Taiwan Semiconductor Manufacturing Company, Ltd.Download PDFPatent Trials and Appeals BoardOct 26, 20202019005580 (P.T.A.B. Oct. 26, 2020) Copy Citation UNITED STATES PATENT AND TRADEMARK OFFICE UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www.uspto.gov APPLICATION NO. FILING DATE FIRST NAMED INVENTOR ATTORNEY DOCKET NO. CONFIRMATION NO. 15/162,115 05/23/2016 Ji-Soo Park TSMP2100387US03 9705 43859 7590 10/26/2020 SLATER MATSIL, LLP/TSMC 17950 PRESTON ROAD, SUITE 1000 DALLAS, TX 75252 EXAMINER TRAN, TONY ART UNIT PAPER NUMBER 2894 NOTIFICATION DATE DELIVERY MODE 10/26/2020 ELECTRONIC Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. Notice of the Office communication was sent electronically on above-indicated "Notification Date" to the following e-mail address(es): docketing@slatermatsil.com PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE ____________ BEFORE THE PATENT TRIAL AND APPEAL BOARD ____________ Ex parte JI-SOO PARK ____________ Appeal 2019-005580 Application 15/162,115 Technology Center 2800 ____________ Before JAMES C. HOUSEL, BRIAN D. RANGE, and DEBRA L. DENNETT, Administrative Patent Judges. DENNETT, Administrative Patent Judge. DECISION ON APPEAL1 Pursuant to 35 U.S.C. § 134(a), Appellant2 appeals from the Examiner’s decision to reject claims 1–20 of Application 15/162,115, which constitute all the claims pending in this application. We have jurisdiction under 35 U.S.C. § 6(b). 1 In our Decision, we refer to the Specification (“Spec.”) of Application No. 15/162,115 filed May 23, 2016; the Final Office Action dated Jan. 19, 2018 (“Final Act.”); the Advisory Action dated Apr. 6, 2018 (“Adv. Act.”); the Appeal Brief filed Aug. 24, 2018 (“Appeal Br.”); the Examiner’s Answer dated May 13, 2019 (“Ans.”); and the Reply Brief filed July 15, 2019 (“Reply Br.”). 2 We use the word “Appellant” to refer to “applicant” as defined in 37 C.F.R. § 1.42. Appellant identifies the real party in interest as TAIWAN SEMICONDUCTOR MANUFACTURING COMPANY, LTD. Appeal Br. 2. Appeal 2019-005580 Application 15/162,115 2 For the reasons set forth below, we AFFIRM IN PART. STATEMENT OF THE CASE The ’115 Application relates to epitaxial growth of a crystalline material. Spec. ¶ 2. The Inventor indicates that dislocation density of epitaxially grown material can be unacceptably high for many applications. Id. ¶ 4. According to the Inventor, Aspect Ratio Trapping (ART) is a defect reduction technique that mitigates defects, causing defects to terminate at non-crystalline, e.g., dielectric sidewalls. Id. ¶ 5. The Inventor states that ART uses high aspect ratio openings such as trenches or holes to trap dislocations, preventing defects from reaching the epitaxial film surface. Id. Figure 7A, reproduced below from the ’115 Application, shows a cross section of an epitaxially grown crystalline material using ART. Id. In Figure 7A crystalline material 140 is epitaxially grown on substrate 100. Id. By confining the crystalline growth within an opening (e.g., trench) with a sufficiently high aspect ratio (e.g., 1 or greater), defects 150 formed while epitaxially growing the crystalline material 140 travel to and end at the insulator sidewalls 130, and crystalline material 140 continues to grow without the continued growth of defects 150. Id. Appeal 2019-005580 Application 15/162,115 3 The Inventor indicates that it is desirable to obtain a smooth crystal surface within opening to avoid interface variances between layers that affect the functionality of an interface from one device to another device on the same substrate. Id. ¶ 7. Thus, according to the Inventor, there is a need to reduce the surface roughness of crystalline materials grown in an ART opening. Id. ¶ 10. Claims 1, 12, and 19 reproduced below from the Claims Appendix of the Appeal Brief illustrate the claimed subject matter: 1. A semiconductor structure comprising: a trench having at least two sidewalls, an insulating layer formed on said at least two sidewalls, the trench having a bottom formed of a crystalline substrate; and an epitaxial crystalline material within the trench, the epitaxial crystalline material being lattice-mismatched with the crystalline substrate, the epitaxial crystalline material having a top surface, wherein the top surface of the epitaxial crystalline material: is below an uppermost surface of the insulating layer; has a root mean square surface roughness of 5 nm or less; is a distinct surface from sidewalls of the epitaxial crystalline material; and comprises at least two facets. 12. A structure comprising: an insulator having an opening to a crystalline substrate, the opening being defined by a pair of non-crystalline sidewalls, the pair of non-crystalline sidewalls including a first noncrystalline sidewall and a second non-crystalline sidewall; and Appeal 2019-005580 Application 15/162,115 4 an epitaxial crystalline material within the opening of the insulator, the epitaxial crystalline material being lattice- mismatched with the crystalline substrate, the epitaxial crystalline material having at least one top surface with a root mean square surface roughness of 5 nm or less, the at least one top surface of the epitaxial crystalline material extending from the first non-crystalline sidewall to the second non-crystalline sidewall, the at least one top surface being below an uppermost surface of the insulator. 19. A structure comprising: a confined area on a substrate, the confined area defined by a pair of laterally opposed portions of oxide material disposed over the substrate; and a first epitaxial material on the confined area of the substrate between the pair of laterally opposed portions of oxide material, the first epitaxial material having a top surface with a root mean square surface roughness of 5 nm or less, the top surface extending from a first sidewall of one of the pair of laterally opposed portions of oxide material to a second sidewall of another of the pair of laterally opposed portions of oxide material. REFERENCES The Examiner relies on the following references in rejecting the claims: Name Reference Date Pan et al. (“Pan”) US 2007/0025670 A1 Feb. 1, 2007 Currie et al. (“Currie ’465”)3 US 2007/0054465 A1 Mar. 8, 2007 Currie et al. (“Currie ’467”) US 2007/0054467 A1 Mar. 8, 2007 Kim et al. (“Kim”) US 2008/0163814 A1 July 10, 2008 3 Currie ’465 and Currie ’467 have the same filing date, publication date, figures, and appear to have identical disclosures. Compare Currie ’465 Appeal 2019-005580 Application 15/162,115 5 REJECTIONS The Examiner rejects claims under 35 U.S.C. § 1034 as follows: (1) claims 19 and 20 over Pan in view of Kim; and (2) claims 1–18 over Pan in view of Kim, and further in view of Currie. Final Act. 2–8. DISCUSSION Rejection of claims 19 and 20 over Pan in view of Kim5 Claim 19 is independent and claim 20 depends from it. Appeal Br. 20. The Examiner finds claims 19 and 20 obvious over Pan in view of Kim. Final Act. 24. Appellant does not address the rejection of these claims in the Appeal Brief. See generally Appeal Br. We summarily sustain the rejection of claims 19 and 20 as obvious over the combination of Pan and Kim. Rejection of claims 1–18 over Pan in view of Kim and Currie6 with Currie ’467. The Examiner cites Currie ’465, paragraph 41, against claims 1–5, 7–15, and 18, and Currie ’467, paragraph 27, against claims 6, 16, and 17. Compare Final Act. 4 with id. at 8. Appellant does not identify which published application is cited. See, e.g., Appeal Br. 10. We cite to “Currie” generically, as there is no difference between the applications in terms of the figures and text cited. 4 Because this application was filed after the March 16, 2013, effective date of the America Invents Act, we refer to the AIA version of the statute. 5 The Examiner did not enter Appellant’s proposed amendments to claims 19 and 20. Adv. Act. 1. 6 In the Final Office Action, the Examiner rejects claims 1–5, 7–15, and 18 over Pan in view of Kim and further in view of Currie ’465. Final Act. 4. The Examiner mentions Kerber in discussing the rejection of claim 11. Id. at 7. The Examiner rejects claims 6, 16, and 17 over “Pan/Kerber as applied Appeal 2019-005580 Application 15/162,115 6 We review the appealed rejections for error based upon the issues identified by Appellant and in light of the arguments and evidence produced thereon. Ex parte Frye, 94 USPQ2d 1072, 1075 (BPAI 2010) (precedential), (cited with approval in In re Jung, 637 F.3d 1356, 1365 (Fed. Cir. 2011)) (“[I]t has long been the Board’s practice to require an applicant to identify the alleged error in the [E]xaminer’s rejections.”). After considering the evidence presented in this Appeal and each of Appellant’s arguments, we are persuaded that Appellant identifies reversible error in the Examiner’s rejection of claims 1–18. Appellant argues claims 1–4, 6–8, 12, and 14–18 as a group. Appeal Br. 7–12. We select claim 1 as representative of the group. 37 C.F.R. § 42.37(c)(1)(iv). To the extent necessary, we address claims 5, 9–11, and 13 separately below. Claims 1 and 12 are independent and contain similar limitations. See Appeal Br. 18, 19. The limitations that are at issue first in this appeal regarding this group of claims are (1) claim 1’s recitation “the top surface of the epitaxial crystalline material: is below an uppermost surface of the insulating layer; has a root mean square surface roughness of 5 nm or less”; and (2) claim 12’s recitation “the epitaxial crystalline material having at to claim 1 and 12 above, and further in view of Currie.” Id. at 8. Kerber is not otherwise identified in the Final Office Action. See generally id. In the Remarks accompanying Appellant’s Nov. 21, 2017 Amendment After Final, Appellant states that the Examiner acknowledged in an Oct. 23, 2017 interview that references to “Kerber” appearing in the Aug. 21, 2017 Non-Final Office Action were typographical errors and should be replaced with “Kim.” The prosecution history is consistent with the Examiner intending to replace “Kerber” with “Kim.” Appeal 2019-005580 Application 15/162,115 7 least one top surface with a root mean square surface roughness of 5 nm or less . . . the at least one top surface [of the epitaxial crystalline material] being below an uppermost surface of the insulator.” Id. at 7. With regard to claim 1, the Examiner finds that Pan teaches a semiconductor structure comprising a trench having at least two sidewalls, an insulating layer formed on said at least two sidewalls, the trench having a bottom formed of a crystalline substrate, and an epitaxial crystalline material within the trench, the epitaxial crystalline material being lattice-mismatched with the crystalline substrate, the epitaxial crystalline material having a top surface which is a distinct surface from sidewalls of the epitaxial crystalline material, and comprises at least two facets. Final Act. 4 (citing Pan FIGS. 4A-4B, ¶¶ 20–21). The Examiner acknowledges that Pan does not teach the epitaxial crystalline material has a top surface with a root mean square surface roughness of 5 nm or less, but relies on Kim for this teaching. Id. at 5 (citing Kim ¶ 80). The Examiner determines that it would have been obvious for one of ordinary skill in the art as of the effective filing date of the invention to combine the teachings of Pan and Kim for the purpose of reducing defects, as taught by Kim. Id. The Examiner finds that the combination of Pan and Kim fails to teach the top surface of the epitaxial crystalline material is below an uppermost surface of the insulating later. Id. The Examiner finds that Currie ’465 teaches this limitation. Id. (citing Currie ’465 FIG. 5B, ¶ 41). The Examiner determines that it would have been obvious to one of ordinary skill in the art to incorporate this teaching into Pan’s modified semiconductor device for the purpose of enhanced mobility, as taught by Currie. Id. Appeal 2019-005580 Application 15/162,115 8 Appellant argues that none of the cited references teaches or suggests a structure that can achieve the claimed roughness for a top surface of an epitaxial crystalline material below an uppermost surface of the insulating layer or insulator. Appeal Br. 7. More specifically, Appellant argues that the Examiner’s rejection requires taking the surface roughness of the top surface of Kim’s layer 112 that is achieved only above the top surface of Kim’s dielectric mask 106, and applying it to the top surfaces of layers 540A and 540B of Currie, which are below the top surface of Currie’s insulator layer 510. Id. at 7–8. Appellant illustrates the point with an annotated figure combining Kim’s Fig. 1(f) and Currie’s Fig. 5A, reproduced below. Id. at 8. The portion of Kim’s Fig. 1 included in Appellant’s combined illustration shows a schematic of final SLEO (sidewall lateral epitaxial overgrowth) regrowth with window regions 108 and sidewalls 110 made by etching. Kim ¶¶ 53, 71. Layer 112, which is typically non-polar m-plane GaN material, is grown in window regions 108 and on sidewalls 110. Id. ¶ 72. As layer 112 starts to grow above the top surface 114 of dielectric mask 106, layer 112 starts growing laterally along top surface 114 until one Appeal 2019-005580 Application 15/162,115 9 lateral growth 116 meets up with another lateral growth 118 as a given intersection 120. Id. At that point, layer 112 starts growing vertically. Id. Currie’s Fig. 5A as included in Appellant’s combined figure depicts a schematic cross-sectional side view illustrating formation of semiconductor structures. Currie ¶ 24. Fig. 5A shows “epitaxially deposited active area material(s) only partially fill openings 520A and 520B defined in an insulator layer 510 and extending to the substrate 500. Thus, top surfaces of active-area regions 540A and 540B do not reach to the top surface 560 of the insulator layer.” Id. ¶ 41. According to Appellant, one of ordinary skill in the art would not have had a reasonable expectation of success in combining the three references, and the combination fails to provide an enabling disclosure to achieve the challenged features of claim 1. Appeal Br. 8. Appellant argues that the top surface of layer 112 in Kim’s Fig. 1(f) is not below an uppermost surface of an insulating layer. Id. at 9. Appellant quotes Kim as teaching “[a]s layer 112 starts to grow above the top surface 114 of dielectric mask 106, layer 112 starts growing laterally along top surface 114, until one lateral growth 116 meets up with another lateral grown 118 at a given intersection 120.” Id. (quoting Kim ¶ 72). Appellant argues that “it is only the coalescing of lateral growth fronts 116 and 118 at intersections 120 . . . over a top surface of dielectric mask 106 to achieve the asserted surface roughness at ‘the top of layer 112 . . . .’” Id. Appellant argues that Kim discloses the surface roughness is a result of growing layer 112 above the uppermost surface of the insulating layer. Id. at 10. Appellant contends that Currie provides no teaching regarding roughness of the top surfaces of the layers 540A and 540B. Id. Appellant argues that Currie’s disclosure of achieving low root mean square surface Appeal 2019-005580 Application 15/162,115 10 roughness values for wafer bonding surfaces in other embodiments does not apply to layers 540A and 540B because they are not wafer bonding surfaces. Id. at 10–11. Appellant also contends that the rejection of claim 1 is based on impermissible hindsight, as none of the cited references teaches or suggests a structure with a top surface of an epitaxial crystalline material having the claimed roughness and being below an uppermost surface of the insulating layer or insulator. Id. at 11. In response to Appellant’s arguments, the Examiner finds that Pan, Kim, and Currie teach the same inventive concept wherein the epitaxial crystalline material grows in the trench formed in the insulating layer. Ans. 4 (“Since, all three Pan, Kim and Currie teach the same inventive concept wherein the epitaxial crystalline material grow in the trench form between the insulating layer 18 and 2 of Pan, FIGS. 4B and 2C; SiO2 masking materials 106 of Kim, FIG. 1 (d); and 510 of Currie, FIG. 5A.”). The Examiner also cites Currie as teaching “a root mean square surface roughness of the surface 280 does not exceed about 1 nm,” and finds that Currie can achieve the claimed roughness for a top surface of an epitaxial crystalline material below the upper surface, making it reasonable to combine the three references to yield a predictable result. Id. (citing Currie ¶ 34). Appellant persuades us of reversible error in the Examiner’s rejection of claim 1. We agree with Appellant’s position that the combined references do not teach a structure with the claimed roughness for a top surface of an epitaxial crystalline material below an uppermost surface of the insulating layer. See Appeal Br. 7. Appeal 2019-005580 Application 15/162,115 11 Kim teaches defect reduction of non-polar m-plane with sidewall lateral epitaxial overgrowth. Kim ¶ 39. The purpose of Kim is to minimize defect densities in nitride materials by employing lateral overgrowth from sidewalls of etched nitride material through a dielectric mask. Id. ¶ 47. As Kim describes: The method includes depositing a patterned mask on non-polar or semi-polar III-Nitride template, etching the template material down to various depths through openings in the mask, and regrowing the non-polar or semi-polar epitaxial film by coalescing laterally from the tops of the sidewalls before the vertically growing material from the trench bottoms reaches the surface. The coalesced features grow through the openings of the mask, and grow laterally over the dielectric mask until a fully coalesced continuous film is achieved. Id. (emphasis added). Therefore, achieving the root mean square surface roughness of the upper surface (the top of layer 112 in step (f) of FIG. 1) that the Examiner relies on requires lateral overgrowth of the epitaxial layer over the dielectric mask. Kim does not teach that the root mean square roughness of 5 nm or less can be achieved “wherein the top surface of the epitaxial crystalline material is below an uppermost surface of the insulating layer,” as required by claim 1. Currie teaches achieving low root mean square surface roughness values for wafer bonding surfaces by performing chemical mechanical polishing. Currie ¶ 32. Currie discloses the difficulty of stopping selective epitaxy precisely at the point that the openings are filled with active-area materials, and explains that portions extending above the top surface of the insulator layer may be removed by planarization so that the surface of the active-area regions is substantially coplanar with the top surface of the insulator layer. Id. ¶ 30. Currie discloses an implementation of Appeal 2019-005580 Application 15/162,115 12 embodiments in which epitaxially deposited active area material(s) only partially fill the openings defined in the insulator, and the top surfaces of active-area regions 540A and 540B do not reach to the top surface of the insulator layer. Id. ¶ 41. However, Currie’s disclosure of achieving low root mean square surface roughness values for wafer bonding surfaces by performing chemical mechanical polishing does not apply to the surfaces of these partially filled openings. See id. ¶¶ 32, 41. Curries teaches that the partially filled openings can be left empty or filled with a dielectric material forming buffer regions over the active-area regions. Id. ¶ 41. If the dielectric material is deposited over the entire surface of the active-area regions and top surface of the insulator layer, the structure may then be planarized such that any dielectric material formed over top surface of the insulator layer is removed, and the dielectric material remains only over active-area regions. Id. Under such circumstances (where the windows or trenches shown in FIG. 5A are filled to the top with dielectric), the surface may be planarized. Id. Thus, Currie indicates that the windows or trenches must be filled to the top in order to achieve a smooth, planarized surface. Whether or not a person of ordinary skill in the art would have had a reasonable expectation that a particular combination of references would work is a pure question of fact. Alza Corp. v. Mylan Labs., Inc., 464 F.3d 1286, 1289 (Fed. Cir. 2006). A reasonable expectation of success must be founded in the prior art to show obviousness. In re Vaeck, 947 F.2d 488, 493 (Fed. Cir. 1991). Given the teachings of Kim and Currie discussed above, we determine that the Examiner has not adequately established that one of ordinary skill in the art as of the effective filing date of the invention would have had a reasonable expectation of success in achieving the structure claimed in claim 1. Appeal 2019-005580 Application 15/162,115 13 We do not sustain the rejection of claim 1 as obvious over Pan in view of Kim and Currie. Because claims 2–18 include the same limitation found lacking in the cited art, we also do not sustain the rejection of these claims as obvious over the same references. DECISION SUMMARY In summary: Claims Rejected 35 U.S.C. § Reference(s)/Basis Affirmed Reversed 1–5, 7–15, 18 103 Pan, Kim, Currie 1–5, 7–15, 18 6, 16, 17 103 Pan, Kim, Currie 6, 16, 17 19, 20 103 Pan, Kim 19, 20 Overall Outcome 19, 20 1–18 TIME PERIOD FOR RESPONSE No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § 1.136(a). AFFIRMED IN PART Copy with citationCopy as parenthetical citation