Del. Admin. Code tit. 7, 1000, 1300, 1302, pt. 265, Waste Treatment, Storage, and Disposal Facilities, subpt. FF, app V

Current through Reigster Vol. 28, No. 6, December 1, 2024
Appendix V - Examples of Potentially Incompatible Waste

Many hazardous wastes, when mixed with other waste or materials at a hazardous waste facility, can produce effects which are harmful to human health and the environment, such as

(1) heat or pressure,
(2) fire or explosion,
(3) violent reaction,
(4) toxic dusts, mists, fumes, or gases, or
(5) flammable fumes or gases.

Below are examples of potentially incompatible wastes, waste components, and materials, along with the harmful consequences which result from mixing materials in one group with materials in another group. The list is intended as a guide to owners or operators of treatment, storage, and disposal facilities, and to enforcement and permit granting officials, to indicate the need for special precautions when managing these potentially incompatible waste materials or components.

This list is not intended to be exhaustive. An owner or operator must, as the regulations require, adequately analyze his wastes so that he can avoid creating uncontrolled substances or reactions of the type listed below, whether they are listed below or not.

It is possible for potentially incompatible wastes to be mixed in a way that precludes a reaction (e.g., adding acid to water rather than water to acid) or that neutralizes them (e.g., a strong acid mixed with a strong base), or that controls substances produced (e.g., by generating flammable gases in a closed tank equipped so that ignition cannot occur, and burning the gases in an incinerator).

In the lists below, the mixing of a Group A material with a Group B material may have the potential consequence as noted.

Group 1AGroup 1B
Acetylene sludge Alkaline caustic liquids Alkaline cleaner Alkaline corrosive liquids Alkaline corrosive battery fluid Caustic wastewater Lime sludge and other corrosive alkalies Lime wastewater Lime and water Spent caustic Acid sludge Acid and water Battery acid Chemical cleaners Electrolyte, acid Etching acid liquid or solvent Pickling liquor and other corrosive acids Spent acid Spent mixed acid Spent sulfuric acid

Potential consequences: Heat generation; violent reaction.

Group 2AGroup 2B
Aluminum Beryllium Calcium Lithium Magnesium Potassium Sodium Zinc powder Other reactive metals and metal hydrides Any waste in Group 1A or 1B

Potential consequences: Fire or explosion; generation of flammable hydrogen gas.

Group 3AGroup 3B
Alcohols Water Any concentrated waste in Groups 1A or 1B Calcium Lithium Metal hydrides Potassium SO2Cl2, SOCl2, PCl3, CH3SiCl3 Other water-reactive waste

Potential consequences: Fire, explosion, or heat generation; generation of flammable or toxic gases.

Group 4AGroup 4B
Alcohols Aldehydes Halogenated hydrocarbons Nitrated hydrocarbons Unsaturated hydrocarbons Other reactive organic compounds and solvents Concentrated Group 4A or 1B wastes Group 2A wastes

Potential consequences: Fire, explosion, or violent reaction.

Group 5AGroup 5B
Spent cyanide and sulfide solutions Group 1B wastes

Potential consequences: Generation of toxic hydrogen cyanide or hydrogen sulfide gas.

Group 6AGroup 6B
Chlorates Chlorine Chlorites Chromic acid Hyphochlorites Nitrates Nitric acid, fuming Perchlorates Permanganates Peroxides Other strong oxidizers Acetic acid and other organic acids Concentrated mineral acids Group 2A wastes Group 4A wastes Other flammable and combustible wastes

Potential consequences: Fire, explosion, or violent reaction.

Source: "Law, Regulations, and Guidelines for Handling of Hazardous Waste." California Department of Health, February 1975.

Appendix VI to Part 265 - Compounds With Henry's Law Constant Less Than 0.1 Y/X

COMPOUND NAMECAS NUMBER
Acetaldol 107-89-1
Acetamide 60-35-5
2-Acetylaminofluorene 53-96-3
3-Acetyl-5-hydroxypiperidine
3-Acetylpiperidine 618-42-8
1-Acetyl-2-thiourea 591-08-2
Acrylamide 79-06-1
Acrylic acid 79-10-7
Adenine 73-24-5
Adipic acid 124-04-9
Adiponitrile 111-69-3
Alachlor 15972-60-8
Aldicarb 116-06-3
Ametryn 834-12-8
4-Aminobiphenyl 92-67-1
4-Aminopyridine 504-24-5
Aniline 62-53-3
o-Anisidine 90-04-0
Anthraquinone 84-65-1
Atrazine 1912-24-9
Benzenearsonic acid 98-05-5
Benzenesulfonic acid 98-11-3
Benzidine 92-87-5
Benzo(a)anthracene 56-55-3
Benzo(k)fluoranthene 207-08-9
Benzoic acid 65-85-0
Benzo(g,h,i)perylene 191-24-2
Benzo(a)pyrene 50-32-8
Benzyl alcohol 100-51-6
gamma-BHC 58-89-9
Bis(2-ethylhexyl)phthalate 117-81-7
Bromochloromethyl acetate
Bromoxynil 1689-84-5
Butyric acid 107-92-6
Caprolactam (hexahydro-2H-azepin-2-one) 105-60-2
Catechol (o-dihydroxybenzene) 120-80-9
Cellulose 9004-34-6
Cell wall
Chlorhydrin (3-Chloro-1,2-propanediol) 96-24-2
Chloroacetic acid 79-11-8
2-Chloroacetophenone 93-76-5
p-Chloroaniline 106-47-8
p-Chlorobenzophenone 134-85-0
Chlorobenzilate 510-15-6
p-Chloro-m-cresol (6-chloro-m-cresol) 59-50-7
3-Chloro-2,5-diketopyrrolidine
Chloro-1,2-ethane diol
4-Chlorophenol 106-48-9
Chlorophenol polymers (2-chlorophenol & 4-chlorophenol) 95-57-8 & 106-48-9
1-(o-Chlorophenyl)thiourea 5344-82-1
Chrysene 218-01-9
Citric acid 77-92-9
Creosote 8001-58-9
m-Cresol 108-39-4
o-Cresol 95-48-7
p-Cresol 106-44-5
Cresol (mixed isomers) 1319-77-3
4-Cumylphenol 27576-86
Cyanide 57-12-5
4-Cyanomethyl benzoate
Diazinon 333-41-5
Dibenzo(a,h)anthracene 53-70-3
Dibutylphthalate 84-74-2
2,5-Dichloroaniline (N,N'-dichloroaniline) 95-82-9
2,6-Dichlorobenzonitrile11 1194-65-6
2,6-Dichloro-4-nitroaniline 99-30-9
2,5-Dichlorophenol 333-41-5
3,4-Dichlorotetrahydrofuran 3511-19
Dichlorvos (DDVP) 62-73-7
Diethanolamine 111-42-2
N,N-Diethylaniline 91-66-7
Diethylene glycol 111-46-6
Diethylene glycol dimethyl ether (dimethyl Carbitol) 111-96-6
Diethylene glycol monobutyl ether (butyl Carbitol) 112-34-5
Diethylene glycol monoethyl ether acetate (Carbitol acetate) 112-15-2
Diethylene glycol monoethyl ether (Carbitol Cellosolve) 111-90-0
Diethylene glycol monomethyl ether (methyl Carbitol) 111-77-3
N,N'-Diethylhydrazine 1615-80-1
Diethyl (4-methylumbelliferyl) thionophosphate 299-45-6
Diethyl phosphorothioate 126-75-0
N,N'-Diethylpropionamide 15299-99-7
Dimethoate 60-51-5
2,3-Dimethoxystrychnidin-10-one 357-57-3
4-Dimethylaminoazobenzene 60-11-7
7,12-Dimethylbenz(a)anthracene 57-97-6
3,3-Dimethylbenzidine 119-93-7
Dimethylcarbamoyl chloride 79-44-7
Dimethyldisulfide 624-92-0
Dimethylformamide 68-12-2
1,1-Dimethylhydrazine 57-14-7
Dimethylphthalate 131-11-3
Dimethylsulfone 67-71-0
Dimethylsulfoxide 67-68-5
4,6-Dinitro-o-cresol 534-52-1
1,2-Diphenylhydrazine 122-66-7
Dipropylene glycol (1,1'-oxydi-2-propanol) 110-98-5
Endrin 72-20-8
Epinephrine 51-43-4
mono-Ethanolamine 141-43-5
Ethyl carbamate (urethane) 5-17-96
Ethylene glycol 107-21-1
Ethylene glycol monobutyl ether (butyl Cellosolve) 111-76-2
Ethylene glycol monoethyl ether (Cellosolve) 110-80-5
Ethylene glycol monoethyl ether acetate (Cellosolve acetate) 111-15-9
Ethylene glycol monomethyl ether (methyl Cellosolve) 109-86-4
Ethylene glycol monophenyl ether (phenyl Cellosolve) 122-99-6
Ethylene glycol monopropyl ether (propyl Cellosolve) 2807-30-9
Ethylene thiourea (2-imidazolidinethione) 9-6-4-5-7
4-Ethylmorpholine 100-74-3
3-Ethylphenol 620-17-7
Fluoroacetic acid, sodium salt 62-74-8
Formaldehyde 50-00-0
Formamide 75-12-7
Formic acid 64-18-6
Fumaric acid 110-17-8
Glutaric acid 110-94-1
Glycerin (Glycerol) 56-81-5
Glycidol 556-52-5
Glycinamide 598-41-4
Glyphosate 1071-83-6
Guthion 86-50-0
Hexamethylene-1,6-diisocyanate (1,6-diisocyanatohexane) 822-06-0
Hexamethyl phosphoramide 680-31-9
Hexanoic acid 142-62-1
Hydrazine 302-01-2
Hydrocyanic acid 74-90-8
Hydroquinone 123-31-9
Hydroxy-2-propionitrile (hydracrylonitrile) 109-78-4
Indeno (1,2,3-cd) pyrene 193-39-5
Lead acetate 301-04-2
Lead subacetate (lead acetate, monobasic) 1335-32-6
Leucine 61-90-5
Malathion 121-75-5
Maleic acid 110-16-7
Maleic anhydride 108-31-6
Mesityl oxide 141-79-7
Methane sulfonic acid 75-75-2
Methomyl 16752-77-5
p-Methoxyphenol 150-76-5
Methyl acrylate 96-33-3
4,4'-Methylene-bis-(2-chloroaniline) 101-14-4
4,4'-Methylenediphenyl diisocyanate (diphenyl methane diisocyanate) 101-68-8
4,4'-Methylenedianiline 101-77-9
Methylene diphenylamine (MDA)
5-Methylfurfural 620-02-0
Methylhydrazine 60-34-4
Methyliminoacetic acid
Methyl methane sulfonate 66-27-3
1-Methyl-2-methoxyaziridine
Methylparathion 298-00-0
Methyl sulfuric acid (sulfuric acid, dimethyl ester) 77-78-1
4-Methylthiophenol 106-45-6
Monomethylformamide (N-methylformamide) 123-39-7
Nabam 142-59-6
alpha-Naphthol 90-15-3
beta-Naphthol 135-19-3
alpha-Naphthylamine 134-32-7
beta-Naphthylamine 91-59-8
Neopentyl glycol (dimethylpropane) 126-30-7
Niacinamide 98-92-0
o-Nitroaniline 88-74-4
Nitroglycerin 55-63-0
2-Nitrophenol 88-75-5
4-Nitrophenol 100-02-7
N-Nitrosodimethylamine 62-75-9
Nitrosoguanidine 674-81-7
N-Nitroso-n-methylurea 684-93-5
N-Nitrosomorpholine (4-nitrosomorpholine) 59-89-2
Oxalic acid 144-62-7
Parathion 56-38-2
Pentaerythritol 115-77-5
Phenacetin 62-44-2
Phenol 108-95-2
Phenylacetic acid 103-82-2
m-Phenylene diamine 108-45-2
o-Phenylene diamine 95-54-5
p-Phenylene diamine 106-50-3
Phenyl mercuric acetate 62-38-4
Phorate 298-02-2
Phthalic anhydride 85-44-9
alpha-Picoline (2-methyl pyridine) 109-06-8
1,3-Propane sultone 1120-71-4
beta-Propiolactone 57-57-8
Proporur (Baygon)
Propylene glycol 57-55-6
Pyrene 129-00-0
Pyridinium bromide 39416-48-3
Quinoline 91-22-5
Quinone (p-benzoquinone) 106-51-4
Resorcinol 108-46-3
Simazine 122-34-9
Sodium acetate 127-09-3
Sodium formate 141-53-7
Strychnine 57-24-9
Succinic acid 110-15-6
Succinimide 123-56-8
Sulfanilic acid 121-47-1
Terephthalic acid 100-21-0
Tetraethyldithiopyrophosphate 3689-24-5
Tetraethylenepentamine 112-57-2
Thiofanox 39196-18-4
Thiosemicarbazide 79-19-6
2,4-Toluenediamine 95-80-7
2,6-Toluenediamine 823-40-5
3,4-Toluenediamine 496-72-0
2,4-Toluene diisocyanate 584-84-9
p-Toluic acid 99-94-5
m-Toluidine 108-44-1
1,1,2-Trichloro-1,2,2-trifluoroethane 76-13-1
Triethanolamine 102-71-6
Triethylene glycol dimethyl ether
Tripropylene glycol 24800-44-0
Warfarin 81-81-2
3,4-Xylenol (3,4-dimethylphenol) 95-65-8

Del. Admin. Code tit. 7, 1000, 1300, 1302, pt. 265, Waste Treatment, Storage, and Disposal Facilities, subpt. FF, app V