Ex Parte PriceDownload PDFPatent Trial and Appeal BoardMar 28, 201812799061 (P.T.A.B. Mar. 28, 2018) Copy Citation UNITED STA TES p A TENT AND TRADEMARK OFFICE APPLICATION NO. FILING DATE 121799,061 04/16/2010 23589 7590 03/30/2018 Hovey Williams LLP 10801 Mastin Blvd., Suite 1000 Overland Park, KS 66210 FIRST NAMED INVENTOR Brian C. Price UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www .uspto.gov ATTORNEY DOCKET NO. CONFIRMATION NO. 43886 3059 EXAMINER RAYMOND, KEITH MICHAEL ART UNIT PAPER NUMBER 3744 NOTIFICATION DATE DELIVERY MODE 03/30/2018 ELECTRONIC Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. Notice of the Office communication was sent electronically on above-indicated "Notification Date" to the following e-mail address( es): amalik@hoveywilliams.com uspatents@hoveywilliams.com PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE BEFORE THE PATENT TRIAL AND APPEAL BOARD Ex parte BRIAN C. PRICE Appeal2016-006864 Application 12/799,061 Technology Center 3700 Before JENNIFER D. BAHR, MICHAEL L. WOODS, and FREDERICK C. LANEY, Administrative Patent Judges. LANEY, Administrative Patent Judge. DECISION ON APPEAL STATEMENT OF THE CASE Brian C. Price (Appellant) 1 appeals under 35 U.S.C. § 134(a) from the Examiner's decision (mailed June 16, 2015, hereinafter "Final Act.") rejecting claims 1--4 and 12-15 under 35 U.S.C. § 103(a) as unpatentable over Phade (US 4,878,932, iss. Nov. 7, 1989), Swenson (US 4,033,735, iss. July 5, 1977), and Hahn (US 7 ,234,322 B2, iss. June 26, 2007). 2 We have jurisdiction over this appeal under 35 U.S.C. § 6(b). 1 Black & Veatch Holding Company is identified as the real parties in interest in Appellant's Appeal Brief (filed Dec. 16, 2015, hereinafter "Appeal Br."), at page 4. 2 Claims 5-11 have been canceled. Amendment 3 (filed June 12, 2014). Appeal 2016-006864 Application 12/799,061 We REVERSE. INVENTION Appellant's invention relates to "a mixed single refrigerant process for separating a nitrogen gas stream from a natural gas stream containing nitrogen to produce a nitrogen gas stream and a liquefied natural gas stream." Spec. i-f 1. There are two independent claims, 1 and 13, pending in this appeal. Claim 1, reproduced below, is illustrative of the invention the Specification discloses. 1. A process for producing liquefied natural gas from a nitrogen-containing natural gas stream, the process comprising: a) cooling a stream of mixed refrigerant in a first heat exchanger of a single closed-loop mixed refrigerant system to provide a cooled mixed refrigerant stream; b) expanding at least a portion of the cooled mixed refrigerant stream to produce an expanded mixed refrigerant stream; c) cooling and at least partially condensing the natural gas stream in a first heat exchange passageway via indirect heat exchange with the expanded mixed refrigerant stream in the first heat exchanger to produce a cooled natural gas stream; d) dividing the cooled natural gas stream withdrawn from the first heat exchange passageway into a first portion and a second portion; e) introducing the first portion into a lower inlet of a first vapor-liquid separator; f) subsequent to said dividing, subcooling the second portion in the first heat exchanger to provide a subcooled liquid portion, wherein said subcooling is carried out in a second heat exchange passageway via indirect heat exchange with said expanded mixed refrigerant; g) subsequent to said subcooling, introducing the subcooled liquid portion into an upper inlet of the first vapor- liquid separator, wherein the upper inlet of the first vapor-liquid 2 Appeal 2016-006864 Application 12/799,061 separator is located at a higher vertical elevation than the lower inlet; h) withdrawing a methane rich liquid bottoms stream and a first nitrogen rich vapor overhead stream from the first vapor- liquid separator; i) further cooling the methane rich liquid bottoms stream in the first heat exchanger in a third heat exchange passageway to provide a first liquid natural gas stream; j) introducing at least a portion of the first liquid natural gas stream into an inlet of a nitrogen stripping column; k) introducing at least a portion of the first nitrogen rich vapor overhead stream into another inlet of the nitrogen stripping column; 1) withdrawing a stream of nitrogen-depleted liquefied natural gas (LNG) from a lower portion of the nitrogen stripping column, wherein the LNG comprises less than 3 volume percent nitrogen; m) recovering an overhead nitrogen rich vapor stream from a location near the top of the nitrogen stripping column, wherein the overhead nitrogen rich vapor stream comprises less than 3 volume percent methane; n) introducing the overhead nitrogen rich vapor stream into the first heat exchanger; and o) using at least a portion of the overhead nitrogen rich vapor stream as a refrigerant in the first heat exchanger to carry out at least a portion of the cooling of step (a) and/or at least a portion of the cooling of step ( c ), wherein the single closed-loop mixed refrigerant system is the only closed-loop refrigeration system used to cool the natural gas stream. Appeal Br. 28-29 (Claims App.). 3 Appeal 2016-006864 Application 12/799,061 ANALYSIS The Examiner determines independent claim 1 would have been obvious in view of Phade, Swenson, and Hahn. Final Act. 2-6. The Examiner finds Phade discloses process steps c) and h }-o) of the claimed process, but not "wherein the single closed-loop mixed refrigerant system is the only closed-loop refrigeration system used to cool the natural gas stream." Id. at 2--4. Swenson, the Examiner finds, discloses process steps a), b ), and "wherein the single closed-loop mixed refrigerant system is the only closed-loop refrigeration system used to cool the natural gas stream." Id. at 4. According to the Examiner, a skilled artisan would have known to modify Phade with the process steps Swenson discloses to give "greater control to the cooling of the feed stream as well as to assist in the cooling of the feed stream." Id. This modification, the Examiner finds, further benefits the system of Phade because it will be capable of maintaining its liquid natural gas product (128) in transportable (by ship) liquid phase since the closed loop refrigeration system ... can be adjusted as required such that the cooling duty of the liquid natural gas product (128) of Phade is no longer needed to cool the natural gas feed stream (111 ). Id. at 5. A skilled artisan would have modified Phade to include the closed loop refrigeration system in Swenson, the Examiner determines, to provide cooling with a greater degree of control, "since it is old and well known that compressors and expansion valves may be adjusted to control efficiency and capacity of a cooling system." Id. For the claimed process steps d}-g), the Examiner relies on Hahn. Id. at 5---6. The Examiner concludes further modifying Phade with these steps of Hahn would have been obvious to a skilled artisan because it would "provid[ e] a greater degree of control of reflux to the first vapor-liquid 4 Appeal 2016-006864 Application 12/799,061 separator ... , as well as to enhance separation by providing countercurrent- mass exchange of the feed stream to itself within the first vapor-liquid separator." Id. at 6. Moreover, the Examiner finds this modification would result in sub-cooling the second portion via indirect heat exchange with the expanded mixed refrigerant. Id. Appellant does not dispute Swenson and Hahn disclose the claimed process steps missing from Phade, but argue "the proposed combination of Phade and Swenson cannot be used to support a proper primafacie case of obviousness with respect to independent claim 1." Appeal Br. 26; see id. at 21-26. This is so, according to Appellant, because the "addition of 'compressors and expansion valves' as asserted by the Examiner would not enhance the efficiency or control of the system of Phade." Id. at 22. Appellant asserts that Phade teaches balancing internal refrigeration capacity with refrigeration demand without the use of an external refrigerant "is a major factor in the 'improved efficiency' of the system of Phade," which undermines the Examiner's position that there would have been a need for additional refrigeration. Id. at 23. In addition, Appellant contends the Examiner erroneously suggests simply including an additional refrigerant to the process of Phade (i.e., so as to not vaporize the stream of liquid methane) would enable the process to maintain the stream of liquid methane withdrawn from column 104 via line 128 in a transportable (by ship) liquid phase. Id. According to Appellant, "simply electing not to vaporize the stream of liquid methane withdrawn from column 104 via line 128 would not convert the system of Phade to an LNG facility capable of forming a 'liquid natural gas product' that is 'transportable."' Id. 5 Appeal 2016-006864 Application 12/799,061 We are persuaded the Examiner's reason for combining Phade and Swenson in the claimed manner lacks a rational underpinning because deficiencies exist with the evidence and technical reasoning given for why a skilled artisan would have been led to the claimed combination. Phade and Swenson disclose two different processes; Phade discloses a cryogenic rectification process for separating nitrogen and methane, and Swenson discloses a single mixed refrigerant, closed loop process for liquefj;ing natural gas. Compare Phade Title, Figs. 1, 2 (and associated text), with Swenson Title, Figs. la, lb (and associated text). The Examiner's analysis fails to account for these process differences sufficiently. Nor does the Examiner explain why the similarities between the Phade and Swenson processes make Swenson's teachings regarding its refrigeration system equally applicable to the process of Phade. The Examiner simply finds Swenson teaches a closed loop vapor compression refrigeration system that provides greater control to the cooling of the feed stream and concludes a skilled artisan would have wanted to provide cooling to the process of Phade with a greater degree of control. Final Act. 4--5; Ans. 9. This rationale presumes inadequacies were known to exist with the ability of the Phade process to control the cooling of the feed stream. The Examiner, however, offers no evidence or technical reasoning to support this presumption. The Examiner does not make any finding of a known shortcoming with the feed stream control in the Phade process or provide a technical reason explaining why a skilled artisan would have perceived a shortcoming with its control. For example, although the Examiner correctly notes Swenson teaches a refrigeration system that enables its process to "bring the 6 Appeal 2016-006864 Application 12/799,061 combined cooling curve of the hot refrigerant and feed gas into relatively close matching relationship to the heating curve of the cold refrigerant stream" (Ans. 9 (quoting Swenson col. 2, 11. 16-50)), the Examiner does not cite any evidence or explain why a similar need exists in the Phade process. See id. And even presuming such a need exists, the Examiner still has not shown the Phade process had known deficiencies creating such a relationship that the refrigeration system in Swenson was known to address. Similarly, the Examiner offers no evidence to support the finding that adding Swenson's refrigeration system to Phade's process would maintain the liquid natural gas product in a transportable liquid phase. Nor does the Examiner explain how the combination would work to accomplish this result. Contrary to the Examiner's contention, we note the refrigeration system in Swenson is only one of several differences that exist between the Phade process for separating nitrogen and methane and the Swenson process for liquefying natural gas. Compare Phade Title, Figs. 1, 2 (and associated text), with Swenson Title, Figs. la, lb (and associated text). This fact more persuasively supports Appellant's assertion that the Phade process does not become a process for creating transferable liquefied natural gas by simply adding the Swenson refrigeration system, even if liquefied natural gas occurs at various points within the Phade process. Appeal Br. 23-24. With respect to core factual findings in a determination of patentability, an examiner cannot establish a prima facie case based on conclusions simply deemed to be basic knowledge or common sense. In re Zurko, 258 F.3d 1379, 1385-86 (Fed. Cir. 2001). Rather, the examiner "must point to some concrete evidence in the record in support of these findings." Id.; see also Perfect Web Tech., Inc. v. InfoUSA, Inc., 587 F.3d 7 Appeal 2016-006864 Application 12/799,061 1324, 1328 (Fed. Cir. 2009) (emphasizing same). It is incumbent upon the examiner to establish a factual basis to support the legal conclusion of obviousness. See In re Fine, 837 F.2d 1071, 1073 (Fed. Cir. 1988). In this case, the Examiner's determination that it would have been obvious to combine Phade with Swenson in the manner claimed is predicated on findings not supported by a preponderance of the evidence. Thus, the Examiner does not establish a sustainable case of obviousness of the subject matter of independent claim 1, or its dependent claims 2--4, and 12. Rejecting claims 13-15, the Examiner states, "Figure 2 of Phade, as modified by Swenson and Hahn, and discussed above in claims 1--4 and 12, necessarily teach all the structure required to meet all of the limitations of claims 13-15." Final Act. 7. As a result, the Examiner's obviousness determination of independent claim 13 incorporates the same errors discussed above in the context of claim 1. Therefore, for the same reasons, we do not sustain the Examiner's rejection of claim 13, as well as claims 14 and 15 depending therefrom. DECISION The Examiner's rejection of claims 1--4 and 12-15 is reversed. REVERSED 8 Copy with citationCopy as parenthetical citation