Ex Parte Wang et alDownload PDFPatent Trial and Appeal BoardAug 31, 201714281492 (P.T.A.B. Aug. 31, 2017) Copy Citation United States Patent and Trademark Office UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O.Box 1450 Alexandria, Virginia 22313-1450 www.uspto.gov APPLICATION NO. FILING DATE FIRST NAMED INVENTOR ATTORNEY DOCKET NO. CONFIRMATION NO. 14/281,492 05/19/2014 Qunhua WANG 020647US/DIS PLAY/AKT/ES ON 4813 44257 7590 09/05/2017 PATTERSON & SHERIDAN, LLP - - Applied Materials 24 Greenway Plaza, Suite 1600 HOUSTON, TX 77046 EXAMINER BOOTH, RICHARD A ART UNIT PAPER NUMBER 2812 NOTIFICATION DATE DELIVERY MODE 09/05/2017 ELECTRONIC Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. Notice of the Office communication was sent electronically on above-indicated "Notification Date" to the following e-mail address(es): Pair_Eofficeaction@pattersonsheridan.com psdocketing@pattersonsheridan.com PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE BEFORE THE PATENT TRIAL AND APPEAL BOARD Ex parte QUNHUA WANG, LAI ZHAO, and SOO YOUNG1 Appeal 2016-005483 Application 14/281,492 Technology Center 2800 Before JEFFREY T. SMITH, MICHAEL P. COLAIANNI, and WESLEY B. DERRICK, Administrative Patent Judges. COLAIANNI, Administrative Patent Judge. DECISION ON APPEAL Appellants appeal under 35 U.S.C. § 134 the Final Rejection of claims 1—8, 10-18, and 20. We have jurisdiction over the appeal pursuant to 35 U.S.C. § 6(b). We REVERSE. Appellants’ invention is directed to methods for forming a silicon- containing layer that may be used in thin film transistor (TFT) devices (Spec. 12). 1 The Appeal Brief identifies Applied Materials, Incorporated is the real party in interest. See App. Br. 2. Appeal 2016-005483 Application 14/281,492 Claim 1 is illustrative: 1. A method comprising: positioning a substrate in a processing region of a process chamber, the substrate having a surface with at least one buffer layer formed thereon; delivering a silicon-containing precursor and an activation gas to the processing region, the activation gas comprising an inert gas and a hydrogen-based gas, wherein the activation gas is no more than 20 atomic % hydrogen, and wherein the ratio of the activation gas to the silicon-containing precursor is greater than about 1:20; igniting the precursor and activation gas into a plasma; depositing an amorphous silicon layer on the substrate; dehydrogenating the amorphous silicon layer; and annealing the dehydrogenated amorphous silicon layer to form a polycrystalline silicon layer. Appellants appeal the following rejections: 1. Claims 1—8 are rejected under 35 U.S.C. § 103(a) as unpatentable over Oka (US 6,235,563 Bl; iss. May 22, 2001) in view of Park (US 2008/0135893 Al; publ. June 12, 2008). 2. Claims 10-18 and 20 are rejected under 35 U.S.C. § 103(a) as unpatentable over Oka in view of Park and Kasahara (US 6,656,779 Bl; iss. Dec. 2, 2003). FINDINGS OF FACT & ANALYSIS The Examiner finds that Oka teaches the subject matter of claim 1, except for the activation gas comprising both an inert gas and a hydrogen- based gas (Final Act. 3). The Examiner finds that Park teaches forming a semiconductor layer in both an inert and hydrogen based gas. Id. The Examiner concludes that it would have been obvious to use an inert gas and a hydrogen based gas to form a thin film transistor (TFT) layer as taught by 2 Appeal 2016-005483 Application 14/281,492 Park to form a thin film transistor layer in Oka. Id. With regard to the limitation that the activation gas is no more than 20 atomic % hydrogen, and wherein the ratio of the activation gas to the silicon-containing precursor is greater than about 1:20, the Examiner finds that that amount of hydrogen gas is a result-effective variable such that it would have been obvious to determine through routine experimentation the optimum concentration based upon a variety of factors including the desired thermal budget (Final Act. 4). Appellants argue that neither Oka nor Park teaches or suggests use of silicon-containing gas and an activation gas that comprises a hydrogen containing gas and an inert gas wherein the activation gas is no more than 20 atomic % hydrogen (App. Br. 8). Appellants contend that the Examiner has not shown that the hydrogen content of the activation gas is recognized as a result effective variable that achieves a recognized result (App. Br. 9). Appellants contend that Oka provides no indication of any ranges for concentrations of the diluent gases described in Oka, especially for hydrogen. Id. The preponderance of the evidence favors Appellants’ argument of non-obviousness. Although the Examiner finds that Oka’s disclosure of hydrogen as a diluent or carrier gas in the abstract shows that the presence of hydrogen is a result-effective variable, the Examiner has not shown the concentration of hydrogen gas is a result effective variable. The Examiner has not directed us to where Oka discloses that the concentration of the hydrogen diluent gas affects Oka’s process in any particular manner. Oka’s only disclosure regarding the concentration of hydrogen states that the concentration of hydrogen in the amorphous silicon film contains about 10 atomic % hydrogen in the form of Si-H, H-Si-H and the like bonds (Oka col. 3 Appeal 2016-005483 Application 14/281,492 8,11. 36—38). However, the Examiner makes no findings regarding how the concentration of hydrogen in the amorphous silicon film relates to the concentration of hydrogen in the activation gas used to form the amorphous film. The Examiner further determines that it would have been obvious to minimize the amount of hydrogen in Oka’s activation gas because Oka teaches to remove the hydrogen in a later step (Ans. 6). The Examiner has not directed us to any guidance provided by Oka or Park regarding the concentration of hydrogen in the activation gas. In other words, minimizing the amount of hydrogen in Oka’s activation gas may still exceed the 20 atomic % required by claim 1. We are left to speculate as to suitable concentrations of hydrogen in Oka’s activation gas; obviousness cannot be based on what is unknown. In re Spormann, 363 F.2d 444, 448 (CCPA 1966). On this record, the Examiner has not established a prima facie case of obviousness. We are constrained to reverse the Examiner’s § 103(a) rejections. DECISION The Examiner’s decision is reversed REVERSED 4 Copy with citationCopy as parenthetical citation