 525.2, 525.3 | 0.0006 |
Di(2-ethylhexyl)phthalate | 2039 | 0.006 | 506, 525.2, 525.3 | 0.0006 |
Dinoseb6 | 2041 | 0.007 | 515.1, 515.2, 515.3, 515.4, 555, 6610B, 6640-B, 6640 B-01, 6640 B-06 | 0.0002 |
Diquat | 2032 | 0.02 | 549.2 | 0.0004 |
Endothall | 2033 | 0.1 | 548.1 | 0.009 |
Endrin3 | 2005 | 0.002 | 505, 508, 508.1, 525.2, 525.3,551.1 | 0.00001 |
Ethylene dibromide (EDB) | 2946 | 0.00005 | 504.1,524.3, 551.1 | 0.00001 |
Glyphosate | 2034 | 0.7 | 547, 6651, 6651B, 6651 B-00, 6640 B-05 | 0.006 |
Heptachlor3 | 2065 | 0.0004 | 505, 508, 508.1, 525.2, 525.3,551.1 | 0.00004 |
Heptachlor epoxide3 | 2067 | 0.0002 | 505, 508, 508.1, 525.2, 525.3,551.1 | 0.00002 |
Hexachlorobenzene3 | 2274 | 0.001 | 505, 508, 508.1, 525.2, 525.3,551.1 | 0.0001 |
Hexachlorocyclopentadiene3 | 2042 | 0.05 | 505, 508, 508.1, 525.2, 525.3,551.1 | 0.0001 |
Lindane (gamma BHC)3 | 2010 | 0.0002 | 505, 508, 508.1, 525.2, 525.3,551.1 | 0.00002 |
Methoxychlor3 | 2015 | 0.04 | 505, 508, 508.1, 525.2, 525.3,551.1 | 0.0001 |
Oxamyl | 2036 | 0.2 | 531.1, 531.2, 6610, 6610B, 6610 B-042 | 0.002 |
Pentachlorophenol | 2326 | 0.001 | 515.1, 515.2, 515.3, 515.4, 525.2, 525.3, 555, D5317-93, 98 (Reapproved 2003), 6610B, 6640-B, 6640 B-01, 6640 B-06 | 0.00004 |
Picloram3. 6 | 2040 | 0.5 | 515.1, 515.2, 515.3, 515.4, 555, D5317-93, 98 (Reapproved 2003), 6610B, 6640-B, 6640 B-01, 6640 B-06 | 0.0001 |
Polychlorinated biphenyls4 (as decachlorobiphenyl) (as Arochlors)3 | 2383 | 0.0005 | 508A 505, 508, 508.1, 525.2, 525.3 | 0.0001 |
Simazine3 | 2037 | 0.004 | 505, 507, 508.1, 523, 525.2,525.3,536,551.1 | 0.00007 |
2,3,7,8-TCDD (dioxin) | 2063 | 3xl0-8 | 1613 | 5xl0"9 |
2,4,5-TP6(Silvex) | 2110 | 0.05 | 515.1, 515.2, 515.3, 515.4, 555, D5317-93, 98 (Reapproved 2003), 6610B, 6640-B, 6640 B-01, 6640 B-06 | 0.0002 |
Toxaphene3 | 2020 | 0.003 | 505, 508, 508.1, 525.2, 525.3 | 0.001 |
*As of January 1, 1999, the contaminant codes for the following compounds were changed from the Iowa Contaminant Code to the EPA Contaminant Code:
Contaminant | Iowa Contaminant Code (Old) | EPA Contaminant Code (New) |
1,2 Dichloropropane | 2325 | 2983 |
Xylenes (total) | 2974 | 2955 |
1Analyses for the contaminants in this section shall be conducted using the following EPA methods or their equivalent as approved by EPA. This incorporation by reference was approved by the Director of the Federal Register in accordance with 5 U.S.C. 552(a) and 1 CFR Part 51. Copies may be inspected at EPAs Drinking Water Docket, EPA West, 1301 Constitution Avenue, NW, Room 3334, Washington, DC 20460 (telephone: (202)566-2426); or at the National Archives and Records Administration (NARA). For information on the availability of this material at NARA, call (202)741-6030, or via Internet at www.archives.gov/federalregister/code_of federal_regulations/ibr_locations.html.
The following methods are available from the National Technical Information Service, U.S. Department of Commerce, 5285 Port Royal Road, Springfield, VA 22161 (telephone: (800)553-6847).
Methods for the Determination of Organic Compounds in Drinking Water, EPA-600/4-88-039, December 1988, Revised July 1991 (NTIS PB91-231480): Methods 508A and 515.1.
Methods for the Determination of Organic Compounds in Drinking Water-Supplement I, EPA-600/4-90-020, July 1990 (NTIS PB91-146027): Methods 547, 550, 550.1.
Methods for the Determination of Organic Compounds in Drinking Water-Supplement II, EPA-600/R-92-129, August 1992 (NTIS PB92-207703): Methods 548.1, 552.1, 555.
Methods for the Determination of Organic Compounds in Drinking Water-Supplement III, EPA-600/R-95-131, August 1995 (NTIS PB95-261616): Methods 502.2, 504.1, 505, 506, 507, 508, 508.1, 515.2, 524.2, 525.2, 531.1, 551.1, 552.2.
EPA Method 523, "Determination of Triazine Pesticides and Their Degradates in Drinking Water by Gas Chromatography/Mass Spectrometry (GC/MS)," 2011. EPA-815-R-11-002. Available at www.nepis.epa.gov .
EPA Method 524.3, Version 1.0. "Measurement of Purgeable Organic Compounds in Water by Capillary Column Gas Chromatography/Mass Spectrometry," June 2009. EPA 815-B-09-009. Available at www.nemi.gov .
EPA Method 525.3, "Determination of Semivolatile Organic Chemicals in Drinking Water by Solid Phase Extraction and Capillary Column Gas Chromatograph/Mass Spectrometry (GC/MS)," 2012. EPA/600/R-12-010. Available at www.nepis.epa.gov .
EPA Method 536, "Determination of Triazine Pesticides and Their Degradates in Drinking Water by Liquid Chromatography Electrospray Ionization Tandem Mass Spectrometry (LC/ESI-MS/MS)," 2007. EPA/815-B-07-002. Available at www.nepis.epa.gov .
EPA Method 557, "Determination of Haloacetic Acids, Bromate, and Dalapon in Drinking Water by Ion Chromatography Electrospray Ionization Tandem Mass Spectrometry (IC-ESI-MS/MS)," September 2009. EPA 815-B-09-012. Available at www.nemi.gov .
Method 1613 "Tetra-through Octa-Chlorinated Dioxins and Furans by Isotope-Dilution HRGC/HRMS," EPA-821-B-94-005, October 1994 (NTIS PB95-104774).
The following American Public Health Association (APHA) documents are available from APHA, 800 I Street, NW, Washington, DC 20001-3710.
Supplement to the 18th Edition of Standard Methods for the Examination of Water and Wastewater, 1994, Standard Methods for the Examination of Water and Wastewater, 19th edition, 1995, 20th edition, 1998, 21st edition, 2005, or 22nd edition, 2012 (any of these editions may be used), APHA: Method 6610 and (carbofuran and oxamyl only) 6610B and 6610 B-04; Method 6640B (21st and 22nd editions only) and SM online 6640 B-01 for 2,4-D, 2,4,5-TP Silvex, dalapon, dinoseb, pentachlorophenol, and picloram; Method 6651B (21st and 22nd editions only) and SM online 6670-B-00 for glyphosate.
Standard Methods for the Examination of Water and Wastewater, 18th edition, 1992, 19th edition, 1995, or 20th edition, 1998, (any of these editions may be used), APHA: Method 6651.
The following American Society for Testing and Materials (ASTM) method is available from ASTM International, 100 Barr Harbor Drive, West Conshohocken, PA 19428.
Annual book of ASTM Standards, 1999, Vol. 11.02 (or any edition published after 1993), ASTM: D5317-93, 98 (Reapproved 2003).
Methods 515.3 and 549.2 are available from U.S. EPA NERL, 26 W. Martin Luther King Drive, Cincinnati, OH 45268.
Method 515.4, "Determination of Chlorinated Acids in Drinking Water by Liquid-Liquid Microextraction, Derivatization and Fast Gas Chromatography with Electron Capture Detection," Revision 1.0, April 2000, EPA 815/B-00/001 and EPA Method 552.3, "Determination of Haloacetic Acids and Dalapon in Drinking Water by Liquid-liquid Microextraction, Derivatization, and Gas Chromatography with Electron Capture Detection," Revision 1.0, July 2003, EPA 815-B-03-002, available at www.epa.gov/safewater/methods/sourcalt.html .
Method 531.2, "Measurement of n-Methylcarbamoyloximes and n-Methylcarbamates in Water by Direct Aqueous Injection HPLC with Postcolumn Derivatization," Revision 1.0, September 2001, EPA 815/B-01/002, available at www.epa.gov/safewater/methods/sourcalt.html .
Syngenta AG-625 Method, "Atrazine in Drinking Water by Immunoassay," February 2001, is available from Syngenta Crop Protection, Inc., 410 Swing Road, P.O. Box 18300, Greensboro, NC 27419, telephone (336)632-6000.
Other required analytical test procedures germane to the conduct of these analyses are contained in Technical Notes on Drinking Water Methods, EPA-600/R-94-173, October 1994 (NTIS PB95-104766).
2Standard Methods Online is available at www.standardmethods.org. The year in which each method was approved by the Standard Methods Committee is designated by the last two digits in the method number. The methods listed are the only online versions that may be used.
3Substitution of the detector specified in Method 505, 507, 508, or 508.1 for the purpose of achieving lower detection limits is allowed as follows. Either an electron capture or nitrogen-phosphorus detector may be used provided all regulatory requirements and quality control criteria are met.
4PCBs are qualitatively identified as Aroclors and measured for compliance purposes as decachlorobiphenyl. Users of Method 505 may have more difficulty in achieving the required detection limits than users of Method 508. 508.1, or 525.2.
5This method may not be used for the analysis of atrazine in any system where chlorine dioxide is used in the drinking water treatment. In samples from all other systems, any result for atrazine generated by Method AG-625 that is greater than one-half the MCL (i.e., greater than 0.0015 mg/L) must be confirmed using another approved method for this contaminant and should use additional volume of the original sample collected for compliance monitoring. In instances where a result from Method AG-625 triggers such confirmatory testing, the confirmatory result is to be used to determine compliance.
6Accurate determination of the chlorinated esters requires hydrolysis of the sample as described in EPA Methods 515.1, 515.2, 515.3, 515.4, and 555, and ASTM Method D5317-93, 98 (Reapproved 2003).
7EPA Method 524.4, Version 1.0. "Measurement of Purgeable Organic Compounds in Water by Gas Chromatography/Mass Spectrometry Using Nitrogen Purge Gas," May 2013, EPA 815-R-13-002.
Acrylamide = 0.05% dosed at 1 ppm (or equivalent)
Epichlorohydrin = 0.01% dosed at 20 ppm (or equivalent) Certifications can rely on information provided by manufacturers or third parties, as approved by the department.
* Previous analytical results.
* The proximity of the system to a potential point or nonpoint source of contamination. Point sources include spills and leaks of chemicals at or near a water treatment facility or at manufacturing, distribution, or storage facilities, or from hazardous and municipal waste landfills and other waste handling or treatment facilities.
* The environmental persistence and transport of the contaminants.
* The number of persons served by the public water system and the proximity of a smaller system to a larger system, and
* How well the water source is protected against contamination, such as whether it is a surface or groundwater system. Groundwater systems must consider factors such as depth of the well, the type of soil, and wellhead protection. Surface water systems must consider watershed protection.
The system must monitor quarterly at each sampling point which resulted in a detection.
The department may decrease the quarterly monitoring requirement specified in 41.5(1) "c "(2)"4" provided it has determined that the system is reliably and consistently below the maximum contaminant level. In no case shall the department make this determination unless a groundwater system takes a minimum of two quarterly samples and a surface water system takes a minimum of four quarterly samples.
If the department determines that the system is reliably and consistently below the MCL, the department may allow the system to monitor annually. Systems which monitor annually must monitor during the quarter(s) which previously yielded the highest analytical result.
Systems which have three consecutive annual samples with no detection of a contaminant may apply to the department for a waiver as specified in 41.5(1) "c "(2)"6."
Groundwater systems which have detected one or more of the following two-carbon organic compounds: trichloroethylene, tetrachloroethylene, 1,2-dichloroethane, 1,1,1-trichloroethane, cis-l,2-dichloroethylene, trans-1,2-dichloroethylene, or 1,1-dichloroethylene shall monitor quarterly for vinyl chloride. A vinyl chloride sample shall be taken at each sampling point at which one or more of the two-carbon organic compounds was detected. If the results of the first analysis do not detect vinyl chloride, the department may reduce the quarterly monitoring frequency of vinyl chloride monitoring to one sample during each compliance period. Surface water systems are required to monitor for vinyl chloride as specified by the department.
* Previous analytical results.
* The proximity of the system to a potential point or nonpoint source of contamination. Point sources include spills and leaks of chemicals at or near a water treatment facility or at manufacturing, distribution, or storage facilities, or from hazardous and municipal waste landfills and other waste handling or treatment facilities. Nonpoint sources include the use of pesticides to control insect and weed pests on agricultural areas, forest lands, home and gardens, and other land application uses.
* The environmental persistence and transport of the pesticide or PCBs.
* How well the water source is protected against contamination due to such factors as depth of the well and the type of soil and the integrity of the well casing.
* Elevated nitrate levels at the water supply source, and
* Use of PCBs in equipment used in the production, storage, or distribution of water (i.e., PCBs used in pumps and transformers).
* Each system must monitor quarterly at each sampling point which resulted in a detection.
* The department may decrease the quarterly SOC monitoring requirement if the system is reliably and consistently below the maximum contaminant level. In no case shall the department make this determination unless a groundwater system takes a minimum of two quarterly samples and a surface water system takes a minimum of four quarterly samples.
* After the department determines the system is reliably and consistently below the maximum contaminant level, the system may monitor annually. Systems which monitor annually must monitor during the quarter that previously yielded the highest analytical result.
* Systems which have three consecutive annual samples with no detection of a contaminant may apply to the department for a waiver as specified in 41.5(1) "c "(3)"6."
* If monitoring results in detection of one or more of certain related contaminants (aldicarb, aldicarb sulfone, aldicarb sulfoxide, heptachlor, and heptachlor epoxide), then subsequent monitoring shall analyze for all related contaminants.
Sources of Contamination | Shallow Wells as defined in 567-402. (455B) | Deep Wells as defined in 567-402. (455B) |
Sanitary and industrial point discharges | 400 ft | 400 ft |
Mechanical waste treatment plants | 400 ft | 200 ft |
Lagoons | 1,000 ft | 400 ft |
Chemical and mineral storage (aboveground) | 200 ft | 100 ft |
Chemical and mineral storage including underground storage tanks on or below ground | 400 ft | 200 ft |
Solid waste disposal site | 1,000 ft | 1,000 ft |
PCB AROCLOR DETECTION LIMITS
Aroclor | Detection Limit (mg/L) |
1016 | 0.00008 |
1221 | 0.02 |
1232 | 0.0005 |
1242 | 0.0003 |
1248 | 0.0001 |
1254 | 0.0001 |
1260 | 0.0002 |
Iowa Admin. Code r. 567-41.5