Ex Parte Phillips et alDownload PDFPatent Trial and Appeal BoardNov 15, 201712852345 (P.T.A.B. Nov. 15, 2017) Copy Citation United States Patent and Trademark Office UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O.Box 1450 Alexandria, Virginia 22313-1450 www.uspto.gov APPLICATION NO. FILING DATE FIRST NAMED INVENTOR ATTORNEY DOCKET NO. CONFIRMATION NO. 12/852,345 08/06/2010 Jeffrey Phillips PWRGP039 3667 22434 7590 11/17/2017 Weaver Austin Villeneuve & Sampson LLP P.O. BOX 70250 OAKLAND, CA 94612-0250 EXAMINER DOVE, TRACY MAE ART UNIT PAPER NUMBER 1726 NOTIFICATION DATE DELIVERY MODE 11/17/2017 ELECTRONIC Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. Notice of the Office communication was sent electronically on above-indicated "Notification Date" to the following e-mail address(es): USPTO@wavsip.com PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE BEFORE THE PATENT TRIAL AND APPEAL BOARD Ex parte JEFFREY PHILLIPS, SAMARESH MOHANTA, DEEP AN BOSE, and CECILIA MASKE Appeal 2016-004152 Application 12/852,345 Technology Center 1700 Before LINDA M. GAUDETTE, N. WHITNEY WILSON, and WESLEY B. DERRICK, Administrative Patent Judges. GAUDETTE, Administrative Patent Judge. DECISION ON APPEAL1 1 This Decision includes citations to the following documents: Specification filed Aug. 6, 2010 (“Spec.”); Final Office Action mailed Apr. 3, 2015 (“Final”); Appeal Brief filed Sept. 4, 2015 (“Appeal Br.”); Examiner’s Answer mailed Feb. 1, 2016 (“Ans.”); and Reply Brief filed Mar. 14, 2016 (“Reply Br.”). Appeal 2016-004152 Application 12/852,345 Appellants2 appeal under 35 U.S.C. § 134(a) from the Examiner’s decision finally rejecting claims 1—6, 9, and 10. We have jurisdiction under 35 U.S.C. § 6(b). We REVERSE. The invention relates to a composition for zinc negative electrodes used in rechargeable nickel-zinc batteries. Spec. 12. Claim 1, the sole independent claim on appeal, is reproduced below: 1. A rechargeable nickel zinc cell comprising: i) a zinc negative electrode comprising electrochemically active zinc and surfactant coated carbon fiber, wherein the surfactant is selected from the group consisting of a polyglycol non-ionic surfactant, a poloxamer and a fluorosurfactant; ii) a nickel positive electrode; and iii) an aqueous alkaline electrolyte. Appeal Br. 15 (Claims App’x). The claims stand finally rejected under 35 U.S.C. § 103(a) as follows: 1. claims 1 and 2 over Furukawa (JP 58163172(A), pub. Sep. 27, 1983 (English Abstract)3) in view of Periard (US 4,810,600, iss. Mar. 7, 1989); and 2. claims 1—6, 9, and 10 over Furukawa in view of Periard, and further in view of Specification paragraphs 76, 106, 109, and 125. 2 Appellants identify the real party in interest as Powergenix Systems, Inc. Appeal Br. 3. 3 Although the rejection appears to be based on the English Abstract (see generally Final 3—8), we also refer to the full English translation (“Furukawa translation”), submitted by Appellants in an information disclosure statement filed January 27, 2012. 2 Appeal 2016-004152 Application 12/852,345 The Examiner finds Furukawa discloses a nickel zinc battery as recited in claims 1 and 2, with the exception that Furukawa does not explicitly use the term “surfactant coated” when describing the carbon fiber. Final 3^4. Rather, the Examiner finds Furukawa describes a carbon fiber “entwined” with “a wettable material.” Id. at 3. The Examiner finds Periard, directed to a cathode coating dispersion for batteries, discloses the use of surfactants to make graphite and/or carbon wettable. See id. at 4. The Examiner finds, therefore, that one of ordinary skill in the art at the time of the invention would have utilized a surfactant as the wettable material in Furukawa’s nickel zinc battery. Id. Based on these findings, the Examiner concludes the invention, as recited in claims 1 and 2, would have been obvious over Furukawa and Periard. Id. In addition to rejecting claims 1 and 2 as obvious over the combination of Furukawa and Periard, the Examiner determines these claims, as well as claims 3—6, 9, and 10 would have been obvious over Furukawa, Periard, and disclosure in the Specification (id. at 4—6) which the Examiner finds is a description of the known prior art (Ans. 8 (explaining that although the relied-upon disclosure in the Specification is not identified as prior art, “use of the phrases ‘generally includes’ and ‘commercially available’ are equivalent to the phrase ‘prior art’”)). With respect to claim 1, for example, the Examiner finds Specification paragraph 125 discloses that it was known in the art at the time of the invention that “surfactant coated carbon fibers, when added to the negative electrode, serve the purpose of irrigating or wetting the electrode.” Final 5. Appellants argue the evidence of record does not support the Examiner’s finding that one of ordinary skill in the art would have used one 3 Appeal 2016-004152 Application 12/852,345 of Periard’s surfactants as the wettable material in Furukawa’s battery. See Appeal Br. 7—8. Appellants further contend the Examiner’s reliance on Specification paragraph 125 in rejecting claim 1 is improper because this paragraph is a description of Appellants’ invention, not the prior art. Id. at 9. Appellants’ arguments are persuasive of error in the Examiner’s rejection of claim 1 for the reasons explained in further detail below. The Specification discloses that “[a] surfactant is a wetting agent[] that lowers the surface tension of a liquid.” Spec. 1132. The Specification discloses that, in the inventive zinc negative electrode, coating carbon fiber with surfactant “enhances the hydrophilicity of the fibers to help maintain conductivity via enhanced electrolyte movement and inhibiting dissolution and deposition of active zinc onto the carbon fibers.” Id. 1134. The Specification discloses that a method of manufacturing surfactant-coated carbon fibers in accordance with the invention includes “i) heat treating carbon fibers to between about 2000°C and about 3000°C; and, ii) exposing the heat treated carbon fibers to a surfactant.” Id. The Specification discloses that, in addition to surfactant coated carbon fibers, there are other materials that can be used in the inventive zinc negative electrode to facilitate wetting, such as titanium oxides. Id. 1125. Furukawa describes entwining titanium oxide, a wettable material, with carbon fiber. Furukawa, Abstract; see also Furukawa translation, p. 3, 11. 2—3, 9-10. Furukawa discloses that “the carbon fibers serve to enhance the electric conductivity of the zinc electrode.” Furukawa translation, p. 3, 11. 5—6. Furukawa discloses that “the addition of titanium oxide ... as wettable material serves to enhance the ability of the zinc electrode to hold 4 Appeal 2016-004152 Application 12/852,345 the electrolytic solution.” Id. at p. 3,11. 2-4. Periard discloses a cathode coating dispersion comprising water, binder, graphite and/or carbon black as the electrically conductive material, and one or more surfactants such as fluorosurfactants. Periard, 1:8—9; 2:1, 6—8, 26—30. Periard discloses that the “surfactants have the task of making the graphite and/or carbon black wettable, of making possible the production of a homogeneous dispersion and of avoiding inclusion of air in the dispersion. ...” Id. at 2:30—33. Appellants argue the Examiner’s rejection is based on an erroneous assumption that a wettable material, e.g., Furukawa’s titanium oxide, is equivalent to a surfactant, e.g., one of Periard’s fluorosurfactants. See Reply Br. 7. Appellants explain that “[w]ettable materials, such as . . . Furukawa’s titanium dioxide, have the function of retaining water within the bulk of material or on the surface. Surfactants, on the other hand, have the function of making other surfaces more wettable by modifying the surface tension of other surfaces.” Id. Appellants’ argument is supported by the above-cited disclosure in the Specification and the references. See Spec. Tflf 125, 132, 134 supra', Furukawa translation, p. 3,11. 2—\ supra. The presence of a wettable material, i.e., titanium dioxide, with carbon fibers is not manifestly equivalent to carbon fibers treated to be wettable, including by treatment with a surfactant. Thus, we agree with Appellants that the Examiner has not explained sufficiently why one of ordinary skill in the art would have replaced Furukawa’s titanium dioxide (a wettable material) with a surfactant (a wetting agent), i.e., a material that performs a different function. Id.', see also Appeal Br. 6. Appellants further argue persuasively that Furukawa and Periard, alone or in combination, fail to teach or suggest the use of surfactant-coated 5 Appeal 2016-004152 Application 12/852,345 carbon fiber in a zinc electrode as required by claim 1. Appeal Br. 6. As argued by Appellants, Periard discloses coating a cathode material with a dispersion of carbon, surfactant, and a binder. Id. The Examiner has not explained sufficiently how replacing Furukawa’s titanium dioxide, which is described as “entwined” with carbon fibers, with a surfactant would result in “surfactant-coated” carbon fiber as required by the claims. Compare Spec. 1134 supra (describing a suitable method of forming surfactant-coated fibers for use in the inventive zinc negative electrode as including a step of exposing carbon fibers that have been heat treated to between about 2000°C and about 3000°C to a surfactant), with Furukawa translation p. 2,11. 5—16 (describing kneading together the titanium oxide, carbon fibers and other materials, drying and pulverizing). We also agree with Appellants that the Examiner has not identified persuasive evidence to support a finding that the disclosure in Specification paragraph 125 is admitted prior art, as applied by the Examiner. In sum, the evidence does not support the Examiner’s conclusion of obviousness as to claim 1. Therefore, we do not sustain the rejections of claim 1, or the rejections of dependent claims 2—6, 9, and 10, which are based on the same unsupported fact finding discussed above. REVERSED 6 Copy with citationCopy as parenthetical citation