Ex Parte Rediger et alDownload PDFPatent Trial and Appeal BoardMay 26, 201611747343 (P.T.A.B. May. 26, 2016) Copy Citation UNITED STATES PATENT AND TRADEMARK OFFICE UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www.uspto.gov APPLICATION NO. FILING DATE FIRST NAMED INVENTOR ATTORNEY DOCKET NO. CONFIRMATION NO. 11/747,343 05/11/2007 Richard Rediger 20215-USA 4333 48255 7590 05/27/2016 GEORGIA-PACIFIC LLC 133 PEACHTREE STREET, NE GA30-39 ATLANTA, GA 30303 EXAMINER KRYLOVA, IRINA ART UNIT PAPER NUMBER 1764 MAIL DATE DELIVERY MODE 05/27/2016 PAPER Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE ________________ BEFORE THE PATENT TRIAL AND APPEAL BOARD ________________ Ex parte RICHARD REDIGER and EDWARD LUCAS ________________ Appeal 2014-003857 Application 11/747,343 Technology Center 1700 ________________ Before TERRY J. OWENS, PETER F. KRATZ, and N. WHITNEY WILSON, Administrative Patent Judges. OWENS, Administrative Patent Judge. DECISION ON APPEAL STATEMENT OF THE CASE The Appellants appeal under 35 U.S.C. § 134(a) from the Examiner’s rejection of claims 1–4, 7, 21–25, and 27–33. We have jurisdiction under 35 U.S.C. § 6(b). The Invention The Appellants claim a solid phenol-formaldehyde novolac resin composition. Claim 1 is illustrative: 1. A solid phenol-formaldehyde novolac resin composition in flake form, comprising: less than 1.5 wt% free phenol; and Appeal 2014-003857 Application 11/747,343 2 a non-phenolic solvent in an amount sufficient to provide a solid phenol-formaldehyde novolac resin having a melt viscosity at 150°C of less than 5,000 cps, wherein the non-phenolic solvent is a dibasic ester selected from the group consisting of dimethyl adipate, dimethyl gluterate, dimethyl succinate, and mixtures thereof, wherein the solid phenol-formaldehyde novolac resin has a melting point of from 77°C to 93°C, and wherein the solid phenol-formaldehyde novolac resin contains no other non-phenolic solvent. The References Vargiu US 3,878,159 Apr. 15, 1975 Funabiki US 4,252,700 Feb. 24, 1981 Chandramouli (Chandramouli ‘170) US 4,897,170 Jan. 30, 1990 Chandramouli (Chandramouli ‘412) US 5,043,412 Aug. 27, 1991 Hesse US 5,652,047 July 29, 1997 Keil US 5,658,360 Aug. 19, 1997 Invista, Technical Information: Dibasic Esters (DBE) 1–2 (2004) (hereinafter DBE Flyer). The Rejections The claims stand rejected under 35 U.S.C. § 103 as follows: claims 1– 4, 7, 21, 22, 24, 27–29, and 31–33 over Chandramouli ‘412 in view of Funabiki and Chandramouli ‘170, claims 23 and 30 over Chandramouli ‘412 in view of Funabiki, Chandramouli ‘170 and DBE Flyer, claims 1–4, 7, 21, 22, 24, 27–29, and 31–33 over Chandramouli ‘412 in view of Funabiki, Chandramouli ‘170, Keil and Hesse, claims 23 and 30–33 over Chandramouli ‘412 in view of Funabiki, Chandramouli ‘170, Keil, Hesse Appeal 2014-003857 Application 11/747,343 3 and DBE Flyer, and claim 25 over Chandramouli ‘412 in view of Funabiki, Chandramouli ‘170, Keil, Hesse and Vargiu.1 OPINION We reverse the rejections. We need address only the independent claims, i.e., claims 1, 7, 21 and 27.2 Those claims require a novolac resin which comprises less than 1.5 wt% free phenol, comprises a non-phenolic solvent selected from the group consisting of dimethyl adipate, dimethyl gluterate, dimethyl succinate and mixtures thereof, and has a melt viscosity at 150 ºC of less than 5,000 cps (claim 1), less than 4000 cps (claims 7 and 27), or “not greater than 10% higher than the melt viscosity at 150oC of the phenol-formaldehyde novolac resin before both the non-phenolic solvent was added and the level of free phenol was reduced” (claim 21). Rejection over Chandramouli ‘412 in view of Funabiki and Chandramouli ‘170 Setting forth a prima facie case of obviousness requires establishing that the applied prior art would have provided one of ordinary skill in the art with an apparent reason to modify the prior art to arrive at the claimed invention. See KSR Int’l Co. v. Teleflex Inc., 550 U.S. 398, 418 (2007). Chandramouli ‘412 discloses a composition for making a free-flowing binder-aggregate mixture for forming a foundry mold, foundry core or furnace lining refractory brick, comprising a mixture of an aggregate material, a phenol formaldehyde novolac resin, a phenol formaldehyde 1 A rejection of claims 1–4, 7, 21–25, and 27–33 under 35 U.S.C. § 112(a) is withdrawn in the Examiner’s Answer (Ans. 16). 2 The Examiner does not rely upon DBE Flyer or Vargiu for any disclosure that remedies the deficiency in the references applied to the independent claims (Ans. 9–10, 13–16). Appeal 2014-003857 Application 11/747,343 4 resole resin and an ester functional curing agent (which can be dimethyl gluterate or dimethyl adipate), wherein the novolac resin component can be in flake form (Abstract; col. 3, ll. 4–7, 50–51; col. 5, ll. 50–65; col. 7, ll. 37– 38). Chandramouli ‘412 is silent as to the novolac resin’s melt viscosity and amount of free phenol. Chandramouli ‘170 discloses a Soderberg electrode3 paste composition comprising carbonaceous aggregate, novolac resin binder and plasticizer (Abstract). The binder’s novolac resin can be in flake form and, to substantially reduce noxious fume evolution, has a free phenol content of less than 4 wt%, preferably less than 2 wt%, based on resin solids (col. 5, ll. 22–27; col. 7, ll. 18, 42–48, 63). The novolac resin can be used with a high boiling plasticizer, which can be a dibasic ester, to “help maintain plasticity and fluidity of the paste mix through the various temperature zones of the Soderberg anode feed system” (col. 5, ll. 28–40). Chandramouli ‘170 is silent as to the novolac resin’s melt viscosity.4 Funabiki discloses “a solid phenolic resin composition useful as a binder in the preparation of foundry sand cores and molds which comprises a solid novolac resin and a lubricant-containing solid resole resin wherein the lubricant is incorporated into the resole during the preparation of the 3 “Soderberg electrodes are used principally in aluminum reduction, calcium carbide production, the production of electric pig iron, processing copper matte, and other kinds of ferro alloy and smelting operations. They are also used in the manufacture of phosphorus” (col. 2, ll. 52–56). 4 Chandramouli ‘170’s viscosity relied upon by the Examiner (Ans. 2–3) is the viscosity of the resin binder composition (exemplified as including a potassium hydroxide solution, water and a phenol formaldehyde resole resin) not the novolac resin’s melt viscosity (col. 6, ll. 38–48; Examples 1– 8). Appeal 2014-003857 Application 11/747,343 5 solid resole” (Abstract). The novolac resin has a melting point of 70 to 100 ºC (col. 4, ll. 49–51). The Examiner asserts that “Chandramouli’170 teaches that plasticizers help maintain plasticity and fluidity through the various temperature zones (col. 5, lines 37-40)” (Ans. 5). The Examiner does not mention that the temperature zones are those of a Soderberg anode feed system (col. 5, ll. 38–40). The Examiner has not established that Chandramouli ‘170’s disclosure that plasticizers help maintain plasticity and fluidity of a paste mix through the various temperature zones of a Soderberg anode feed system (col. 5, ll. 37–40) would have provided one of ordinary skill in the art with an apparent reason to include a plasticizer in Chandramouli ‘412’s composition for making a foundry mold, foundry core or furnace lining refractory brick (col. 3, ll. 4– 7). The Examiner argues that in view of Chandramouli ‘170’s disclosure that plasticizers help maintain plasticity and fluidity of a paste mix through the various temperature zones of a Soderberg anode feed system (col. 5, ll. 37–40), one of ordinary skill in the art would have arrived at the Appellants’ recited melt viscosity through routine optimization depending upon the novolac resin’s initial melt viscosity and desired fluidity (Ans. 5). The Appellants’ novolac resin, like Chandramouli ‘412’s novolac resin, is useful for making foundry molds and cores (Appellants’ Spec. ¶ 4; Chandramouli ‘412, col. 3, ll. 4–7). The Examiner has not established that optimizing the melt viscosity of a novolac resin used in a Soderberg electrode paste would lead to a melt viscosity which would be optimum, or Appeal 2014-003857 Application 11/747,343 6 even suitable, for a novolac resin which is useful for making foundry molds and cores. Rejection over Chandramouli ‘412 in view of Funabiki, Chandramouli ‘170, Keil and Hesse Keil discloses an uncured molded abrasive article (such as an uncured grinding wheel) comprising granular abrasive materials coated with a novolac resin which is solid at room temperature, preferably contains less than 0.5 wt% free phenol and has a melt viscosity which, due to being relatively low (preferably about 400 cp to about 800 cp which corresponds to a temperature of about 125 ºC to about 115 ºC), makes the novolac resin easy to handle and blend with other components (col. 1, l. 10; col. 3, ll. 10– 20; col. 4, ll. 55–65; col. 5, ll. 11–13). Hesse discloses novolac resins which are useful as binders for fiber composites, are in powder form, contain particularly preferably less than 0.05 wt% free phenol, and have a melting point range from 35 to 120 ºC (col. 2, ll. 51–58, 63–66; col. 3, ll. 10–15, 37–51; col. 4, ll. 34–50). The Examiner argues that in view of Chandramouli ‘170’s (col. 5, ll. 22–27), Keil’s (col. 3, ll. 16–17) and Hesse’s (col. 2, ll. 63–66) use of a reduced-phenol-content novolac resin to reduce noxious fumes, one of ordinary skill in the art would have reduced Chandramouli ‘412’s novolac resin’s phenol content to achieve that benefit (Ans. 8, 12–13). The Appellants’ claims require not only a low free phenol content but also a non-phenolic dibasic ester solvent and a low melt viscosity (which the Appellants achieve by replacing removed phenol with a non-phenolic dibasic ester solvent (Spec. ¶ 19)). The Examiner has not established that Chandramouli ‘412, Chandramouli ‘170, Funabiki, Keil and Hesse would Appeal 2014-003857 Application 11/747,343 7 have led one of ordinary skill in the art to use in Chandramouli ‘412’s composition a novolac resin having the Appellants novolac resin’s required combination of low free phenol content, non-phenolic dibasic ester solvent and low melt viscosity. Thus, the Examiner has not established a prima facie case of obviousness of the Appellants’ claimed novolac resin composition. DECISION/ORDER The rejections under 35 U.S.C. § 103 of claims 1–4, 7, 21, 22, 24, 27– 29, and 31–33 over Chandramouli ‘412 in view of Funabiki and Chandramouli ‘170, claims 23 and 30 over Chandramouli ‘412 in view of Funabiki, Chandramouli ‘170 and DBE Flyer, claims 1–4, 7, 21, 22, 24, 27– 29, and 31–33 over Chandramouli ‘412 in view of Funabiki, Chandramouli ‘170, Keil and Hesse, claims 23 and 30–33 over Chandramouli ‘412 in view of Funabiki, Chandramouli ‘170, Keil, Hesse and DBE Flyer, and claim 25 over Chandramouli ‘412 in view of Funabiki, Chandramouli ‘170, Keil, Hesse and Vargiu are reversed. It is ordered that the Examiner’s decision is reversed. REVERSED Copy with citationCopy as parenthetical citation