Ex Parte POBER et alDownload PDFPatent Trials and Appeals BoardMar 29, 201914902665 - (D) (P.T.A.B. Mar. 29, 2019) Copy Citation UNITED STA TES p A TENT AND TRADEMARK OFFICE APPLICATION NO. FILING DATE 14/902,665 01/04/2016 27683 7590 04/02/2019 HA YNES AND BOONE, LLP IP Section 2323 Victory A venue Suite 700 Dallas, TX 75219 FIRST NAMED INVENTOR Kenneth W. POBER UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www .uspto.gov ATTORNEY DOCKET NO. CONFIRMATION NO. 7523.1382US01_08217 8935 EXAMINER HEINCER, LIAM J ART UNIT PAPER NUMBER 1767 NOTIFICATION DATE DELIVERY MODE 04/02/2019 ELECTRONIC Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. Notice of the Office communication was sent electronically on above-indicated "Notification Date" to the following e-mail address(es): ipdocketing@haynesboone.com PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE BEFORE THE PATENT TRIAL AND APPEAL BOARD Ex parte KENNETH W. POBER and CATO R. MCDANIEL Appeal2018-004956 Application 14/902,665 Technology Center 1700 Before MICHAEL P. COLAIANNI, BRIAN R. RANGE, and MICHAEL G. McMANUS, Administrative Patent Judges. McMANUS, Administrative Patent Judge. DECISION ON APPEAL The Examiner finally rejected claims 1, 9, 10, 13, 16, 18, 19, 21, 23, 31, 32, 36, 39, 46, 47, 50, 51, and 55 of Application 14/902,665 under 35 U.S.C. § 103 and/or for obviousness-type double patenting. Final Act. (Jul. 18, 2017) 2-10. Appellant1 seeks reversal of these rejections pursuant to 35 U.S.C. § 134(a). We have jurisdiction under 35 U.S.C. § 6(b ). For the reasons set forth below, we AFFIRM-IN-PART. 1 The Appellant is the Applicant, Halliburton Energy Services, Inc., which is also identified as the real party in interest. Appeal Br. 2. Appeal2018-004956 Application 14/902,665 BACKGROUND Humus is a brown or black material derived from decomposition of plant and/or animal substances. Humus may generally be described as "the organic portion of soil that will not undergo any further decomposition or degradation, and which comprises complex molecules resembling or incorporating at least a portion of a humic acid-like structure." Spec. ,r 9. Humus my comprise brown coal, lignite, subbituminous coal, leonardite, humic acid, fulvic acid, humin, peat, lignin, and the like, or combinations thereof. Id. ,r 10. The Specification concerns a method of alkoxylating a humus material that includes heating a mixture comprising a humus material, a C3+ cyclic ether, a catalyst and an inert reaction solvent, and recovering a C3+ alkoxylated humus material from the reaction mixture. Id. ,r 3. Claims 1 and 55 are illustrative of the subject matter on appeal and are reproduced below: 1. A method of alkoxylating a humus material comprising: heating a reaction mixture comprising a dehydrated humus material, a C3+ cyclic ether, a catalyst and an inert reaction solvent; and recovering a C3+ alkoxylated humus material from the reaction mixture; wherein the dehydrated humus material comprises brown coal, subbituminous coal, humic acid, a compound characterized by Structure I, fulvic acid, humin, peat, or combinations thereof 2 Appeal2018-004956 Application 14/902,665 Appeal Br. 18 (Claims App.) (reformatted for clarity). 55. A C3+ alkoxylated humus material, wherein the C3+ alkoxylated humus material is a product of a reaction between a humus material and a C3+ cyclic ether characterized by: (a) Structure VII: Structure VII wherein HM represents the humus material; n is in the range of from about O to about 3; m is in the range of from about 1 to about 30; xis in the range of from about Oto about 300, per 100 g of humus material; p is in the range of from about 1 to about 30; y is in the range of from about Oto about 200, per 100 g of humus material; q is in the range of from about 1 to about 30; z is in the range of from about O to about 300, per 100 g of humus material; and x and z cannot both be O at the same time; or (b) Structure VIII: 3 Appeal2018-004956 Application 14/902,665 Structure VIII wherein HM represents the humus material; n is in the range of from about O to about 3; m 1 is in the range of from about 1 to about 30; xl is in the range of from about Oto about 300, per 100 g of humus material; p is in the range of from about 1 to about 30; y is in the range of from about Oto about 200, per 100 g of humus material; q is in the range of from about 1 to about 30; z is in the range of from about O to about 300, per 100 g of humus material; and x 1 and z cannot both be O at the same time. Id. at 31 (Claims App.). REJECTIONS The Examiner maintains the following rejections: 1. Claims 1, 9, 10, 13, 16, 18, 19, 21, 23, 31, 32, 47, 50, 51, and 55 are rejected under 35 U.S.C. § 103 as obvious over Pober2 in view of Baer et al. 3 Final Act. 2--4. 2. Claims 47, 50, 51, and 55 are rejected under 35 U.S.C. § 103 as obvious over Christian et al. Id. at 5. 3. Claims 1, 9, 10, 21, and 23 are provisionally rejected on the basis of nonstatutory double patenting over claims 9-11, 15, and 16 of Application No. 14/893,264. Id. at 6. 2 US 4,578,456, published Mar. 25, 1986 ("Pober"). 3 Holger Baer et al., PROPYLENE OXIDE, Ullmann 's Encyclopedia of Industrial Chemistry I-29 (2012) ("Baer"). 4 Appeal2018-004956 Application 14/902,665 4. Claim 13 is provisionally rejected on the basis of nonstatutory double patenting over claims 9-11, 15, and 16 of Application No. 14/893,264 and further in view of Gagnon. 4 Id. at 6-7. 5. Claim 16 is provisionally rejected on the basis of nonstatutory double patenting over claims 9-11, 15, and 16 of Application No. 14/893,264 and further in view ofYang. 5 Id. at 7. 6. Claims 18 and 19 are provisionally rejected on the basis of nonstatutory double patenting over claims 9-11, 15, and 16 of Application No. 14/893,264 and further in view of Pober. Id. at 7- 8. 7. Claims 31, 32, 36, 39, 46, 47, 51, and 55 are provisionally rejected on the basis of nonstatutory double patenting over claims 9-11, 15, and 16 of Application No. 14/893,264. Id. at 8. 8. Claims 1, 9, 10, 18, 19, 21, and 27 are rejected on the basis of nonstatutory double patenting over claims 1 and 10 of US Pat. No. 4,578,456 in view of Baer. Id. at 8-9. 9. Claim 31 is rejected on the basis of nonstatutory double patenting over claim 12 of US Pat. No. 4,578,456 in view of Baer. Id. at 9- 10. DISCUSSION Rejection 1. The Examiner rejected claims 1, 9, 10, 13, 16, 18, 19, 21, 23, 31, 32, 47, 50, 51, and 55 as obvious over Pober in view of Baer. 4 Steven D. Gagnon, PROPYLENE OXIDE AND HIGHER 1, 2-EPOXIDE POLYMERS, Encyclopedia of Polymer Science and Technology 1-38 (2008) ("Gagnon"). 5 US 4,456,697, issued June 26, 1984 ("Yang"). 5 Appeal2018-004956 Application 14/902,665 Final Act. 2--4. In support of the rejection, the Examiner determined that Pober teaches most limitations of the claims at issue. The Examiner found that Pober teaches a method of alkoxylating lignite (a humus material) by heating a mixture of lignite, cyclic ether, catalyst, and inert solvent. Id. at 2. The Examiner determined that the cyclic ether disclosed by Pober does not teach the "C3+ cyclic ether" limitation of claim 1 because it has only two carbon atoms. Id. The Examiner further determined, however, that Baer teaches using a mixture of ethylene oxide and propylene oxide (a C3+ cyclic ether) to form surface active agents and it would have been obvious to one of skill in the art to have added propylene oxide to the mixture of Pober "to balance the water/ oil solubility by increasing the hydrophobicity of the emulsion breaker of Pober." Id. at 2-3. Appellant seeks reversal on several bases. First, Appellant argues that the rejection of claim 1 and the claims depending therefrom (claims 9, 10, 13, 16, 18, 19, 21, and 23) is in error because the Examiner has not articulated an adequate reason why a person of ordinary skill in the art would have combined the teachings of the references as proposed by the Examiner. Appeal Br. 7-8. Appellant argues that Baer teaches the use of polyethers (including those derived from propylene oxide) for surface-active agents ("surfactants") in various contexts but not "for use in chemically modifying humus materials or the substitution of ethylene oxide with propylene oxide generally." Id. at 8. Accordingly, Appellant argues, one of skill in the art would not look to combine the teachings of Pober and Baer "because of the divergent art areas encompassed by these references." Id. This is not persuasive. Pointing out that Baer does not specifically teach to use surfactants in modifying humus materials does not rebut the 6 Appeal2018-004956 Application 14/902,665 Examiner's determination that an emulsion breaker is a type of surface active agent and that Baer teaches that the propylene oxide/ethylene oxide ratio causes a surfactant to become more hydrophobic. Answer 11. Appellant further argues that the Examiner does not cite to any portion of Pober that indicates a need to balance water/oil solubility nor to "any portion of either Baer or Pober '456 that relates any of the components of the reaction mixture of Pober '456 to either an emulsion breaker or a surface active agent." App. Br. 8. This argument lacks merit. Pober teaches that its reaction product may be used as an emulsion breaker. The Examiner has found that alkoxylation of the lignite of Pober with polypropylene would increase the hydrophobicity of the emulsion breaker of Pober. Final Act. 3. In the Answer, the Examiner found that an emulsion breaker is a type of surface- active agent. Answer 11. The Examiner further found that "[t]he desirable balance of hydrophobic and hydrophilic properties is dependent on the nature of the emulsion and its components." Id. The Examiner then determined that one of skill in the art would have looked to Baer's teaching "that the ratio of ethylene oxide and propylene oxide controls the hydrophobicity of the compound. Thus, by adding propylene oxide a person having ordinary skill in the art can control the water and oil solubility of the compound and tailor the properties for the emulsion that is being treated with the compound." Id. Appellant has not sought to rebut such findings. Accordingly, Appellant has failed to show error in the Examiner's determination that a person of skill in the art would have had reason to combine the teachings of Pober and Baer. 7 Appeal2018-004956 Application 14/902,665 Second, Appellant argues that a person of ordinary skill in the art would not have had a reasonable expectation of success in combining the teachings of Pober and Baer because Baer teaches away from the combination. Appeal Br. 9. Appellant argues that Pober is directed to lignites with increased water solubility while Baer teaches that the proposed modification would decrease water solubility (increase hydrophobicity). Id. An invention is obvious if "a skilled artisan would have been motivated to combine the teachings of the prior art references to achieve the claimed invention, and that the skilled artisan would have had a reasonable expectation of success in doing so." Proctor & Gamble Co. v. Teva Pharm. USA, Inc., 566 F.3d 989, 994 (Fed. Cir. 2009) (quoting Pfizer, Inc. v. Apotex, Inc., 480 F.3d 1348, 1361 (Fed. Cir. 2007)). The reasonable expectation of success requirement refers to the likelihood of success in combining references to meet the limitations of the claimed invention. "[F]ailure to consider the appropriate scope of the ... patent's claimed invention in evaluating the reasonable expectation of success ... constitutes a legal error." Allergan, Inc. v. Apotex Inc., 754 F.3d 952, 966 (Fed. Cir. 2014). In other words, one must have a motivation to combine accompanied by a reasonable expectation of achieving what is claimed. Here, the Examiner has put forward a rationale for combining the teachings of Pober and Baer. Appellant argues that such combination would not have been successful in increasing the hydrophilicity of the lignite of Pober, but does not address whether such combination would achieve what is claimed. Rather, Appellant's arguments go to whether there would have been a reason to combine. Further, Pober teaches some variability in the solubility of the reaction product. Pober, 3: 17-53. 8 Appeal2018-004956 Application 14/902,665 To the extent that Appellant argues that one of skill in the art would not have had reason to combine the teachings of Pober and Baer because Baer teaches away from such combination, such argument fails. Prior art may teach away if it "criticize[s], discredit[s], or otherwise discourage[s] the solution claimed." In re Fulton, 391 F.3d 1195, 1201 (Fed. Cir. 2004). Pober' s teaching regarding water solubility do not rise to such level. Indeed, Pober indicates some level of variance in solubility. See Pober 3:50-53 ("The ethoxylated lignites of the present invention are generally insoluble in alkanes such as hexane, pentane and the like.") ( emphasis added). Accordingly, Appellant has not shown reversible error in the Examiner's determination. Claims 31, 32, 47, 50, and 51 over Pober in View of Baer Appellant seeks reversal of the rejection of claims 31, 32, 47, 50, and 51 on the same basis as put forward with regard to claim 1 and its dependents. Appeal Br. 10. As we have found such arguments not to be persuasive, we determine that Appellant has not shown error in this regard concerning the rejection of claims 31, 32, 47, 50, and 51. Appellant additionally references, but does not articulate, an argument that the rejection of claims 32, 47, 50, and 51 is in error because the Examiner has not shown that the cited references teach the "m" and "x" limitations recited in claim 32 (with claims 47, 50, and 51 depending from claim 32). Id. As explained below, this argument is persuasive Claim 55 over Pober in View of Baer Appellant argues that the rejection of claim 55 over Pober in view of Baer is in error. Appeal Brief 11-13. 9 Appeal2018-004956 Application 14/902,665 Claim 55 is to, inter alia, a compound having the following structure (referred to as Structure VII in the Specification and claims): where "mis in the range of from about 1 to about 30 [and] xis in the range of from about O to about 3 00, per 100 g of humus material." First, Appellant argues that claim 55 is not obvious over Pober in view of Baer for the same reasons as set forth with regard to claim 1. Appeal Br. 11. As we have found such arguments not to be persuasive, we determine that Appellant has not shown error in this regard concerning the rejection of claim 55. Second, Appellant argues that the Examiner has not stated an adequate reason why a person of ordinary skill in the art would have had reason to have optimize the "m" and "x" values so as to arrive at the claimed ranges. Id. at 12-13. In regard to the recited values of "m" and "x," the Examiner finds that these values would control the hydrophobicity of the lignite and thus would be considered to be result effective variables. As such, it would have been obvious to a person having ordinary skill in the art at the time of invention to have optimized the m and x values through routine experimentation, and the motivation to do so would have been, as Baer et al. suggests, to provide the desired hydrophobicity to the emulsion breaker of Pober. Final Act. 4 Thus, the Examiner determines that "m" and "x" are result-effective variables. "[W]here the general conditions of a claim are disclosed in the 10 Appeal2018-004956 Application 14/902,665 prior art, it is not inventive to discover the optimum or workable ranges by routine experimentation." In re Aller, 220 F.2d 454, 456 (CCP A 1955). "[D]iscovery of an optimum value of a result effective variable in a known process is ordinarily within the skill of the art." In re Boesch, 617 F.2d 272, 276 (CCPA 1980). Here, the Examiner finds that it would have been within the skill of the art to optimize the hydrophobicity of the emulsion breaker of Pober. Final Act. 4. The Examiner is silent, however, as to whether or not such optimum hydrophobicity would fall within the claimed ranges for the "m" and "x" limitations. Nor has the Examiner adequately explained the relative roles of the "m" and "x" values or how the cited references establish that "m" and "x" are result-effective. See In re Antoine, 559 F.2d 618 (C.C.P.A. 1977) ( explaining that result-effective variable rationale is improper where "the parameter optimized was not recognized to be a result-effective variable .... "). Thus, the general conditions of the claim have not been shown to be disclosed in the prior art. Accordingly, Appellant has shown error in the Examiner's determination that optimization of the variables in question for hydrophobicity would yield the recited values. Rejection 2. The Examiner rejected claims 47, 50, 51, and 55 as obvious over Christian. Final Act. 5. Each of these claims requires an alkoxy group bound to humus material where the "m" and "x" variables indicate the size of the alkoxy structure in a manner similar to claim 5 5. Appeal Br. 27-30 (Claims App.). Appellant makes an argument regarding these claims similar to that it made regarding the rejection of claim 55 over Pober in view of Baer. Appeal Br. 13-15. 11 Appeal2018-004956 Application 14/902,665 The Examiner finds that Christian teaches that the hydroxyl number and ratio of the lignin to the alkoxylating agent are result effective variables. Final Act. 5. The Examiner relies on the following portion of Christian: When the polyoxyalkylene ether-polyol is utilized in the preparation of polyurethane foams, sufficient oxyalkylating agent should be employed in order to obtain a polyoxyalkylene ether-polyol which has a hydroxyl number in the range of about 50 to 1000, preferably in the range of 200 to 800. The weight ratio between the lignin or tannin and the oxyalkylating agent is generally maintained 3: 1 to 1: 100. The preferred lignin or tannin to oxyalkylating agent weight ratio is 1: 1 to 1:20. Christian 3:46-52. This teaching pertains to the preparation of polyurethane foams. As with regard to the previous rejection of claim 55, the Examiner has not shown that the optimum values for "m" and "x" for polyurethane preparation fall within the range of recited values. Nor does the Examiner adequately explain the relative roles of the "m" and "x" values. Accordingly, Appellant has shown error with regard to the rejection of claims 4 7, 50, 51, and 55 as obvious over Christian. Rejections 3--7. The Examiner provisionally rejected claims 1, 9-10, 13, 16, 18, 19, 21, 23, 31-32, 36, 39, 46-47, 51, and 55 on the ground of nonstatutory double patenting as being unpatentable over claims 9-11, 15, and 16 of Application No. 14/893,264 ("the '264 Application") and, for certain claims, a secondary reference. Final Act. 6-8. Appellant argues that such provisional rejections are premature and should be held in abeyance until a notice of allowance is received for either the '264 Application or the present Application. Appeal Br. 16. 12 Appeal2018-004956 Application 14/902,665 Review of public records indicates that the '264 Application issued as U.S. Patent No. 10,144,829 on December 4, 2018. The issued claims appear to be substantially those pending at the time the Final Rejection in the present Application was issued (July 18, 2017). In view of the absence of any substantive argument in the Appeal Brief responding to the subject rejections, we summarily affirm this rejection. See Manual of Patent Examining Procedure (MPEP) § 1205.02 (9th ed. Rev. 08.2017, January 2018) ("If a ground of rejection stated by the examiner is not addressed in the appellant's brief, appellant has waived any challenge to that ground of rejection and the Board may summarily sustain it, unless the examiner subsequently withdrew the rejection in the examiner's answer."). Rejections 8 and 9. The Examiner rejected claims 1, 9, 10, 18, 19, 21, and 27 on the basis of nonstatutory double patenting over claims 1 and 10 of Pober in view of Baer. Final Act. 8-9. The Examiner further rejected claim 31 on the basis of nonstatutory double patenting over claim 12 of Pober in view of Baer. Id. at 9-10. Appellant argues that the rejection of claims 1, 9-10, 18-19, 21, 27, and 31 on the ground of nonstatutory double patenting should be reversed, because the claims at issue require reaction of a "dehydrated humus material" and the cited claims of Pober do not. Appeal Br. 16-17. The Specification provides guidance as to how the term "dehydrated humus material" should be construed. In an embodiment, the humus materials may be dehydrated by heating the humus material (for example, in an oven or dryer such as a rotary dryer) at temperatures of from about 50 °C to about 125 °C, alternatively from about 55 °C to about 120 °C, 13 Appeal2018-004956 Application 14/902,665 or alternatively from about 60 °C to about 110 °C. In an embodiment, the humus material suitable for adding to the reaction mixture or to any pre-mixed components thereof comprises a water content of less than about 3.5 wt.%, alternatively less than about 3 wt.%, alternatively less than about 2.5 wt.%, or alternatively less than about 2 wt.%, by weight of the humus material. Spec. ,r 20 ( emphasis added). During examination, claim terms must be given their broadest reasonable construction consistent with the Specification. In re ICON Health and Fitness, Inc., 496 F.3d 1374, 1379 (Fed. Cir. 2007). In view of the Specification, we construe "dehydrated humus material" to mean humus material comprising a water content of less than 3.5% weight percent. Claim 1 of Pober (and claim 10 and 12 by virtue of dependency) requires that the lignite to be reacted contain "less than about 3.5% by weight water." Pober, 6:43--44. Accordingly, we determine that the relevant claims of Pober require "dehydrated humus material." In view of the foregoing, Appellant has failed to show reversible error in the Examiner's determination that claims 1, 9, 10, 18, 19, 21, and 27 should be rejected on the basis of nonstatutory double patenting over claims 1 and 10 of Pober in view of Baer and that claim 31 shold be rejected on the basis of nonstatutory double patenting over claim 12 of Pober in view of Baer. CONCLUSION The rejection of claims 1, 9, 10, 13, 16, 18, 19, 21, 23, and 31 as obvious over Pober in view of Baer is affirmed. The rejection of claims 32, 47, 50, 51, and 55 over Pober in view of Baer is reversed. The rejection of claims 47, 50, 51, and 55 as obvious over Christian is reversed. The 14 Appeal2018-004956 Application 14/902,665 rejection of claims 1, 9, 10, 13, 16, 18, 19, 21, 23, 31, 32, 36, 39, 46, 47, 51, and 55 on the ground of nonstatutory double patenting over claims 9-11, 15, and 16 of Application No. 14/893,264 (and certain secondary references) is affirmed. The rejection of claims 1, 9, 10, 18, 19, 21, and 27 on the basis of nonstatutory double patenting over claims 1 and 10 of Pober in view of Baer is affirmed. The rejection of claim 31 on the basis of nonstatutory double patenting over claim 12 of Pober in view of Baer is affirmed. Thus, at least one rejection is affirmed with respect to every pending claim except for claim 5 0. No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § 1.136(a). AFFIRMED-IN-PART 15 Copy with citationCopy as parenthetical citation