The Government of the United States of America, as represented by the Secretary of the NavyDownload PDFPatent Trials and Appeals BoardDec 22, 20212021000842 (P.T.A.B. Dec. 22, 2021) Copy Citation UNITED STATES PATENT AND TRADEMARK OFFICE UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www.uspto.gov APPLICATION NO. FILING DATE FIRST NAMED INVENTOR ATTORNEY DOCKET NO. CONFIRMATION NO. 15/089,728 04/04/2016 Felice DiMascio 100160-US4 4607 26384 7590 12/22/2021 NAVAL RESEARCH LABORATORY ASSOCIATE COUNSEL (PATENTS) CODE 1008.2 4555 OVERLOOK AVENUE, S.W. WASHINGTON, DC 20375-5320 EXAMINER JAIN, SALIL ART UNIT PAPER NUMBER 1795 NOTIFICATION DATE DELIVERY MODE 12/22/2021 ELECTRONIC Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. Notice of the Office communication was sent electronically on above-indicated "Notification Date" to the following e-mail address(es): patent.docketing@nrl.navy.mil PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE BEFORE THE PATENT TRIAL AND APPEAL BOARD Ex parte FELICE DIMASCIO, DENNIS R. HARDY, M. KATHLEEN LEWIS, HEATHER D. WILLAUER, and FREDERICK WILLIAMS Appeal 2021-000842 Application 15/089,728 Technology Center 1700 Before TERRY J. OWENS, KAREN M. HASTINGS, and MERRELL C. CASHION, JR., Administrative Patent Judges. OWENS, Administrative Patent Judge. DECISION ON APPEAL STATEMENT OF THE CASE Pursuant to 35 U.S.C. § 134(a), the Appellant1 appeals from the Examiner’s decision to reject claims 1–18. We have jurisdiction under 35 U.S.C. § 6(b). We AFFIRM IN PART. 1 “Appellant” refers to “applicant” as defined in 37 C.F.R. § 1.42. The Appellant identifies the real party in interest as the Government of the United States of America, as represented by the Secretary of the Navy (Appeal Br. 2). Appeal 2021-000842 Application 15/089,728 2 CLAIMED SUBJECT MATTER The claims are directed to an apparatus for extracting carbon dioxide and hydrogen from seawater. Claim 1, reproduced below, illustrates the claimed subject matter: 1. An apparatus for treating seawater, comprising: an anode compartment including an anode; a cathode compartment including a cathode; a central compartment, wherein the central compartment contains either no material or only inert media, and wherein the central compartment is between the anode and cathode compartments; cation-permeable membranes separating the cathode and anode compartments from the central compartment; a seawater inlet in the central compartment; a continuous flow of seawater into the seawater inlet and through the central compartment, wherein carbon dioxide is generated in the central compartment when the flow of seawater is present; an anode water inlet in the anode compartment, wherein hydrogen ions are generated in the anode compartment when water is present; a cathode water inlet in the cathode compartment, wherein dihydrogen gas is generated in the cathode compartment when water is present; a power supply for applying current to the cathode and anode to create the driving force for an ion exchange substitution reaction where sodium ions are exchanged for hydrogen ions in the central compartment using an electrically driven membrane process; a dihydrogen gas outlet in the cathode compartment; a dihydrogen gas exit stream exiting the dihydrogen gas outlet; and an applied current from the power supply controlling a molar ratio of dihydrogen gas in the dihydrogen gas exit stream to carbon dioxide simultaneously generated in the central compartment. Appeal 2021-000842 Application 15/089,728 3 REFERENCES The prior art relied upon by the Examiner is: Name Reference Date Kaczur US 5,264,089 Nov. 23, 1993 Nakajima US 2002/0134687 A1 Sept. 26, 2002 Hartvigsen US 2007/0045125 A1 Mar. 1, 2007 Field US 2007/0187262 A1 Aug. 16, 2007 Bader US 7,392,848 B1 July 1, 2008 REJECTIONS The claims stand rejected as follows: 1) claims 1–5, 8, 10–14, and 17 under 35 U.S.C. § 102(b) over Kaczur; 2) claims 1–5, 7–14, and 16–18 under 35 U.S.C. § 103(a) over Hartvigsen in view of Kaczur, Bader, and Nakajima; and 3) claims 6 and 15 under 35 U.S.C. § 103(a) over Hartvigsen in view of Kaczur, Bader, Nakajima, and Field. OPINION Rejection under 35 U.S.C. § 102(b) The Appellant argues the claims as a group (Reply Br. 2). We therefore limit our discussion to one claim, i.e., claim 1. See 37 C.F.R. § 41.37(c)(1)(iv) (2013). “Anticipation requires that every limitation of the claim in issue be disclosed, either expressly or under principles of inherency, in a single prior art reference.” Corning Glass Works v. Sumitomo Elec. U.S.A., Inc., 868 F.2d 1251, 1255–56 (Fed. Cir. 1989). Kaczur discloses an apparatus comprising an anode compartment (10) (col. 3, l. 3); a cathode compartment (30) (col. 3, ll. 3–4); a central ion exchange compartment (20), containing a spacer material (22), between the anode compartment and the cathode compartment (col. 3, ll. 4–6, 65–68; Appeal 2021-000842 Application 15/089,728 4 Fig. 2); cation permeable ion-exchange membranes (16, 24) separating, respectively, the anode and cathode compartments from the central compartment (col. 3, ll. 56–59; Fig. 2); a continuous flow inlet (55) to the central compartment (col. 4, ll. 26; col. 5, ll. 17, 22–23; Fig. 3); a water inlet in each of the anode and cathode compartments (Fig. 3), a power supply for applying current to the cathode and anode to create the driving force for an ion exchange substitution reaction where sodium ions are exchanged for hydrogen ions in the central compartment using an electrically driven membrane process (col. 3, ll. 8–12; col. 8, ll. 37–42); and a gas outlet in the cathode compartment (Fig. 2). The continuous flow inlet to the central compartment appears to be capable of flowing seawater instead of deionized water to the central compartment, and the central compartment appears to be capable of carbon dioxide being generated therein when seawater is present. The anode compartment appears to be capable of hydrogen ions being generated therein when water is present, and the cathode compartment appears to be capable, when water is present, of dihydrogen gas being generated therein and exiting the gas outlet. 2 The exemplified power supply current densities include 120 and 150 mA/cm2 (col. 14, ll. 18–19; col. 15, ll. 9–10) which are within the Appellant’s range of 5 to 200 mA/cm2 (Spec. ¶ 37), thereby indicating that the power supply is capable of performing the functions of the Appellant’s power supply, including controlling a molar ratio of dihydrogen gas in the cathode compartment gas outlet to carbon dioxide simultaneously generated in the central compartment. 2 The Appellant’s recited seawater, carbon dioxide, hydrogen ions, sodium ions, and dihydrogen gas are not components of the claimed apparatus. Appeal 2021-000842 Application 15/089,728 5 The Appellant argues: Kaczur’s process cannot anticipate the claims of the present invention because it cannot treat seawater. Kaczur does not disclose a seawater inlet in the central compartment or a continuous flow of seawater, and in fact teaches away from these because seawater is not substantially free of anionic and cationic impurities. The Appellant claims an apparatus, not a process for treating seawater. See Hewlett-Packard Co. v. Bausch & Lomb Inc. 909 F.2d 1464, 1468 (Fed. Cir. 1990) (“apparatus claims cover what a device is, not what a device does”). As set forth above, Kaczur’s apparatus has the recited components of the Appellant’s apparatus and appears to be capable of treating seawater when seawater instead of Kaczur’s alkali metal chlorate solution is fed to the central compartment (col. 5, ll. 15–23). Hence, we are not persuaded of reversible error in the rejection under 35 U.S.C. § 102(b). Rejections under 35 U.S.C. § 103(a) We need address only the independent claims (1 and 10).3 Hartvigsen discloses a batch process for producing synthesis gas (a mixture of CO and H2) (¶ 30). The process is carried out using a two- compartment electrochemical cell (12) comprising an anode chamber (14) separated from a cathode chamber (16) by a sodium-conducting membrane (18) (¶ 30; Fig. 1). In the anode chamber, water is decomposed to hydrogen and oxygen, and sodium carbonate is decomposed to sodium ions, carbon dioxide, and water (¶¶ 31, 32, 34; Fig 4). In the cathode chamber, water is reduced to form hydrogen gas and generate hydroxyl ions that react 3 The Examiner does not rely upon Field for any disclosure that remedies the deficiency in the references applied to the independent claims (Final 10–11). Appeal 2021-000842 Application 15/089,728 6 with sodium ions migrating through the membrane to form sodium hydroxide (¶¶ 34, 36; Fig 4). The carbon dioxide from the anode chamber is combined with the hydrogen from the cathode chamber to form synthesis gas (¶ 40; Fig. 5). Kaczur discloses a continuous process for producing chlorine dioxide, comprising, as its first steps, feeding an aqueous solution of alkali metal chlorate to an electrolytic cell (4)’s ion exchange compartment (20) between an anode compartment (10) and a cathode compartment (30), electrolyzing an anolyte in the anode compartment to generate hydrogen ions, passing the hydrogen ions through a cation exchange membrane (16) into the ion exchange compartment to displace alkali metal ions and produce an aqueous solution of chloric acid and alkali metal chlorate, passing alkali metal ions from the ion exchange compartment through a cation exchange membrane (24) into the cathode compartment, and removing the aqueous solution of chloric acid and alkali metal chlorate from the ion exchange compartment, thereby producing a solution of chloric acid-alkali metal chlorate that is substantially free of anionic and cationic impurities (col. 2, l. 67; col. 3, ll. 1–20; Figs. 1, 3).4 4 Regarding Bader and Nakajima, the Examiner states (Final 8): Bader is cited to show that acidifying seawater results in production of carbon dioxide (see column 14, lines 31-33), similar to production of carbon dioxide from a sodium carbonate solution as taught by Hartvigsen. Nakajima is cited to show that it was common in the electrochemical art to use seawater as the starting material for electrochemical processes, wherein seawater comes in contact with cation exchange membranes, cathodes, and anodes (see Fig. 1 and paragraph 0016). Appeal 2021-000842 Application 15/089,728 7 The Examiner finds (Final 4–5): Although the processes performed by Hartvigsen and Kaczur are different, the structures of the electrochemical cells used by Hartvigsen and Kaczur are very similar, as can be seen from the fact that Kaczur's three-compartment cell of Fig. 1 is also divided into three compartments by two cation exchange membranes exactly as Hartvigsen’s three-compartment cell of Fig. 4 is also divided into three compartments by two cation exchange membranes. One of ordinary skill in the electrochemical art wanting to modify the electrochemical cell of Hartvigsen so as to make it capable of performing a continuous process would have looked to the art to find a reference like Kaczur, wherein continuous processes are performed in similar apparatus, and incorporate after suitable adaptation those features of the system of Kaczur which are suitable for converting Hartvigsen’s batch process into a continuous process, for example, inlets for various compartments, pumps, liquid-gas separators, recycle streams, etc. The Examiner concludes (Final 5): Therefore, it would have been obvious to a person having ordinary skill in the art at the time of the effective filing date of the application for the claimed invention to modify the electrochemical cell taught by Hartvigsen by adding an inlet in the central compartment; an anode water inlet in the anode compartment, and a cathode water inlet in the cathode compartment, pumps, a dihydrogen gas outlet, and other suitable features required for converting the batch process of Hartvigsen into a continuous process, as taught by Kaczur. The person with ordinary skill in the art would have been further motivated to make this modification, because one of ordinary skill in the art would have recognized the advantages of a continuous process over a batch process, particularly better process control and savings in labor cost. In any case, the courts have held that claimed continuous operation would have been obvious in light of the batch process of the prior art. In re Appeal 2021-000842 Application 15/089,728 8 Dilnot, 319 F.2d 188, 138 USPQ 248 (CCPA 1963). See MPEP 2144.04 (V) (E). Setting forth a prima facie case of obviousness requires establishing that the applied prior art would have provided one of ordinary skill in the art with an apparent reason to modify the prior art to arrive at the claimed invention. See KSR Int’l Co. v. Teleflex Inc., 550 U.S. 398, 418 (2007). The Examiner does not establish that the similarities pointed out by the Examiner between Kaczur’s apparatus for making chlorine dioxide from alkali metal chlorate and Hartvigsen’s apparatus for obtaining carbon dioxide and hydrogen for producing synthesis gas would have provided one of ordinary skill in the art with an apparent reason to convert Hartvigsen’s apparatus to a continuous process by incorporating suitable “inlets for various compartments, pumps, liquid-gas separators, recycle streams, etc.” adapted from Kaczur’s apparatus to provide better process control and reduce labor cost (Final 5). Thus, the record indicates that the Examiner’s combination of the references is based upon impermissible hindsight in view of the Appellant’s disclosure. See In re Warner, 379 F.2d 1011, 1017 (CCPA 1967) (“A rejection based on section 103 clearly must rest on a factual basis, and these facts must be interpreted without hindsight reconstruction of the invention from the prior art”). The Examiner’s finding that “the courts have held that claimed continuous operation would have been obvious in light of the batch process of the prior art” (Final 5) is based upon a per se rule of obviousness. As stated by the Federal Circuit in In re Ochiai, 71 F.3d 1565, 1572 (Fed. Cir. 1995), “reliance on per se rules of obviousness is legally incorrect and must cease.” Appeal 2021-000842 Application 15/089,728 9 For the above reasons, we reverse the rejections under 35 U.S.C. § 103(a). CONCLUSION The rejection under 35 U.S.C. § 102(b) is affirmed. The rejections under 35 U.S.C. § 103(a) are reversed. DECISION SUMMARY In summary: Claims Rejected 35 U.S.C. § Reference(s)/Basis Affirmed Reversed 1–5, 8, 10– 14, 17 102(b) Kaczur 1–5, 8, 10– 14, 17 1–5, 7–14, 16–18 103(a) Hartvigsen, Kaczur, Bader, Nakajima 1–5, 7–14, 16–18 6, 15 103(a) Hartvigsen, Kaczur, Bader, Nakajima 6, 15 Overall Outcome 1–5, 8, 10– 14, 17 6, 7, 9, 15, 16, 18 TIME PERIOD FOR RESPONSE No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § 1.136(a). See 37 C.F.R. § 1.136(a)(1)(iv). AFFIRMED-IN-PART Copy with citationCopy as parenthetical citation