29 C.F.R. § 1915.1000

Current through October 31, 2024
Section 1915.1000 - Air contaminants

Wherever this section applies, an employee's exposure to any substance listed in Table Z-Shipyards of this section shall be limited in accordance with the requirements of the following paragraphs of this section.

(a)
(1)Substances with limits preceded by "C"-Ceiling values. An employee's exposure to any substance in Table Z-Shipyards, the exposure limit of which is preceded by a "C," shall at no time exceed the exposure limit given for that substance. If instantaneous monitoring is not feasible, then the ceiling shall be assessed as a 15-minute time weighted average exposure which shall not be exceeded at any time over a working day.
(2)Other Substances-8-hour Time Weighted Averages. An employee's exposure to any substance in Table Z-Shipyards, the exposure limit of which is not preceded by a "C," shall not exceed the 8-hour Time Weighted Average given for that substance in any 8-hour work shift of a 40-hour work week.
(b)-(c) [Reserved]
(d)Computation formula. The computation formula which shall apply to employee exposure to more than one substance for which 8-hour time weighted averages are listed in subpart Z of 29 CFR part 1915 in order to determine whether an employee is exposed over the regulatory limit is as follows:
(1)
(i) The cumulative exposure for an 8-hour work shift shall be computed as follows:

E = (Ca Ta + Cb Tb + ...Cn Tn) ÷ 8

Where:

E is the equivalent exposure for the working shift.

C is the concentration during any period of time T where the concentration remains constant.

T is the duration in hours of the exposure at the concentration C.

The value of E shall not exceed the 8-hour time weighted average specified in subpart Z of 29 CFR part 1915 for the material involved.

(ii) To illustrate the formula prescribed in paragraph (d)(1)(i) of this section, assume that Substance A has an 8-hour time weighted average limit of 100 ppm noted in Table Z-Shipyards. Assume that an employee is subject to the following exposure:

Two hours exposure at 150 ppm

Two hours exposure at 75 ppm

Four hours exposure at 50 ppm

Substituting this information in the formula, we have

(2 * 150 + 2 * 75 + 4 * 50) ÷ 8 = 81.25 ppm

Since 81.25 ppm is less than 100 ppm, the 8-hour time weighted average limit, the exposure is acceptable.

(2)
(i) in case of a mixture of air contaminants an employer shall compute the equivalent exposure as follows:

Em = (C1÷ L1 + C2÷ L2) + ...(Cn÷ Ln)

Where:

Em is the equivalent exposure for the mixture.

C is the concentration of a particular contaminant.

L is the exposure limit for that substance specified in subpart Z of 29 CFR part 1915.

The value of Em shall not exceed unity (1).

(ii) To illustrate the formula prescribed in paragraph (d)(2)(i) of this section, consider the following exposures:

SubstanceActual concentration of 8 hour exposure (ppm)8 hr. TWA PEL (ppm)
B5001000
C45200
D40200

Substituting in the formula, we have:

Em = 500 ÷ 1,000 + 45 ÷ 200 + 40 ÷ 200

Em = 0.500 + 0.225 + 0.200

Em = 0.925

Since Em is less than unity (1), the exposure combination is within acceptable limits.

Table Z-Shipyards

SubstanceCAS No.d ppma * mg/m3 b *Skin Designation
Abate; see Temephos
Acetaldehyde75-07-0200360-
Acetic acid64-19-71025-
Acetic anhydride108-24-7520-
Acetone67-64-110002400-
Acetonitrile75-05-84070-
2-Acetylaminofluorine; see § 1915.1014 53-96-3
Acetylene74-86-2E
Acetylene dichloride; see 1,2-Dichloroethylene
Acetylene tetrabromide79-27-6114-
Acrolein107-02-80.10.25-
Acrylamide79-06-1-0.3X
Acrylonitrile; see § 1915.1045 107-13-1
Aldrin309-00-2-0.25X
Allyl alcohol107-18-625X
Allyl chloride107-05-113-
Allyl glycidyl ether (AGE)106-92-3(C)10(C)45-
Allyl propyl disulfide2179-59-1212-
alpha-Alumina1344-28-1
Total dust-15-
Respirable fraction-5-
Aluminum, (as Al) Metal7429-90-5
Total dust-15-
Respirable fraction-5-
Alundum; see alpha-Alumina
4-Aminodiphenyl; see § 1915.1011 92-67-1
2-Aminoethanol; see Ethanolamine
2-Aminopyridine504-29-00.52-
Ammonia7664-41-75035-
Ammonium sulfamate7773-06-0
Total dust-15-
Respirable fraction-5-
n-Amyl acetate628-63-7100525-
sec-Amyl acetate626-38-0125650-
Aniline and homologs62-53-3519X
Anisidine (o-, p-isomers)29191-52-4-0.5X
Antimony and compounds (as Sb)7440-36-0-0.5-
ANTU (alpha Naphthylthiourea)86-88-4-0.3-
Argon7440-37-1E
Arsenic, inorganic compounds (as As); see § 1915.1018 7440-38-2---
Arsenic, organic compounds (as As)7440-38-2-0.5-
Arsine7784-42-10.050.2-
Asbestos; see 1915.1001
Azinphos-methyl86-50-0-0.2X
Barium, soluble compounds (as Ba)7440-39-3-0.5-
Barium sulfate7727-43-7
Total dust-15-
Respirable fraction-5-
Benomyl17804-35-2
Total dust-15-
Respirable fraction-5-
Benzeneg; see § 1915.1028 71-43-2
Benzidine; see § 1915.1010 92-87-5
p-Benzoquinone; see Quinone
Benzo(a)pyrene; see Coal tar pitch volatiles
Benzoyl peroxide94-36-0-5-
Benzyl chloride100-44-715-
Beryllium and beryllium compounds (as Be); see 1915.1024(q)7440-41-70.002
Biphenyl; see Diphenyl
Bismuth telluride, Undoped1304-82-1
Total dust-15-
Respirable fraction-5-
Bisphenol A; see Diglycidyl ether
Boron oxide1303-86-2
Total dust-15-
Boron tribromide10294-33-4110-
Boron trifluoride7637-07-2(C)1(C)3-
Bromine7726-95-60.10.7-
Bromine pentafluoride7789-30-20.10.7-
Bromoform75-25-20.55X
Butadiene (1,3-Butadiene); see 29 CFR 1910.1051 ; 29 CFR 1910.19(l) 106-99-01
ppm/5
ppm
STEL
--
Butanethiol; see Butyl mercaptan
2-Butanone (Methyl ethyl ketone)78-93-3200590-
2-Butoxyethanol111-76-250240X
n-Butyl-acetate123-86-4150710-
sec-Butyl acetate105-46-4200950-
tert-Butyl acetate540-88-5200950-
n-Butyl alcohol71-36-3100300-
sec-Butyl alcohol78-92-2150450-
tert-Butyl alcohol75-65-0100300-
Butylamine109-73-9(C)5(C)15X
tert-Butyl chromate (as CrO3); see 1915.1026n1189-85-1
n-Butyl glycidyl ether (BGE)2426-08-650270-
Butyl mercaptan109-79-50.51.5-
p-tert-Butyltoluene98-51-11060-
Cadmium dust fume (as Cd); see 1915.10277440-43-9---
Calcium carbonate1317-65-3
Total dust-15-
Respirable fraction-5-
Calcium hydroxide1305-62-0---
Calcium hydroxide
Total dust-15-
Respirable fraction-5-
Calcium oxide1305-78-8-5-
Calcium silicate1344-95-2
Total dust-15-
Respirable fraction-5-
Calcium sulfate7778-18-9
Total dust-15-
Respirable fraction-5-
Camphor, synthetic76-22-2-2-
Carbaryl (Sevin)63-25-2-5-
Carbon black1333-86-4-3.5-
Carbon dioxide124-38-950009000-
Carbon disulfide75-15-02060X
Carbon monoxide630-08-05055-
Carbon tetrachloride56-23-51065X
Cellulose9004-34-6
Total dust-15-
Respirable fraction-5-
Chlordane57-74-9-0.5X
Chlorinated camphene8001-35-2-0.5X
Chlorinated diphenyl oxide55720-99-5-0.5-
Chlorine7782-50-513-
Chlorine trifluoride7790-91-2(C)0.1(C)0.4-
Chloroacetaldehyde107-20-0(C)1(C)3-
a-Chloroacetophenone (Phenacyl chloride)532-27-40.050.3-
Chlorobenzene108-90-775350-
o-Chlorobenzylidene malononitrile2698-41-10.050.4-
Chlorobromomethane74-97-52001050-
2-Chloro-1,3-butadiene; see beta-Chloroprene
Chlorodiphenyl (42% Chlorine) (PCB)53469-21-9-1X
Chlorodiphenyl (54% Chlorine) (PCB)11097-69-1-0.5X
1-Chloro,2,3-epoxypropane; see Epichlorohydrin
2-Chloroethanol; see Ethylene chlorohydrin
Chloroethylene; see Vinyl chloride
Chloroform (Trichloromethane)67-66-350240-
bis(Chloromethyl) ether; see § 1915.1008 542-88-1
Chloromethyl methyl ether; see § 1915.1006 107-30-2
1-Chloro-1-nitropropane600-25-920100-
Chloropicrin76-06-20.10.7
beta-Chloroprene126-99-82590X
2-Chloro-6-(trichloromethyl) pyridine1929-82-4
Total dust-15-
Respirable fraction-5-
Chromium (II) compounds
(as Cr)7440-47-3-0.5-
Chromium (III) compounds
(as Cr)7440-47-3-0.5-
Chromium (VI) compounds; see 1915.1026o
Chromium metal and insol. salts (as Cr)7440-47-3-1-
Chrysene; see Coal tar pitch volatiles
Clopidol2971-90-6
Total dust-15-
Respirable fraction-5-
Coal tar pitch volatiles (benzene soluble fraction), anthracene, BaP, phenanthrene, acridine, chrysene, pyrene65966-93-2-0.2-
Cobalt metal, dust, and fume (as Co)7440-48-4-0.1-
Copper7440-50-8
Fume (as Cu)-0.1-
Dusts and mists (as Cu)-1-
Corundum; see Emery
Cotton dust (raw)-1
Crag herbicide (Sesone)136-78-7
Total dust-15-
Respirable fraction-5-
Cresol, all isomers1319-77-3522X
Crotonaldehyde123-73-9;26
4170-30-3
Cumene98-82-850245X
Cyanides (as CN)Varies with Compound-5-
Cyanogen460-19-510--
Cyclohexane110-82-73001050-
Cyclohexanol108-93-050200-
Cyclohexanone108-94-150200-
Cyclohexene110-83-83001015-
Cyclonite121-82-4-1.5X
Cyclopentadiene542-92-775200-
2,4-D (Dichlorophenoxyacetic acid)94-75-7-10-
Decaborane17702-41-90.050.3X
Demeton (Systox)8065-48-3-0.1X
Diacetone alcohol (4-Hydroxy-4-methyl-2-pentanone)123-42-250240-
1,2-Diaminoethane; see Ethylenediamine
Diazomethane334-88-30.20.4-
Diborane19287-45-70.10.1-
1,2-Dibromo-3-chloropropane (CBCP); see § 1915.1044 96-12-8-
1,2-Dibromoethane; see Ethylene dibromide
Dibutyl phosphate107-66-415-
Dibutyl phthalate84-74-2-5-
Dichloroacetylene7572-29-4(C)0.1(C)0.4-
o-Dichlorobenzene95-50-1(C)50(C)300-
p-Dichlorobenzene106-46-775450-
3,3'-Dichlorobenzidine; see § 1915.1007 91-94-1
Dichlorodifluoromethane75-71-810004950-
1,3-Dichloro-5,5-dimethyl hydantoin118-52-5-0.2-
Dichlorodiphenyltrichloroethane (DDT)50-29-3-1X
1,1-Dichloroethane75-34-3100400-
1,2-Dichloroethane; see Ethylene dichloride
1,2-Dichloroethylene540-59-0200790-
Dichloroethyl ether111-44-4(C)15(C)90X
Dichloromethane; see Methylene chloride
Dichloromonofluoromethane75-43-410004200-
1,1-Dichloro-1-nitroethane594-72-9(C)10(C)60-
1,2-Dichloropropane; see Propylene dichloride
Dichlorotetrafluoroethane76-14-210007000-
Dichlorvos (DDVP)62-73-7-1X
Dicyclopentadienyl iron102-54-5
Total dust-15-
Respirable fraction-5-
Dieldrin60-57-1-0.25X
Diethylamine109-89-72575-
2-Diethylaminoethanol100-37-81050-
Diethylene triamine111-40-0(C)10(C)42X
Diethyl ether; see Ethyl ether
Difluorodibromomethane75-61-6100860-
Diglycidyl ether (DGE)2238-07-5(C)0.5(C)2.8-
Dihydroxybenzene; see Hydroquinone
Diisobutyl ketone108-83-850290-
Diisopropylamine108-18-9520X
4-Dimethylaminoazobenzene; see § 1915.1015 60-11-7
Dimethoxymethane; see Methylal
Dimethyl acetamide127-19-51035X
Dimethylamine124-40-31018-
Dimethylaminobenzene; see Xylidine
Dimethylaniline (N,N-Dimethylaniline)121-69-7525X
Dimethylbenzene; see Xylene
Dimethyl-1,2-dibromo- 2,2-dichloroethyl phosphate300-76-5-3-
Dimethylformamide68-12-21030X
2,6-Dimethyl-4-heptanone; see Diisobutyl ketone
1,1-Dimethylhydrazine57-14-70.51X
Dimethylphthalate131-11-3-5-
Dimethyl sulfate77-78-315X
Dinitrobenzene (all isomers)1X
(ortho)528-29-0
(meta)99-65-0
(para)100-25-4
Dinitro-o-cresol534-52-1-0.2X
Dinitrotoluene25321-14-6-1.5X
Dioxane (Diethylene dioxide)123-91-1100360X
Diphenyl (Biphenyl)92-52-40.21-
Diphenylamine122-39-4-10-
Diphenylmethane diisocyanate; see Methylene bisphenyl isocyanate
Dipropylene glycol methyl ether34590-94-8100600X
Di-sec octyl phthalate (Di-(2-ethylhexyl) phthalate)117-81-7-5-
Emery12415-34-8
Total dust-15-
Respirable fraction-5-
Endosulfan115-29-7-0.1X
Endrin72-20-8-0.1X
Epichlorohydrin106-89-8519X
EPN2104-64-5-0.5X
1,2-Epoxypropane; see Propylene oxide
2,3-Epoxy-1-propanol; see Glycidol
Ethane74-84-0E
Ethanethiol; see Ethyl mercaptan
Ethanolamine141-43-536-
2-Ethoxyethanol (Cellosolve)110-80-5200740X
2-Ethoxyethyl acetate (Cellosolve acetate)111-15-9100540X
Ethyl acetate141-78-64001400-
Ethyl acrylate140-88-525100X
Ethyl alcohol (Ethanol)64-17-510001900-
Ethylamine75-04-71018-
Ethyl amyl ketone (5-Methyl-3-heptanone)541-85-525130-
Ethyl benzene100-41-4100435-
Ethyl bromide74-96-4200890-
Ethyl butyl ketone (3-Heptanone)106-35-450230-
Ethyl chloride75-00-310002600-
Ethyl ether60-29-74001200-
Ethyl formate109-94-4100300-
Ethyl mercaptan75-08-10.51-
Ethyl silicate78-10-4100850-
Ethylene74-85-1E
Ethylene chlorohydrin107-07-3516X
Ethylenediamine107-15-31025-
Ethylene dibromide106-93-4(C)25(C)190X
Ethylene dichloride (1,2-Dichloroethane)107-06-250200-
Ethylene glycol dinitrate628-96-6(C)0.2(C)1X
Ethylene glycol methyl acetate; see Methyl cellosolve acetate
Ethyleneimine; see § 1915.1012 151-56-4
Ethylene oxide; see § 1915.1047 75-21-8
Ethylidene chloride; see 1,1-Dichloroethane
N-Ethylmorpholine100-74-32094X
Ferbam14484-64-1
Total dust-15-
Ferrovanadium dust12604-58-9-1-
Fibrous Glass
Total dust15-
Respirable fraction-5-
Fluorides (as F)Varies with compound-2.5-
Fluorine7782-41-40.10.2-
Fluorotrichloromethane (Trichlorofluoromethane)75-69-410005600-
Formaldehyde; see § 1915.1048 50-00-0
Formic acid64-18-659-
Furfural98-01-1520X
Furfuryl alcohol98-00-050200-
Gasoline8006-61-9A3-
Glycerin (mist)56-81-5
Total dust-15-
Respirable fraction-5-
Glycidol556-52-550150-
Glycol monoethyl ether; see 2-Ethoxyethanol
Graphite, natural, respirable dust7782-42-5(2)(2)(2)
Graphite, synthetic
Total dust-15-
Respirable fraction-5-
Guthion; see Azinphos methyl
Gypsum13397-24-5
Total dust-15-
Respirable fraction-5-
Hafnium7440-58-6-0.5-
Helium7440-59-7E
Heptachlor76-44-8-0.5X
Heptane (n-Heptane)142-82-55002000-
Hexachloroethane67-72-1110X
Hexachloronaphthalene1335-87-1-0.2X
n-Hexane110-54-35001800-
2-Hexanone (Methyl n-butyl ketone)591-78-6100410-
Hexone (Methyl isobutyl ketone)108-10-1100410-
sec-Hexyl acetate108-84-950300-
Hydrazine302-01-211.3X
Hydrogen1333-74-0E
Hydrogen bromide10035-10-6310-
Hydrogen chloride7647-01-0(C)5(C)7-
Hydrogen cyanide74-90-81011X
Hydrogen fluoride (as F)7664-39-332-
Hydrogen peroxide7722-84-111.4-
Hydrogen selenide (as Se)7783-07-50.05
Hydrogen sulfide7783-06-41015-
Hydroquinone123-31-9-2-
Indene95-13-61045-
Indium and compounds (as In)7440-74-6-0.1-
Iodine7553-56-2(C)0.1(C)1-
Iron oxide fume1309-37-1-10-
Iron salts (soluble) (as Fe)Varies with compound-1-
Isoamyl acetate123-92-2100525-
Isoamyl alcohol (primary and secondary)123-51-3100360-
Isobutyl acetate110-19-0150700-
Isobutyl alcohol78-83-1100300-
Isophorone78-59-125140-
Isopropyl acetate108-21-4250950-
Isopropyl alcohol67-63-0400980-
Isopropylamine75-31-0512-
Isopropyl ether108-20-35002100-
Isopropyl glycidyl ether (IGE)4016-14-250240-
Kaolin1332-58-7
Total dust-15-
Respirable fraction-5-
Ketene463-51-40.50.9-
Lead, inorganic (as Pb); see § 1915.1025 7439-92-1---
Limestone1317-65-3
Total dust-15-
Respirable fraction-5-
Lindane58-89-9-0.5X
Lithium hydride7580-67-8-0.025-
L.P.G. (Liquefied petroleum gas)68476-85-710001800
Magnesite546-93-0
Total dust-15-
Respirable fraction-5-
Magnesium oxide fume1309-48-4
Total particulate15--
Malathion121-75-5
Total dust-15X
Maleic anhydride108-31-60.25
Manganese compounds (as Mn)7439-96-5-(C)5-
Manganese fume (as Mn)7439-96-5-(C)5-
Marble1317-65-3
Total dust-15-
Respirable fraction-5-
Mercury (aryl and inorganic)(as Hg)7439-97-60.1X
Mercury (organo) alkyl compounds (as Hg)7439-97-6-0.01X
Mercury (vapor) (as Hg)7439-97-6-0.1X
Mesityl oxide141-79-725100-
Methane74-82-8E
Methanethiol; see Methyl mercaptan
Methoxychlor72-43-5
Total dust-15-
2-Methoxyethanol (Methyl cellosolve)109-86-42580X
2-Methoxyethyl acetate (Methyl cellosolve acetate)110-49-625120X
Methyl acetate79-20-9200610-
Methyl acetylene (Propyne)74-99-710001650-
Methyl acetylene-propadiene mixture (MAPP)10001800-
Methyl acrylate96-33-31035X
Methylal (Dimethoxy-methane)109-87-510003100-
Methyl alcohol67-56-1200260-
Methylamine74-89-51012-
Methyl amyl alcohol; see Methyl isobutyl carbinol
Methyl n-amyl ketone110-43-0100465-
Methyl bromide74-83-9(C)20(C)80X
Methyl butyl ketone; see 2-Hexanone
Methyl cellosolve; see 2-Methoxyethanol
Methyl cellosolve acetate; see 2-Methoxyethyl acetate
Methyl chloride74-87-3100210-
Methyl chloroform (1,1,1-Trichloroethane)71-55-63501900-
Methylcyclohexane108-87-25002000-
Methylcyclohexanol25639-42-3100470-
o-Methylcyclohexanone583-60-8100460X
Methylene chloride; see § 1910.1052
Methyl ethyl ketone (MEK); see 2-Butanone
Methyl formate107-31-3100250-
Methyl hydrazine (Monomethyl hydrazine)60-34-4(C)0.2(C)0.35X
Methyl iodide74-88-4528X
Methyl isoamyl ketone110-12-3100475-
Methyl isobutyl carbinol108-11-225100X
Methyl isobutyl ketone; see Hexone
Methyl isocyanate624-83-90.020.05X
Methyl mercaptan74-93-10.51-
Methyl methacrylate80-62-6100410100
Methyl propyl ketone; see 2-Pentanone
Methyl silicate681-84-5530-
alpha-Methyl styrene98-83-9(C)100(C)480-
Methylene bisphenyl isocyanate (MDI)101-68-8(C)0.02(C)0.2-
Mica; see Silicates
Mineral wool
Total dust-15-
Respirable dust-5-
Molybdenum (as Mo)7439-98-7
Soluble compounds-5-
Insoluble compounds
Total dust-15-
Monomethyl aniline100-61-829X
Monomethyl hydrazine; see Methyl hydrazine
Morpholine110-91-82070X
Naphtha (Coal tar)8030-30-6100400-
Naphthalene91-20-31050-
alpha-Naphthylamine; see § 1915.1004 134-32-7
beta-Naphthylamine; see § 1915.1009 91-59-8-
Neon7440-01-9
Nickel carbonyl (as Ni)13463-39-30.0010.007-
Nickel, metal and insoluble compounds (as Ni)7440-02-0-1-
Nickel, soluble compounds (as Ni)7440-02-0-1-
Nicotine54-11-5-0.5X
Nitric acid7697-37-225-
Nitric oxide10102-43-92530-
p-Nitroaniline100-01-616X
Nitrobenzene98-95-315X
p-Nitrochlorobenzene100-00-5-1X
4-Nitrodiphenyl; see § 1915.1003 92-93-3
Nitroethane79-24-3100310-
Nitrogen7727-37-9E
Nitrogen dioxide10102-44-0(C)5(C)9-
Nitrogen trifluoride7783-54-21029-
Nitroglycerin55-63-0(C)0.2(C)2X
Nitromethane75-52-5100250-
1-Nitropropane108-03-22590-
2-Nitropropane79-46-92590-
N-Nitrosodimethylamine; see § 1915.1016 62-79-9-
Nitrotoluene (all isomers)530X
o-isomer88-72-2;
m-isomer99-08-1;
p-isomer99-99-0
Nitrotrichloromethane; see Chloropicrin
Nitrous oxide10024-97-2E
Octachloronaphthalene2234-13-1-0.1X
Octane111-65-94001900-
Oil mist, mineral8012-95-1-5-
Osmium tetroxide (as Os)20816-12-0-0.002-
Oxalic acid144-62-7-1-
Oxygen difluoride7783-41-70.050.1-
Ozone10028-15-60.10.2-
Paraquat, respirable dust4685-14-7;-0.5X
1910-42-5;
2074-50-2
Parathion56-38-2-0.1-
Particulates not otherwise regulated
Total dust organic and inorganic-15-
PCB; see Chlorodiphenyl (42% and 54% chlorine)
Pentaborane19624-22-70.0050.01-
Pentachloronaphthalene1321-64-8-0.5X
Pentachlorophenol87-86-5-0.5X
Pentaerythritol115-77-5
Total dust-15-
Respirable fraction-5-
Pentane109-66-05001500-
2-Pentanone (Methyl propyl ketone)107-87-9200700-
Perchloroethylene (Tetrachloroethylene)127-18-4100670-
Perchloromethyl mercaptan594-42-30.10.8-
Perchloryl fluoride7616-94-6313.5-
Perlite93763-70-3
Total dust-15-
Respirable fraction-5-
Petroleum distillates (Naphtha)(Rubber Solvent)A3-
Phenol108-95-2519X
p-Phenylene diamine106-50-3-0.1X
Phenyl ether, vapor101-84-817-
Phenyl ether-biphenyl mixture, vapor17-
Phenylethylene; see Styrene
Phenyl glycidyl ether (PGE)122-60-11060-
Phenylhydrazine100-63-0522X
Phosdrin (Mevinphos)7786-34-7-0.1X
Phosgene (Carbonyl chloride)75-44-50.10.4-
Phosphine7803-51-20.30.4-
Phosphoric acid7664-38-2-1-
Phosphorus (yellow)7723-14-0-0.1-
Phosphorus pentachloride10026-13-8-1-
Phosphorus pentasulfide1314-80-3-1-
Phosphorus trichloride7719-12-20.53-
Phthalic anhydride85-44-9212-
Picloram1918-02-1
Total dust-15-
Respirable fraction-5-
Picric acid88-89-1-0.1-
Piperazine dihydrochloride142-64-3--X
Pindone (2-Pivalyl-1,3-indandione)83-26-1-0.1-
Plaster of Paris26499-65-0
Total dust-15-
Respirable fraction-5-
Platinum (as Pt)7440-06-4
Metal---
Soluble salts-0.002-
Polytetrafluoroethylene decomposition productsA2
Portland cement65997-15-1
Total dust15-10
Respirable fraction5--
Propargyl alcohol107-19-71-X
beta-Propriolactone; see § 1915.1013 57-57-8
Propionic acid79-09-4---
n-Propyl acetate109-60-4200840-
n-Propyl alcohol71-23-8200500-
n-Propyl nitrate627-13-425110-
Propylene dichloride78-87-575350-
Propylene imine75-55-825X
Propylene oxide75-56-9100240-
Propyne; see Methyl acetylene
Pyrethrum8003-34-7-5-
Pyridine110-86-1515-
Quinone106-51-40.10.4-
RDX; see Cyclonite
Rhodium (as Rh), metal fume and insoluble compounds7440-16-6-0.1-
Rhodium (as Rh), soluble compounds7440-16-6-0.001-
Ronnel299-84-3-10-
Rotenone83-79-4-5-
Rouge-
Total dust-15-
Respirable fraction-5-
Selenium compounds (as Se)7782-49-2-0.2-
Selenium hexafluoride (as Se)7783-79-10.050.4-
Silica, amorphous, precipitated and gel112926-00-8(2)(2)(2)
Silica, amorphous, diatomaceous earth, containing less than 1% crystalline silica61790-53-2(2)(2)(2)
Silica, crystalline, respirable dust
Cristobalite; see 1915.105314464-46-1
Quartz; see 1915.1053514808-60-7
Tripoli (as quartz); see 1915.105351317-95-9
Tridymite; see 1915.105315468-32-3
Silica, fused, respirable dust60676-86-0(2)(2)(2)
Silicates (less than 1% crystalline silica)
Mica (respirable dust)12001-26-2(2)(2)(2)
Soapstone, total dust-(2)(2)(2)
Soapstone, respirable dust-(2)(2)(2)
Talc (containing asbestos)-(3)(3)(3)
Talc (containing no asbestos), respirable dust14807-96-6(2)(2)(2)
Tremolite, asbestiform(3)(3)(3)
Silicon7440-21-3
Total dust-15-
Respirable fraction-5-
Silicon carbide409-21-2
Total dust-15-
Respirable fraction-5-
Silver, metal and soluble compounds (as Ag)7440-22-4-0.01-
Soapstone; see Silicates
Sodium fluoroacetate62-74-8-0.05X
Sodium hydroxide1310-73-2-2-
Starch9005-25-8
Total dust-15-
Respirable fraction-5-
Stibine7803-52-30.10.5-
Stoddard solvent8052-41-32001150-
Strychnine57-24-9-0.15-
Styrene100-42-510042050
Sucrose57-50-1
Total dust-15-
Respirable fraction-5-
Sulfur dioxide7446-09-5513-
Sulfur hexafluoride2551-62-410006000-
Sulfuric acid7664-93-9-1-
Sulfur monochloride10025-67-916-
Sulfur pentafluoride5714-22-70.0250.25-
Sulfuryl fluoride2699-79-8520-
Systox, see Demeton
2,4,5-T (2,4,5-trichlorophenoxyacetic acid)93-76-5-10-
Talc; see Silicates-
Tantalum, metal and oxide dust7440-25-7-5-
TEDP (Sulfotep)3689-24-5-0.2X
Teflon decomposition productsA2
Tellurium and compounds (as Te)13494-80-9-0.1-
Tellurium hexafluoride (as Te)7783-80-40.020.2-
Temephos3383-96-8
Total dust-15-
Respirable fraction-5-
TEPP (Tetraethyl pyrophosphate)107-49-3-0.05X
Terphenyls26140-60-3(C)1(C)9-
1,1,1,2-Tetrachloro-2,2-difluoroethane76-11-95004170-
1,1,2,2-Tetrachloro-1,2-difluoroethane76-12-05004170-
1,1,2,2-Tetrachloroethane79-34-5535X
Tetrachloroethylene; see Perchloroethylene
Tetrachloromethane; see Carbon tetrachloride
Tetrachloronaphthalene1335-88-2-2X
Tetraethyl lead (as Pb)78-00-2-0.1X
Tetrahydrofuran109-99-9200590-
Tetramethyl lead, (as Pb)75-74-1-0.15X
Tetramethyl succinonitrile3333-52-60.53X
Tetranitromethane509-14-818-
Tetryl (2,4,6-Trinitrophenylmethylnitramine)479-45-8-1.5X
Thallium, soluble compounds (as Tl)7440-28-0-0.1X
4,4'-Thiobis (6-tert, Butyl-m-cresol)96-69-5
Total dust-15-
Respirable fraction-5-
Thiram137-26-8-5-
Tin, inorganic compounds (except oxides) (as Sn)7440-31-5-2-
Tin, organic compounds (as Sn)7440-31-5-0.1-
Tin oxide (as Sn)21651-19-4---
Total dust-15-
Respirable fraction-5-
Titanium dioxide13463-67-7
Total dust-15-
Toluene108-88-3200750100
Toluene-2,4-diisocyanate (TDI)584-84-9(C)0.02(C)0.14-
o-Toluidine95-53-4522X
Toxaphene; see Chlorinated camphene
Tremolite; see Silicates
Tributyl phosphate126-73-8-5-
1,1,1-Trichloroethane; see Methyl chloroform
1,1,2-Trichloroethane79-00-51045X
Trichloroethylene79-01-6100535-
Trichloromethane; see Chloroform
Trichloronaphthalene1321-65-9-5X
1,2,3-Trichloropropane96-18-450300-
1,1,2-Trichloro-1,2,2-trifluoroethane76-13-110007600-
Triethylamine121-44-825100-
Trifluorobromomethane75-63-810006100-
Trimethyl benzene25551-13-725120-
2,4,6-Trinitrophenyl; see Picric acid
2,4,6-Trinitrophenylmethylnitramine; see Tetryl
2,4,6-Trinitrotoluene (TNT)118-96-7-1.5X
Triorthocresyl phosphate78-30-8-0.1-
Triphenyl phosphate115-86-6-3-
Tungsten (as W)7440-33-7
Insoluble compounds-5-
Soluble compounds-1-
Turpentine8006-64-2100560-
Uranium (as U)7440-61-1
Soluble compounds-0.2-
Insoluble compounds-0.2-
Vanadium1314-62-1
Respirable dust (as V2 O5)-(C)0.5-
Fume (as V2 O5)-(C)0.1-
Vegetable oil mist
Total dust-15-
Respirable fraction-5-
Vinyl benzene; see Styrene
Vinyl chloride; see § 1915.1017 75-01-4
Vinyl cyanide; see Acrylonitrile
Vinyl toluene25013-15-4100480-
Warfarin81-81-2-0.1-
Xylenes (o-, m-, p-isomers)1330-20-7100435-
Xylidine1300-73-8525X
Yttrium7440-65-5-1-
Zinc chloride fume7646-85-7-1-
Zinc oxide fume1314-13-2-5-
Zinc oxide1314-13-2
Total dust-15-
Respirable fraction-5-
Zinc stearate557-05-1
Total dust-15-
Respirable fraction-5-
Zirconium compounds (as Zr)7440-67-7-5

Mineral Dusts

Substance mppcf(j)
SILICA:
Crystalline250(k)
Quartz. Threshold Limit calculated from the formula(p)% SiO2 + 5
Cristobalite
Amorphous, including natural diatomaceous earth20
SILICATES (less than 1% crystalline silica)
Mica20
Portland cement50
Soapstone20
Talc (non-asbestiform)20
Talc (fibrous), use asbestos limit-
Graphite (natural)15
Inert or Nuisance Particulates:(m)50 (or 15 mg/m3 whichever is the smaller) of total dust [LESS THAN]1% SiO2
Conversion factors
mppcf * 35.3 = million particles per cubic meter = particles per c.c.

Footnotes to Table Z-Shipyards:

1 [Reserved]

2 See Mineral Dusts Table.

3 Use Asbestos Limit § 1915.1001 .

4 See 1915.1001.

5 See Mineral Dusts table for the exposure limit for any operations or sectors where the exposure limit in § 1915.1053 is stayed or is otherwise not in effect.

* The PELs are 8-hour TWAs unless otherwise noted; a (C) designation denotes a ceiling limit. They are to be determined from breathing-zone air samples.

a Parts of vapor or gas per million parts of contaminated air by volume at 25 °C and 760 torr.

b Milligrams of substance per cubic meter of air. When entry is in this column only, the value is exact; when listed with a ppm entry, it is approximate.

c [Reserved]

d The CAS number is for information only. Enforcement is based on the substance name. For an entry covering more than one metal compound, measured as the metal, the CAS number for the metal is given-not CAS numbers for the individual compounds.

e-f [Reserved]

g For sectors excluded from § 1915.1028 the limit is 10 ppm TWA.

h Where OSHA has published a proposal for a substance but has not issued a final rule, the proposal is referenced and the existing limit is published.

i [Reserved]

j Millions of particles per cubic foot of air, based on impinger samples counted by light-field techniques.

k The percentage of crystalline silica in the formula is the amount determined from airborne samples, except in those instances in which other methods have been shown to be applicable.

m Covers all organic and inorganic particulates not otherwise regulated. Same as Particulates Not Otherwise Regulated.

n If the exposure limit in § 1915.1026 is stayed or is otherwise not in effect, the exposure limit is a ceiling of 0.1 mg/m3.

o If the exposure limit in § 1915.1026 is stayed or is otherwise not in effect, the exposure limit is 0.1 mg/m3 (as CrO3) as an 8-hour TWA.

p This standard applies to any operations or sectors for which the respirable crystalline silica standard, 1915.1053, is stayed or otherwise is not in effect.

q This standard applies to any operations or sectors for which the beryllium standard, 1915.1024, is stayed or otherwise is not in effect.

The 1970 TLV uses letter designations instead of a numerical value as follows:

A1 [Reserved]

A2 Polytetrafluoroethylene decomposition products. Because these products decompose in part by hydrolysis in alkaline solution, they can be quantitatively determined in air as fluoride to provide an index of exposure. No TLV is recommended pending determination of the toxicity of the products, but air concentrations should be minimal.

A3 Gasoline and/or Petroleum Distillates. The composition of these materials varies greatly and thus a single TLV for all types of these materials is no longer applicable. The content of benzene, other aromatics and additives should be determined to arrive at the appropriate TLV.

E Simple asphyxiants. The limiting factor is the available oxygen which shall be at least 18% and be within the requirement addressing explosion in subpart B of part 1915.

29 C.F.R. §1915.1000

58 FR 35514, July 1, 1993, as amended at 61 FR 56856, Nov. 4, 1996; 62 FR 1619, Jan. 10, 1997; 67 FR 44545 , July 3, 2002; 71 FR 10377 , Feb. 28, 2006; 71 FR 36009 , June 23, 2006; 76 FR 80740 , Dec. 27, 2011; 81 FR 16874 , Mar. 2 2016; 81 FR 31167 , May 19, 2016; 81 FR 60273 , Sept. 2, 2016; 82 FR 2744 , Jan. 9, 2017
82 FR 2744 , 3/10/2017