Shiguang LI et al.Download PDFPatent Trials and Appeals BoardOct 21, 20212020006742 (P.T.A.B. Oct. 21, 2021) Copy Citation UNITED STATES PATENT AND TRADEMARK OFFICE UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www.uspto.gov APPLICATION NO. FILING DATE FIRST NAMED INVENTOR ATTORNEY DOCKET NO. CONFIRMATION NO. 14/870,906 09/30/2015 Shiguang LI GTI-2003 3843 42419 7590 10/21/2021 PAULEY ERICKSON & SWANSON 2800 WEST HIGGINS ROAD SUITE 365 HOFFMAN ESTATES, IL 60169 EXAMINER HOLECEK, CABRENA L ART UNIT PAPER NUMBER 1776 MAIL DATE DELIVERY MODE 10/21/2021 PAPER Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE BEFORE THE PATENT TRIAL AND APPEAL BOARD Ex parte SHIGUANG LI, SHAOJUN ZHOU, HOWARD S. MEYER, and MIAO YU Appeal 2020-006742 Application 14/870,906 Technology Center 1700 Before JAMES C. HOUSEL, CHRISTOPHER C. KENNEDY, and SHELDON M. MCGEE, Administrative Patent Judges. HOUSEL, Administrative Patent Judge. DECISION ON APPEAL STATEMENT OF THE CASE Pursuant to 35 U.S.C. § 134(a), Appellant1 appeals from the Examiner’s decision to reject claims 1–6, 8–11, and 20–28. We have jurisdiction under 35 U.S.C. § 6(b). We AFFIRM. 1 We use the word “Appellant” to refer to “applicant” as defined in 37 C.F.R. § 1.42. Appellant identifies Gas Technology Institute and South Carolina Research Foundation as the real parties in interest. Appeal Brief (“Appeal Br.”) filed March 31, 2020, at 2. Appeal 2020-006742 Application 14/870,906 2 CLAIMED SUBJECT MATTER The invention recited in the claims on appeal relates to an improved method of producing high purity oxygen from air. Specification (“Spec.”) filed September 30, 2015, at 1 (Field of the Invention).2 Claim 1, reproduced below from the Claims Appendix to the Appeal Brief, is illustrative of the claimed subject matter: 1. A method of producing oxygen from an oxygen-containing gas comprising the steps of: feeding a gas to the first side of a first membrane, the gas including nitrogen and oxygen; feeding an oxygen-absorbing solvent selected from the group consisting of poly(ethyleneimine)-cobalt, cobalt porphyrins, cobalt porphyrin complexes, and combinations thereof to a second side of the first membrane; passing the oxygen through the first membrane, from the first side to the second side of the first membrane, where the oxygen is absorbed by the oxygen absorbing solvent to form an oxygen-rich carrier solution; feeding the oxygen-rich carrier solution to a first side of a second membrane; passing the oxygen from the oxygen-rich carrier solution through the second membrane, from the first side of the second membrane to a second side of the second membrane; and recovering gaseous oxygen in a purity of greater than 95% from the second side of the second membrane. 2 This Decision also cites to the Examiner’s Answer (“Ans.”) dated July 29, 2020, and the Reply Brief (“Reply Br.”) filed September 28, 2020. Appeal 2020-006742 Application 14/870,906 3 Independent claim 21 recites a method of producing oxygen from an oxygen-containing gas similar to claim 1, wherein the first membrane is in the form of one or more tubes defining a bore side (interior of the tubes) and a shell side (exterior of the tubes), such that the gas is fed to the bore side and the solvent is fed to the shell side. Independent claim 26 recites a method of producing oxygen from an oxygen-containing gas similar to claim 1, wherein the second membrane is in the form of one or more tubes defining a bore side (interior of the tubes) and a shell side (exterior of the tubes), such that the oxygen-rich carrier solution is fed to the shell side and oxygen is recovered from the bore side. REFERENCES The Examiner relies on the following prior art: Name Reference Date Bonaventura US 4,602,987 July 29, 1986 Sirkar US 6,165,253 Dec. 26, 2000 REJECTIONS The Examiner maintains, and Appellant requests our review of, the following rejections: 1. Claim 21 under 35 U.S.C. § 112(b) as indefinite; 2. Claims 1–3 and 20 under 35 U.S.C. § 103 as unpatentable over Bonaventura; and 3. Claims 1–6, 8–11, and 21–28 under 35 U.S.C. § 103 as unpatentable over Sirkar in view of Bonaventura. OPINION We review the appealed rejections for error based upon the issues Appellant identifies, and in light of the arguments and evidence produced Appeal 2020-006742 Application 14/870,906 4 thereon. Cf. Ex parte Frye, 94 USPQ2d 1072, 1075 (BPAI 2010) (precedential) (cited with approval in In re Jung, 637 F.3d 1356, 1365 (Fed. Cir. 2011) (“[I]t has long been the Board’s practice to require an applicant to identify the alleged error in the examiner’s rejections.”)). After considering Appellant’s arguments and the evidence of record, we are not persuaded of reversible error in the Examiner’s rejections for substantially the fact findings, reasoning, and conclusions set forth in the Examiner’s Answer, which we adopt as our own. We offer the following for emphasis. Rejection 1: Indefiniteness The Examiner rejects claim 21 under 35 U.S.C. § 112(b) as indefinite for reciting, on line 7, an adjective, “oxygen-absorbing,” without an associated noun. Ans. 3. The Examiner also observes that claim 21, line 9, recites “the oxygen-absorbing solvent” which lacks antecedent basis (due to the missing noun on line 7.3 Id. at 4. Appellant fails to address this rejection in the Appeal Brief (Ans. 17), but acknowledges this issue in the Reply Brief (Reply Br. 3). In doing so, Appellant also acknowledges that the Examiner’s review of claim 21 based on the noun, “solvent,” being associated with the adjective, “oxygen- absorbing,” is correct. Id. Accordingly, we summarily affirm the Examiner’s indefiniteness rejection of claim 21, but will decide the merits of the obviousness of this claim on the same basis as the Examiner. 3 We observe that an indefiniteness rejection applied against an independent claim often casts a similar indefiniteness cloud on claims dependent therefrom, unless the dependent claims provide a corrective remedy to the issue in the independent claim. Appeal 2020-006742 Application 14/870,906 5 Rejection 2: Obviousness over Bonaventura The Examiner rejects claims 1–3 and 20 under 35 U.S.C. § 103 as unpatentable over Bonaventura. Ans. 5–8. Appellant addresses claims 1, 2, and 20 separately. Claim 3 will stand or fall with claim 2 from which it depends. Claim 1 The Examiner finds that Bonaventura discloses the method substantially as recited in claim 1, except for the purity of the recovered oxygen of greater than 95%. Ans. 5–7. However, the Examiner also finds that Bonaventura teaches that some industries may require pure oxygen. Id. at 21–22. Therefore, the Examiner determines that it would have been obvious to an ordinary artisan to have optimized Bonaventura’s recovered oxygen purity involving only routine skill in the art. Id. at 7 (citing In re Aller, 220 F.2d 454, 456 (CCPA 1955) (“it is not inventive to discover the optimum or workable ranges by routine experimentation”)). Appellant argues that Bonaventura requires the added complexity and expense of first electrochemically unloading oxygen from the carrier complex and then passing the freed oxygen to the membrane for passage through the membrane. Appeal Br. 7. As such, Appellant asserts that the claimed invention requires feeding an “oxygen-rich carrier,” which “is the oxygen absorbing solvent with the oxygen absorbed.” Id. Because Bonaventura teaches “disassociat[ing] the oxygen from [the] complex by electrodes upstream of the membrane,” Appellant contends that Bonaventura fails to disclose or suggest feeding an oxygen-rich carrier solution to a first side of a second membrane. Id. Appellant also contends that there is no basis in the record, outside of Appellant’s disclosure, for modifying Bonaventura Appeal 2020-006742 Application 14/870,906 6 to feed oxygen complex directly to the second membrane without first passing the oxidizing station. Id. at 8. Appellant further argues that Bonaventura fails to show or suggest recovering gaseous oxygen in a purity of greater than 95% from the second side of the second membrane. Appeal Br. 8. In this regard, Appellant asserts that Bonaventura discloses directly utilizing oxygen in a fuel cell without release of the oxygen in gaseous form. Id. Appellant’s arguments are not persuasive of reversible error. Contrary to Appellant’s arguments that Bonaventura requires first electrochemically unloading oxygen from the carrier complex and then passing the freed oxygen to the membrane for passage through the membrane, Bonaventura actually teaches that this step may be omitted. For example, Bonaventura teaches that the “unloading of oxygen may be accomplished merely by reducing the pressure of oxygen at the unloading station.” Bonaventura 7:60–63. Bonaventura also teaches that “[i]n an embodiment of the invention that is particularly useful for purifying oxygen from air, the electrochemical cell can be eliminated.” Id. at 35:47–49; see also id. at 22:26–33 (discussing that oxygen can be released “without requiring oxidation or reduction by an electrochemical cell”). Bonaventura teaches that such an embodiment (lacking an electrochemical cell) “takes advantage of the reversible nature of the oxygen binding reaction itself.” Id. at 35:52–53. According to Bonaventura, the recovery of gaseous oxygen can be accomplished by connecting an inlet port of a compressor to the second side of the second membrane, thereby producing compressed, purified oxygen. Id. at 35:58–68. In addition, Bonaventura compares the disclosed process and system to a typical oxygen production facility producing 95% oxygen, which Appeal 2020-006742 Application 14/870,906 7 Bonaventura characterizes as a lower purity product than the disclosed invention. Id. at 35:31–46. Thus, even if claim 1 excludes electrochemically unloading oxygen from the carrier complex, Bonaventura teaches an embodiment without this electrochemical unloading step and suggests recovery of gaseous oxygen in a purity greater than 95%. Notwithstanding Bonaventura’s alternative embodiment, we note that claim 1 recites the method steps using the transitional term, “comprising.” “The word ‘comprising’ transitioning from the preamble to the body signals that the entire claim is presumptively open-ended.” Gillette Co. v. Energizer Holdings, Inc., 405 F.3d 1367, 1371–1372 (Fed. Cir. 2005). “‘Comprising’ is a term of art used in claim language which means that the named elements are essential, but other elements may be added and still form a construct within the scope of the claim.” Genentech, Inc. v. Chiron Corp., 112 F.3d 495, 501 (Fed. Cir. 1997). Thus, Bonaventura’s embodiment utilizing electrochemical unloading steps is not excluded from claim 1, at least by virtue of the transitional term. We further note that claim 1 recites that a gas including oxygen is fed to the first side of a first membrane and an oxygen-absorbing solvent is fed to the second side of the first membrane, and oxygen passes through the membrane and is absorbed by the solvent “to form an oxygen-rich carrier solution.” There is no dispute that Bonaventura teaches both of these steps. Claim 1 further recites that the oxygen-rich carrier solution is fed to a first side of a second membrane. Here, Appellant contends that Bonaventura fails to feed the oxygen-rich carrier solution to the first side of a second membrane because Bonaventura’s oxygen-rich carrier solution is fed to an electrochemical cell to release oxygen from the carrier. However, though Appeal 2020-006742 Application 14/870,906 8 oxygen is released from the carrier in this embodiment, Bonaventura teaches that the freed oxygen and carrier solution are fed to the first side of the second membrane. Bonaventura 20:16–51. Claim 1 does not require that the oxygen-rich carrier solution is fed directly to the second membrane, nor that the oxygen remain absorbed onto the carrier at the time the solution is fed to the second membrane. Because Bonaventura’s solution includes both the oxygen absorbed onto the carrier from the first membrane and the carrier, this solution is still the oxygen-rich carrier solution. Thus, even Bonaventura’s electrochemical embodiment feeds the oxygen-rich carrier solution to the second membrane as claim 1 requires. Further, although Bonaventura discloses that this embodiment may be combined with a fuel cell to directly deliver oxygen to the fuel cell without release of gaseous oxygen (id. at 20:52–67), this disclosure is merely one possible use of this embodiment. Bonaventura also discloses this embodiment may be used to produce gaseous oxygen. Id. at 20:16–18. In addition, Appellant fails to rebut or otherwise address the Examiner’s position that optimizing Bonaventura’s recovered oxygen purity involves only routine skill in the art and, therefore, would have been obvious to one of ordinary skill in the art.4 4 We note the dispute between the Examiner and Appellant regarding whether some oxygen would remain bound to Bonaventura’s carrier when fed to the second membrane after passing through the electrochemical oxygen unloading station. Compare Ans. 18 and 20 with Reply Br. 2–3. However, because we agree with the Examiner that Bonaventura feeds oxygen-rich carrier solution to the second membrane in both the direct embodiment and in the indirect embodiment as discussed above, resolution of this dispute is unnecessary to our Decision. Appeal 2020-006742 Application 14/870,906 9 Claim 2 With regard to claim 2, the Examiner finds that Bonaventura teaches that the gas is fed to the first side of the first membrane under atmospheric pressure, which the Examiner interprets as “using pressure.” Ans. 7. However, Appellant argues that feeding a gas to a membrane using pressure, as claim 2 requires, is different from simply having a membrane in contact with a gas under atmospheric pressure. Appeal Br. 8. This argument is not persuasive because Appellant fails to explain in any detail why the claim 2 limitation is distinguished from a gas under atmospheric pressure. Indeed, Bonaventura recognizes that the transport of oxygen across the membranes depends in part on the partial pressure of oxygen on opposing sides of the membranes. Bonaventura 8:20–34, 15:31–40, 17:34–42 and 53–61, 22:26– 33. As the Examiner finds, atmospheric pressure is 14.7 psi (typically absolute and at sea level), such that gas is fed to the first side of the membrane under pressure. Ans. 22. Accordingly, we sustain the Examiner’s obviousness rejection of claim 2. Claim 20 With regard to claim 20, the Examiner finds that although Bonaventura fails to expressly teach producing gaseous oxygen in a purity of greater than 99%, Bonaventura nonetheless suggests producing pure oxygen (purity greater than 99%). Ans. 22–23. Appellant merely recites the limitation of claim 20 and asserts that Bonaventura fails to disclose or suggest this limitation. Skeletal arguments or arguments merely amounting to assertions that the references do not disclose or suggest certain claim limitations are not arguments for separate patentability within the meaning of 37 C.F.R. § 41.37(c)(1)(iv). See In re Lovin, 652 F.3d 1349, 1356–57 Appeal 2020-006742 Application 14/870,906 10 (Fed. Cir. 2011). Accordingly, we sustain the Examiner’s obviousness rejection of claim 20. Rejection 3: Obviousness over Sikar and Bonaventura The Examiner rejects claims 1–6, 8–11, and 21–28 under 35 U.S.C. § 103 as unpatentable over Sirkar in view of Bonaventura. Ans. 8–17. Appellant does not argue the claims under this rejection separately. We select claim 1 as representative; claims 2–6, 8–11, and 21–28 stand or fall with claim 1. 37 C.F.R. § 41.37(c)(1)(iv) (2019). The Examiner finds that Sirkar discloses the method substantially as recited in claim 1, except for recovery of gaseous oxygen at a purity of greater than 95% and the use of an oxygen absorbing solvent selected from the group consisting of poly(ethyleneimine)-cobalt, cobalt porphyrins, cobalt porphyrin complexes, and combinations thereof. Ans. 8–9. However, the Examiner finds that Bonaventura teaches that such compounds were known in the art as oxygen-absorbing carriers for reversible binding of oxygen. Id. at 9. In addition, the Examiner finds that Bonaventura teaches recovery of gaseous oxygen at a purity of at least 95%. Id. The Examiner concludes that it would have been obvious to include Bonaventura’s oxygen-absorbing carriers in Sirkar’s method in order to bind oxygen reversibly and that it would have been obvious to optimize the oxygen purity. Id. at 9–10. Appellant argues that Sirkar fails to teach that the starting gas includes nitrogen and oxygen when oxygen is the target gas to be collected. Appeal Br. 9. Appellant concedes that Sirkar teaches that the starting gas may be air, nitrogen, or oxygen, but asserts that Sirkar removes target volatile compounds from these starting gases, rather than oxygen. Id. at 10. Appellant contends that Sirkar discloses gas scrubbing and regeneration of Appeal 2020-006742 Application 14/870,906 11 absorbents, rather than separation of oxygen from air. Id. In addition, Appellant asserts that the Sirkar and the Bonaventura processes are essentially opposite, and contends that there is no basis for their combination absent Appellant’s disclosure. Id. at 10, 11. And Appellant argues that any combination of these references would still incorporate Bonaventura’s electrode-based oxidation/reduction. Id. at 11. Appellant’s arguments are not persuasive of reversible error. To begin, as explained above, not only does Bonaventura expressly teach that electrode-based oxidation/reduction is optional and may be omitted, but claim 1 does not exclude electrode-based oxidation/reduction steps from the method. Moreover, Appellant fails to explain in any detail how and why Sirkar’s and Bonaventura’s processes are essentially opposites. Sirkar discloses a system for transferring a solute or target from a feed gas to an absorbent liquid separated by a membrane. Sirkar 3:58–62. Although Sirkar is also concerned with removal of volatile organic compounds from the feed gas such as air or nitrogen, Sirkar discloses that the gas species to be selectively removed may be oxygen. Id. at 17:52–53. Thus, Sirkar’s process is similar to Bonaventura’s which selectively removes oxygen from a feed gas such as air by transferring oxygen from the feed gas to an absorbent liquid separated by a membrane. The fact that Sirkar’s membranes are in the form of hollow fibers whereas Bonaventura’s are shown to be flat membranes alone does not demonstrate that their respective processes are opposite, especially since both membrane forms perform the same selective separation and transfer. Further, we disagree with Appellant’s characterization of Sirkar as directed to gas scrubbing and regeneration. Sirkar merely indicates that the Appeal 2020-006742 Application 14/870,906 12 inventive absorbent scheme and operational conditions are equally applicable to gas scrubbing and regeneration. This teaching does not negate the fact that Sirkar’s process is a selective removal process using membrane separation and an absorbent liquid as recited in claim 1. Further, the teaching that the gas species to be selectively removed may be oxygen is similarly not limited to gas scrubbing and regeneration, but to both the inventive process, as well as gas scrubbing and regeneration. Therefore, a preponderance of the evidence supports the Examiner’s findings, reasoning, and conclusion that the claim 1 method would have been obvious over the combination of Sirkar and Bonaventura. Accordingly, we sustain the Examiner’s obviousness rejection of claim 1, and claims 2–6, 8–11, and 21–28. CONCLUSION Upon consideration of the record and for the reasons set forth above and in the Examiner’s Answer, the Examiner’s decision to reject claims 1–6, 8–11, and 21–28 under 35 U.S.C. § 103 is affirmed. DECISION SUMMARY In summary: Claims Rejected 35 U.S.C. § Reference(s)/Basis Affirmed Reversed 21 112 Indefiniteness 21 1–3, 20 103 Bonaventura 1–3, 20 1–6, 8–11, 21–28 103 Bonaventura, Sirkar 1–6, 8–11, 21–28 Overall Outcome 1–6, 8–11, 20–28 Appeal 2020-006742 Application 14/870,906 13 TIME PERIOD FOR RESPONSE No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § 1.136(a). See 37 C.F.R. § 1.136(a)(1)(iv). AFFIRMED Copy with citationCopy as parenthetical citation