Section 173.319 - Cryogenic liquids in tank cars(a)General requirements.(1) A tank car containing a flammable cryogenic liquid may not be shipped unless it was loaded by, or with the consent of, the owner of the tank car.(2) The amount of flammable cryogenic liquid loaded into a tank car must be determined, either by direct measurement or by calculation based on weight, to verify that the tank has not been filled to a level in excess of the limits specified in paragraph (d)(2) of this section. The weight of any flammable cryogenic liquid loaded, except hydrogen, must be checked by use of scales after disconnecting the loading line.(3) The shipper must notify the Federal Railroad Administration whenever a tank car containing any flammable cryogenic liquid is not received by the consignee within 20 days from the date of shipment. Notification to the Federal Railroad Administration may be made by email to HMassist@dot.gov or telephone call to (202) 493-6245.(4) A tank car may not be loaded with any flammable cryogenic liquid: (i) That may combine chemically with any residue in the tank to produce an unsafe condition,(ii) That is colder than the design service temperature of the tank,(iii) If the average daily pressure rise in the tank exceeded 3 psig during the prior shipment,(iv) Unless it is marked with the name of contents, in accordance with § 172.330 of this subchapter.(b) When a tank car containing a flammable cryogenic liquid is offered for transportation:(1) At least 0.5 percent outage must be provided below the inlet of the pressure relief or pressure control valve at the start-to-discharge pressure setting of the valve, with the tank car in a level attitude, and(2) The absolute pressure in the annular space must be less than 75 microns of mercury.(c)Temperature. A flammable cryogenic liquid must be loaded into a tank car at such a temperature that the average daily pressure rise during transportation will not exceed 3 psig (see paragraph (a)(4)(iii) of this section).(d) A Class DOT-113 tank car is authorized for the shipment of the following cryogenic liquids subject to the following additional requirements:(1) For purposes of this section, "filling density" is defined as the percent ratio of the weight of lading in the tank to the weight of water that the tank will hold at the design service temperature (one pound of water = 27.737 cubic inches at 60 °F., or one gallon of water = 231 cubic inches at 60 °F. and weighs 8.32828 pounds).(2)Ethylene, hydrogen (minimum 95 percent parahydrogen), and methane, cryogenic liquids must be loaded and shipped in accordance with the following table: Table 1 to § 173.319(d) -Pressure Control Valve Setting or Relief Valve Setting
Maximum start-to-discharge pressure
(psig) | Maximum permitted filling density
(percent by weight) |
| Ethylene | Ethylene | Ethylene | Hydrogen | Methane |
| 17 | | | | 6.60 | |
| 45 | 52.8 | | | | |
| 75 | | 51.1 | 51.1 | | 37.3. |
| Maximum pressure when offered for transportation | 10 psig | 20 psig | 20 psig | | 15 psig. |
| Design service temperature | Minus 260 °F | Minus 260 °F | Minus 155 °F | Minus 423 °F | Minus 260 °F. |
| Specification (see§ 180.507(b)(3) of this subchapter) | 113D60W, 113C60W | 113C120W | 113D120W | 113A175W, 113A60W | 113C120W9. |
Note: For DOT 113 cryogenic tank cars, delimiters indicate the following:
A-authorized for minus 423 °F loading;
C-authorized for minus 260 °F loading;
D-authorized for minus 155 °F loading.
The specification suffix "9" indicates the tank car is equipped with (minimum) 9/16 inch TC 128B normalized steel outer jacket and tank heads.
(e)Special requirements for class DOT 113 tank cars.(1) A class DOT-113 tank car need not be periodically pressure tested; however, each shipment must be monitored to determine the average daily pressure rise in the tank car. If the average daily pressure rise during any shipment exceeds 0.2 Bar (3 psig) per day, the tank must be tested for thermal integrity prior to any subsequent shipment.(2)Thermal integrity test. When required by paragraph (e)(1) of this section, either of the following thermal integrity tests may be used: (i)Pressure rise test. The pressure rise in the tank may not exceed 0.34 Bar (5 psig) in 24 hours. When the pressure rise test is performed, the absolute pressure in the annular space of the loaded tank car may not exceed 75 microns of mercury at the beginning of the test and may not increase more than 25 microns during the 24-hour period; or(ii)Calculated heat transfer rate test. The insulation system must be performance tested as prescribed in § 179.400-4 of this subchapter. When the calculated heat transfer rate test is performed, the absolute pressure in the annular space of the loaded tank car may not exceed 75 microns of mercury at the beginning of the test and may not increase more than 25 microns during the 24-hour period. The calculated heat transfer rate in 24 hours may not exceed: (A) 120 percent of the appropriate standard heat transfer rate specified in § 179.401-1 of this subchapter, for DOT-113A60W and DOT-113C120W tank cars;(B) 122.808 joules (0.1164 Btu/day/lb.) of inner tank car water capacity, for DOT-113A175W tank cars;(C) 345.215 joules (0.3272 Btu/day/lb.) of inner tank car water capacity, for DOT-113C60W and 113D60W tank cars; or(D) 500.09 joules (0.4740 Btu/day/lb.) of inner tank car water capacity, for DOT-113D120W tank cars.(3) A tank car that fails a test prescribed in paragraph (e)(2) of this section must be removed from hazardous materials service. A tank car removed from hazardous materials service because it failed a test prescribed in paragraph (e)(2) of this section may not be used to transport a hazardous material unless the tank car conforms to all applicable requirements of this subchapter.(4) Each rupture disc must be replaced every 12 months, and the replacement date must be marked on the car near the pressure relief valve information.(5) Pressure relief valves and alternate pressure relief valves must be tested every five years. The start-to-discharge pressure and vapor tight pressure requirements for the pressure relief valves must be as specified in § 179.401-1 of this subchapter. The alternate pressure relief device values specified in § 179.401-1 of this subchapter for a DOT-113C120W tank car apply to a DOT-113D120W tank car.Amdt. 173-166, 48 FR 27698, June 16, 1983, as amended by Amdt. 173-245, Sept. 21, 1995; 65 FR 58630, Sept. 29, 2000; 66 FR 45184, 45379, 45383, Aug. 28, 2001; 70 FR 34076, June 13, 2005; 81 FR 3681, Jan. 21, 2016; 85 FR 45029, July 24, 2020 49 U.S.C. 1803, 1804, 1808 ; 49 CFR 1.53, app. A to part 1
81 FR 3681, 1/21/2016; 85 FR 45029, 8/24/2020