Act means the Toxic Substances Control Act (15 U.S.C. 2601 et seq.).
Biopolymer means a polymer directly produced by living or once-living cells or cellular components.
Category of chemical substances has the same meaning as in section 26(c)(2) of the Act (15 U.S.C. 2625 ).
Cationic polymer means a polymer that contains a net positively charged atom(s) or associated groups of atoms covalently linked to its polymer molecule.
Chemical substance, Director, EPA, importer, impurity, Inventory, known to or reasonably ascertainable, manufacture, manufacturer, mixture, new chemical, person, possession or control, process and test data have the same meanings as in § 720.3 of this chapter.
Equivalent weight of a functional group means the ratio of the molecular weight to the number of occurrences of that functional group in the molecule. It is the weight of substance that contains one formula-weight of the functional group.
Fluorotelomers means the products of telomerization, which is the reaction of a telogen (such as pentafluoroethyl iodide) with an ethylenic compound (such as tetrafluoroethylene) to form low molecular weight polymeric compounds, which contain an array of saturated carbon atoms covalently bonded to each other (C-C bonds) and to fluorine atoms (C-F bonds). This array is predominantly a straight chain, and depending on the telogen used produces a compound having an even number of carbon atoms. However, the carbon chain length of the fluorotelomer varies widely. The perfluoroalkyl groups formed by this process are usually, but do not have to be, connected to the polymer through a functionalized ethylene group as indicated by the following structural diagram: (Rf-CH2CH2-Anything).
Internal monomer unit means a monomer unit that is covalently bonded to at least two other molecules. Internal monomer units of polymer molecules are chemically derived from monomer molecules that have formed covalent bonds between two or more other monomer molecules or other reactants.
Monomer means a chemical substance that is capable of forming covalent bonds with two or more like or unlike molecules under the conditions of the relevant polymer-forming reaction used for the particular process.
Monomer Unit means the reacted form of the monomer in a polymer.
Number-average molecular weight means the arithmetic average (mean) of the molecular weight of all molecules in a polymer.
Oligomer means a polymer molecule consisting of only a few monomer units (dimer, trimer, tetramer)
Other reactant means a molecule linked to one or more sequences of monomer units but which, under the relevant reaction conditions used for the particular process, cannot become a repeating unit in the polymer structure.
Perfluoroalkyl carboxylate (PFAC) means a group of saturated carbon atoms covalently bonded to each other in a linear, branched, or cyclic array and covalently bonded to a carbonyl moiety and where all carbon-hydrogen (C-H) bonds have been replaced with carbon-fluorine (C-F) bonds. The carbonyl moiety is also covalently bonded to a hetero atom, typically, but not necessarily oxygen (O) or nitrogen (N).
Perfluoroalkyl sulfonate (PFAS) means a group of saturated carbon atoms covalently bonded to each other in a linear, branched, or cyclic array and covalently bonded to a sulfonyl moiety and where all carbon - hydrogen (C-H) bonds have been replaced with carbon - fluorine (C-F) bonds. The sulfonyl moiety is also covalently bonded to a hetero atom, typically, but not necessarily oxygen (O) or nitrogen (N).
Polyester means a chemical substance that meets the definition of polymer and whose polymer molecules contain at least two carboxylic acid ester linkages, at least one of which links internal monomer units together.
Polymer means a chemical substance consisting of molecules characterized by the sequence of one or more types of monomer units and comprising a simple weight majority of molecules containing at least 3 monomer units which are covalently bound to at least one other monomer unit or other reactant and which consists of less than a simple weight majority of molecules of the same molecular weight. Such molecules must be distributed over a range of molecular weights wherein differences in the molecular weight are primarily attributable to differences in the number of monomer units. In the context of this definition, sequence means that the monomer units under consideration are covalently bound to one another and form a continuous string within the molecule, uninterrupted by units other than monomer units.
Polymer molecule means a molecule which contains a sequence of at least 3 monomer units which are covalently bound to at least one other monomer unit or other reactant.
Reactant means a chemical substance that is used intentionally in the manufacture of a polymer to become chemically a part of the polymer composition.
Reactive functional group means an atom or associated group of atoms in a chemical substance that is intended or can reasonably be anticipated to undergo further chemical reaction.
Reasonably anticipated means that a knowledgeable person would expect a given physical or chemical composition or characteristic to occur based on such factors as the nature of the precursors used to manufacture the polymer, the type of reaction, the type of manufacturing process, the products produced in polymerization, the intended uses of the substance, or associated use conditions.
Table 1-List of Reactants From Which Polyester May be Made
Reactant | CAS No. |
Monobasic Acids and Natural Oils | |
Benzoic acid | 65-85-0 |
Canola oil | 120962-03-0 |
Coconut oil | 8001-31-8* |
Corn oil | 8001-30-7* |
Cottonseed oil | 8001-29-4* |
Dodecanoic acid | 143-07-7 |
Fats and glyceridic oils, anchovy | 128952-11-4* |
Fats and glyceridic oils, babassu | 91078-92-1* |
Fats and glyceridic oils, herring | 68153-06-0* |
Fats and glyceridic oils, menhaden | 8002-50-4* |
Fats and glyceridic oils, sardine | 93334-41-9* |
Fats and glyceridic oils, oiticica | 8016-35-1* |
Fatty acids,C16-18 and C18-unsatd. | 67701-08-0* |
Fatty acids, castor-oil | 61789-44-4* |
Fatty acids, coco | 61788-47-4* |
Fatty acids, dehydrated castor-oil | 61789-45-5* |
Fatty acids, linseed oil | 68424-45-3* |
Fatty acids, safflower oil | |
Fatty acids, soya | 68308-53-2* |
Fatty acids, sunflower oil | 84625-38-7* |
Fatty acids, sunflower-oil, conjugated | 68953-27-5* |
Fatty acids, tall-oil | 61790-12-3* |
Fatty acids, tall-oil, conjugated* | |
Fatty acids, vegetable oil | 61788-66-7* |
Glycerides, C16-18 and C18-unsatd. | 67701-30-8* |
Heptanoic acid | 111-14-8 |
Hexanoic acid | 142-62-1 |
Hexanoic acid, 3,3,5-trimethyl- | 3302-10-1 |
Linseed oil | 8001-26-1* |
Linseed oil, oxidized | 68649-95-6* |
Nonanoic acid | 112-05-0 |
Oils, Cannabis* | |
Oils, palm kernel | 8023-79-8* |
Oils, perilla | 68132-21-8* |
Oils, walnut | 8024-09-7 |
Safflower oil | 8001-23-8* |
Soybean oil | 8001-22-7* |
Sunflower oil | 8001-21-6* |
Tung oil | 8001-20-5* |
Di and Tri Basic Acids: | |
1,2-Benzenedicarboxylic acid | 88-99-3 |
1,3-Benzenedicarboxylic acid | 121-91-5 |
1,3-Benzenedicarboxylic acid, dimethyl ester | 1459-93-4 |
1,4-Benzenedicarboxylic acid | 100-21-0 |
1,4-Benzenedicarboxylic acid, diethyl ester | 636-09-9 |
1,4-Benzenedicarboxylic acid, dimethyl ester | 120-61-6 |
1,2,4-Benzenetricarboxylic acid | 528-44-9 |
Butanedioic acid | 110-15-6 |
Butanedioic acid, diethyl ester | 123-25-1 |
Butanedioic acid, dimethyl ester | 106-65-0 |
2-Butenedioic acid (E)- | 110-17-8 |
Decanedioic acid | 111-20-6 |
Decanedioic acid, diethyl ester | 110-40-7 |
Decanedioic acid, dimethyl ester | 106-79-6 |
Dodecanedioic acid | 693-23-2 |
Fatty acids, C18-unsatd., dimers | 61788-89-4* |
Heptanedioic acid | 111-16-0 |
Heptanedioic acid, dimethyl ester | 1732-08-7 |
Hexanedioic acid | 124-04-9 |
Hexanedioic acid, dimethyl ester | 627-93-0 |
Hexanedioic acid, diethyl ester | 141-28-6 |
Nonanedioic acid | 123-99-9 |
Nonanedioic acid, dimethyl ester | 1732-10-1 |
Nonanedioic acid, diethyl ester | 624-17-9 |
Octanedioic acid | (505-48-6) |
Octanedioic acid, dimethyl ester | 1732-09-8 |
Pentanedioic acid | (110-94-1) |
Pentanedioic acid, dimethyl ester | 1119-40-0 |
Pentanedioic acid, diethyl ester | 818-38-2 |
Undecanedioic acid | 1852-04-6 |
Polyols | |
1,3-Butanediol | 107-88-0 |
1,4-Butanediol | 110-63-4 |
1,4-Cyclohexanedimethanol | 105-08-8 |
1,2-Ethanediol | 107-21-1 |
Ethanol, 2,2'-oxybis- | 111-46-6 |
1,6-Hexanediol | 629-11-8 |
1,3-Pentanediol, 2,2,4-trimethyl- | 144-19-4 |
1,2-Propanediol, | 57-55-6 |
1,3-Propanediol, 2,2-bis(hydroxymethyl)- | 115-77-5 |
1,3-Propanediol, 2,2-dimethyl- | 126-30-7 |
1,3-Propanediol, 2-ethyl-2-(hydroxymethyl)- | 77-99-6 |
1,3-Propanediol, 2-(hydroxymethyl)-2-methyl- | 77-85-0 |
1,3-propanediol, 2-methyl | 2163-42-0 |
1,2,3-Propanetriol | 56-81-5 |
1,2,3-Propanetriol, homopolymer | 25618-55-7 |
2-Propen-1-ol, polymer with ethenylbenzene | 25119-62-4 |
Modifiers | |
Acetic acid, 2,2'-oxybis- | 110-99-6 |
1-Butanol | 71-36-3** |
Cyclohexanol | 108-93-0 |
Cyclohexanol, 4,4'-(1-methylethylidene)bis- | 80-04-6 |
Ethanol, 2-(2-butoxyethoxy)- | 112-34-5 |
1-Hexanol | 111-27-3 |
Methanol, hydrolysis products with trichlorohexylsilane and trichlorophenylsilane | 72318-84-4* |
1-Phenanthrenemethanol, tetradecahydro-1,4a-dimethyl-7-(1-methylethyl)- | 13393-93-6 |
Phenol, 4,4'-(1-methylethylidene)bis-, polymer with 2,2'- [(1-methylethylidene)bis(4,1-phenyleneoxymethylene)] bis[oxirane] | 25036-25-3 |
Siloxanes and Silicones, di-Me, di-Ph, polymers with Ph silsesquioxanes, methoxy-terminated | 68440-65-3* |
Siloxanes and Silicones, di-Me, methoxy Ph, polymers with Ph silsesquioxanes, methoxy-terminated | 68957-04-0* |
Siloxanes and Silicones, Me Ph, methoxy Ph, polymers with Ph silsesquioxanes, methoxy- and Ph-terminated | 168957-06-2* |
Silsesquioxanes, Ph Pr | 168037-90-1* |
* Chemical substance of unknown or variable composition, complex reaction products, and biological materials (UVCB). The CAS Registry Numbers for UVCB substances are not used in CHEMICAL ABSTRACTS and its indexes.
** These substances may not be used in a substance manufactured from fumaric or maleic acid because of potential risks associated with esters, which may be formed by reaction of these reactants.
40 C.F.R. §723.250