Ex Parte Hebrink et alDownload PDFPatent Trials and Appeals BoardJun 17, 201913142025 - (D) (P.T.A.B. Jun. 17, 2019) Copy Citation UNITED STA TES p A TENT AND TRADEMARK OFFICE APPLICATION NO. FILING DATE 13/142,025 06/24/2011 32692 7590 06/19/2019 3M INNOVATIVE PROPERTIES COMPANY PO BOX 33427 ST. PAUL, MN 55133-3427 FIRST NAMED INVENTOR Timothy J. Hebrink UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www .uspto.gov ATTORNEY DOCKET NO. CONFIRMATION NO. 64819US012 9007 EXAMINER LEI, JIE ART UNIT PAPER NUMBER 2872 NOTIFICATION DATE DELIVERY MODE 06/19/2019 ELECTRONIC Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. Notice of the Office communication was sent electronically on above-indicated "Notification Date" to the following e-mail address(es): LegalUSDocketing@mmm.com PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE BEFORE THE PATENT TRIAL AND APPEAL BOARD Ex parte TIMOTHY J. HEBRINK, SEBASTIAN F. ZEHENTMAIER, and LUDWIG MA YER Appeal2018-007500 Application 13/142,025 Technology Center 2800 Before ROMULO H. DELMENDO, MARK NAGUMO, and CHRISTOPHER C. KENNEDY, Administrative Patent Judges. DELMENDO, Administrative Patent Judge. DECISION ON APPEAL The Applicants 1 ("Appellants") appeal under 35 U.S.C. § 134(a) from the Primary Examiner's final decision to reject claims 1, 5-10, 12, 14--18, 22, 23, 27, and 28. 2 We have jurisdiction under 35 U.S.C. § 6(b). We affirm. 1 The Applicants identify "3M Company ... and its affiliate 3M Innovative Properties Company" as the real parties in interest (Appeal Brief filed May 22, 2017 ("Appeal Br."), 2). 2 Appeal Br. 4--13; Reply Brief filed July 16, 2018 ("Reply Br."), 2-5 (not paginated); Final Office Action entered October 17, 2016 ("Final Act."), 2- 17; Examiner's Answer entered May 17, 2018 ("Ans."), 2-11. Appeal2018-007500 Application 13/142,025 I. BACKGROUND The subject matter on appeal relates to a multilayer optical film and to a method for making such a film (Specification filed June 24, 2011 ("Spec."), 1, 11. 5---6). The Appellants explain that "[b ]y selecting the appropriate layer pairs, the layer thickness, and/or the number of layer pairs [in the optical film], the optical stack [i.e., the optical film] can be designed to transmit or reflect the desired wavelengths" (id. at 9, 11. 5-7). The optical film is described as being useful in architectural applications, greenhouse applications, solar power applications, lighting, fenestration products, and other applications (id. at 20, 11. 30-32). Representative claim 1, which is the sole independent claim, is reproduced from the Claims Appendix to the Appeal Brief, as follows: 1. A multilayer optical film comprising an optical stack, wherein the optical stack comprises: a) a plurality of first optical layers, each first optical layer comprising a single melt-processible polymer, wherein the melt-processible polymer comprises interpolymerized units derived from tetrajluoroethylene, hexajluoropropylene, and vinylidene fluoride; and b) a plurality of second optical layers disposed in a repeating sequence with the plurality of first optical layers, each second optical layer comprising a non-fluorinated polymeric material selected from the group consisting of: poly(methyl methacrylate ); copolymers of poly(methyl methacrylate ); polypropylene; copolymers of propylene; polystyrenes; copolymers of styrene; polyvinylidene chloride; polycarbonates; thermoplastic polyurethanes; copolymers of ethylene; cyclic olefin copolymers; and combinations thereof wherein the optical stack comprises layer pairs comprising the first optical layer and the second optical layer. (Appeal Br. 14 (emphasis added).) 2 Appeal2018-007500 Application 13/142,025 II. REJECTIONS ON APPEAL The claims on appeal stand rejected under pre-AIA 35 U.S.C. § 103(a) as follows: A. Claims 1, 5-10, 12, 15-18, 23, 27, and 28 as unpatentable over Wheatley et al. 3 ("Wheatley") in view of Fukushi et al. 4 ("Fukushi"); and B. Claims 14 and 22 as unpatentable over Wheatley and Fukushi, further in view of Condo et al. 5 ("Condo"). (Ans. 2-11; Final Act. 2-17.) III. DISCUSSION Rejection A. The Appellants' arguments focus primarily on claim 1 but also address several additional claims (Appeal Br. 4--12). Therefore, we address claim 1 and any other claims that have been argued separately within the meaning of 37 C.F.R. § 4I.37(c)(l)(iv). 1. Claim 1 The Examiner finds that Wheatley describes a multilayer optical film including every limitation recited in claim 1 except the reference does not specifically disclose that each first optical layer includes a melt-processible polymer comprising interpolymerized units derived from tetrafluoroethylene, hexafluoropropylene, and vinylidene fluoride (Final Act. 3--4). The Examiner finds, however, that Fukushi teaches a multi-layer article including (i) a first optical layer comprising a fluoropolymer with 3 US 5,278,694, issued January 11, 1994. 4 US 6,074,719, issued June 13, 2000. 5 US 6,498,683 B2, issued December 24, 2002. 3 Appeal2018-007500 Application 13/142,025 interpolymerized units derived from tetrafluoroethylene, hexafluoropropylene, and vinylidene fluoride and (ii) a second layer comprising a non-fluorinated polymer, wherein the article exhibits certain advantageous properties (flexibility and resistance to chemical agents, solvents, and soil) (id. at 4). Based on these findings, the Examiner concludes: [I]t would have been obvious to a person having ordinary skill in the art ... to modify the multilayer optical film of Wheatley by the multilayer of Fukushi for the purpose of providing of a multi- layer compositions and articles of retroreflective which is [sic] flexible, resistant to chemical agents, solvents, soils, reduced moisture vapor transmission, and particularly useful for making articles, such as tubing and hoses suitable for use in motor vehicles, for example as fuel-line hoses, and flexible retroreflective sheetings. (Id., emphasis added). The Examiner also concludes that the claimed subject matter would have been obvious because "it has been held to be within the general skill of a worker in the art to select a known material on the basis of its suitability for the intended use as a matter of design choice, involv[ing] only routine skill in the art" (Ans. 7 (internal citation omitted)). See also Advisory Action entered January 4, 2017, 2. The Appellants contend that Wheatley ( disclosing reflective films) and Fukushi ( disclosing retroreflective films) cannot be combined as proposed in the rejection because these references are not in the same field of endeavor (Appeal Br. 5-6). The Appellants argue that Fukushi teaches a different type of construction because the 2-layer polymer construction would contain retrorefractive elements in the form of physical elements such as cube comers, microspheres, or prisms, which alter light rather than 4 Appeal2018-007500 Application 13/142,025 substantially reflect light, and that "the individual polymeric layers of Fukushi are in the hundreds of micrometers in thickness not the micrometer or submicrometer thicknesses disclosed in Wheatley, Condo, or the present application" (id. at 6-7). Furthermore, the Appellants argue that the rejection fails to articulate a sufficient motivation or reason to substitute Wheatley' s perfluorinated polymers with a tetrafluoroethylene- hexafluoropropylene-vinylidene fluoride terpolymer as disclosed in Fukushi (id. at 7-8). Regarding the Examiner's obviousness based on selection rationale, the Appellants argue that Wheatley discloses a myriad of suitable thermoplastic resins (i.e., 820 combinations) and that the Examiner "failed to show why a person having ordinary skill in the art would tum away from the about 820 combinations of Wheatley and tum to a reference which is not in the same field" (id. at 8-9). For the reasons discussed below, we conclude that the Appellants' arguments fail to identify any reversible error in the Examiner's conclusion that it would have been obvious to select and use an interpolymer derived from units comprising tetrafluoroethylene, hexafluoropropylene, and vinylidene fluoride in Wheatley as a matter of obvious selection based on its expected suitability. In re Jung, 637 F.3d 1356, 1365 (Fed. Cir. 2011). Wheatley describes a multilayered reflective polymer body comprising a sufficient number of alternating layers of first and second polymeric materials such that at least 30% of the light incident on the body is reflected (Wheatley, Abstract; Fig. 1; col. 2, 1. 66-col. 3, 1. 9). As the Examiner finds (Final Act. 3), Wheatley discloses an embodiment in which a copolycarbonate (ofthiodiphenol and bisphenol-A}-i.e., a polycarbonate- 5 Appeal2018-007500 Application 13/142,025 is identified as a preferred second polymeric material (Wheatley, col. 4, 11. 49-51 ). Wheatley teaches that in this embodiment, the first polymeric material comprises a copolymer (i.e., an interpolymer) of methyl methacrylate, vinylidene fluoride, and a fluorocarbon monomer selected from a list of identified fluorocarbon monomers (id., col. 4, 11. 3 8--49). Both polymeric materials in Wheatley are disclosed as "thermoplastic" materials that may be processed in a heat plastifying extruder-i.e., these materials are melt-processible (id., col. 12, 11. 64---66). Fukushi discloses a multilayer article comprising a fluoropolymer layer comprising interpolymerized units derived from vinylidene fluoride and a melt-processible, substantially non-fluorinated polymer comprising a polyamide, polyimide, polyurethane, or a carboxyl-, anhydride-, or imide- functionalized polyolefin (Fukushi, Abstract). Fukushi teaches that the fluoropolymer may be a homopolymer, copolymer, or terpolymer derived from monomers selected from the group consisting of vinylidene fluoride, tetrafluoroethylene, and hexafluoropropene (id., col. 19, 11. 24--29). Fukushi teaches: Transparent embodiments of multi-layer compositions of the present invention may find particular utility in the construction of retroreflective sheeting articles generally, and particularly when resistance to chemical agents, solvents, soils, reduced moisture vapor transmission or good interlayer adhesion in flexible sheetings subject to severe bending and flexing is required. (Id., col. 6, 11. 25-31 (emphases added).) Considering the prior art teachings as a whole, we concur with the Examiner that the claimed subject matter would have been obvious to a person having ordinary skill in the art based on the prior art's suggestion to 6 Appeal2018-007500 Application 13/142,025 select and use a fluoropolymer material that includes the same monomers recited in claim 1 (i.e., vinylidene fluoride, tetrafluorethylene, and hexafluoropropylene ). As we found above, Wheatley teaches an embodiment in which: (i) the first polymeric material comprises an interpolymer of methyl methacrylate, vinylidene fluoride, and a fluorocarbon monomer selected from a list of identified monomers; and (ii) the second polymeric material is a copolycarbonate (id., col. 4, 11. 38- 51 ). Regarding the fluorocarbon monomers that may be interpolymerized with methyl methacrylate and vinylidene fluoride, Wheatley identifies a finite number of various fluorocarbon monomers including, inter alia, hexafluoropropylene and tetrafluoroethylene (id.). Although Wheatley does not disclose reacting a mixture of fluorocarbon monomers with methyl methacrylate and vinylidene fluoride, a person having ordinary in the art would have found it obvious to select an interpolymer of methyl methacrylate, 6 vinylidene fluoride, and a mixture of both hexafluoropropylene and tetrafluoroethylene as the first polymeric material based on the reasonable expectation that a mixture of fluorocarbon monomers, each identified as suitable, would also provide a suitable interpolymer. In re Kerkhoven, 626 F.2d 846, 850 (CCPA 1980) (citation omitted) ("It is prima facie obvious to combine two compositions each of which is taught by the prior art to be useful for the same purpose, in order to 6 The additional presence of methyl methacrylate in Wheatley is immaterial because claim 1 does not exclude unrecited monomers in the interpolymer. In re Baxter, 656 F.2d 679, 686 (CCPA 1981) ("As long as one of the monomers in the reaction is propylene, any other monomer may be present, because the term 'comprises' permits the inclusion of other steps, elements, or materials."). 7 Appeal2018-007500 Application 13/142,025 form a third composition which is to be used for the very same purpose."). See also Hotchkiss v. Greenwood, 52 U.S. 248,265 (1850) ("[T]he knob of clay was simply the substitution of one [known] material for another [ wood]."). In this regard, Fukushi demonstrates that a similar interpolymer derived from vinylidene fluoride, tetrafluoroethylene, and hexafluoropropylene has been successfully used in multilayers having optical properties (Fukushi, col. 6, 11. 25-31; col. 19, 11. 24--29 (claim 10)). Thus, a person having ordinary skill in the art would have had a reasonable expectation of success in selecting and using an interpolymer derived from methyl methacrylate, vinylidene fluoride, tetrafluoroethylene, and hexafluoropropylene in Wheatley's optical multilayer. The Appellants' argument that Wheatley teaches a myriad of polymers lacks persuasive merit because as we found above, Wheatley discloses a specific embodiment in which the combination of the same fluorocarbon monomers specified in claim 1 may be selected from a list of finite options (Wheatley, col. 4, 11. 38--45). Wm. Wrigley Jr. Co. v. Cadbury Adams USA LLC, 683 F.3d 1356, 1364--65 (Fed. Cir. 2012) (explaining that a "strong case of obviousness" exists where the combination of ingredients recited in the claims were based on selections from a finite number of identified, predictable solutions). See also Merck & Co., Inc. v. Biocraft Labs., Inc., 874 F.2d 804, 807 (Fed. Cir. 1989) ("That the [reference] discloses a multitude of effective combinations does not render any particular formulation less obvious."); In re Corkill, 771 F.2d 1496, 1500 (Fed. Cir. 1985) (upholding obviousness rejection of claims based on prior art teaching that "hydrated zeolites will work" in detergent formulations, 8 Appeal2018-007500 Application 13/142,025 even though "the inventors selected the zeolites of the claims from among 'thousands' of compounds"). Because we sustain the rejection of claim 1 on the ground that the claimed subject matter is unpatentable as a matter of obvious selection of a known or suggested material based on its suitability for the purpose disclosed in Wheatley, we need not reach the Examiner's alternative rationale based on the advantages disclosed in Fukushi (Fukushi, col. 6, 11. 25-31). 2. Claim 28 Claim 28, which depends from claim 1, recites that "the non- fluorinated polymeric material is selected from the group consisting of: poly(methyl methacrylate ), copolymers of poly(methyl methacrylate ), and combinations thereof' (Appeal Br. 17). The Appellants acknowledge that the Examiner relies on Wheatley for these materials but argues that these materials are not disclosed in Fukushi (id. at 9). Because Wheatley teaches polymethyl methacrylate as an alternative second polymeric material (Wheatley, col. 6, 11. 22-23, 56-57), the Appellants' arguments focusing solely on Fukushi are inapt. In re Keller, 642 F.2d 413,425 (CCPA 1981). Accordingly, we uphold the rejection of claim 28. 3. Claims 5 and 6 Claims 5 and 6, which depend from claim 1, recite that the optical stack transmits and receives, respectively, at least portions of light having certain specified wavelengths (Appeal Br. 14--15). The Appellants acknowledge that "[t]he [Examiner] relies solely on the teaching of Wheatley" for these claims but argues that "if the [Examiner] is replacing 9 Appeal2018-007500 Application 13/142,025 the polymeric material of Wheatley with that of Fukushi, the [Examiner] has not shown nor provided evidence that such a combination of materials would reflect or transmit the wavelengths recited" (id. at 10). The Appellants' argument is not persuasive. As the Examiner finds (Final Act. 5-6), Wheatley's films may be useful as optical interference films for reflecting wavelength in the infrared region while transmitting light in the visible spectrum (Wheatley, col. 7, 11. 48-52). This teaching in Wheatley is sufficient to meet the limitations in claims 5 and 6, as broadly recited. Furthermore, consistent with the Examiner's position (Ans. 9), the claimed film's functional limitations or characteristics would necessarily follow from the prior art-suggested modification of Wheatley' s film in view of the structural similarities between the claimed film and Wheatley' s film. In re Dillon, 919 F.2d 688, 692 (Fed. Cir. 1990) (en bane) ("[S]tructural similarity between claimed and prior art subject matter, proved by combining references or otherwise, where the prior art gives reason or motivation to make the claimed compositions, creates a prima facie case of obviousness, and ... the burden (and opportunity) then falls on an applicant to rebut that prima facie case."). For these reasons, we sustain the rejection of claims 5 and 6. 4. Claim 16 Claim 16 recites: "A coating comprising small pieces of the multilayer optical film according to claim 1, wherein the largest dimension of each piece is at least twice the thickness of the multilayer optical film and not more than the maximum thickness of the coating" (Appeal Br. 16). The Specification informs one skilled in the relevant art that the subject matter recited in claim 16 includes a coating (in the form of a matrix) that 10 Appeal2018-007500 Application 13/142,025 incorporates small pieces of the multilayer optical film as glitter (Spec. 21, 11. 21-28). The Examiner's position regarding claim 16, which has been consistent throughout the prosecution, is stated as follows: [I]t is common knowledge in the art that the multilayer optical film can be converted into small pieces of the multilayer optical film in any variety of desired shapes and sizes, including the largest dimension of each piece is at least twice the thickness of the multilayer optical film and not more than the maximum thickness of the coating ... (Final Act. 8; Non-Final Action entered January 25, 2013.) In the Appeal Brief, the Appellants argue, for what appears to be the first time in the prosecution: If the Examiner is relying upon personal knowledge of cutting a multilayer optical film into small pieces and using it in a coating, the Examiner is respectfully requested to supply an affidavit for this record as per 37 CPR § 1.104(d)(2), cite evidence to this effect, or withdraw the unsupported assertion. (Appeal Br. 10; compare, e.g., Reply filed December 19, 2016, 8 (relying on claim 1 for the patentability of claim 16) and Reply filed August 1, 2016, 10 (same)). The Appellants' request does not amount to a substantive argument that the subject matter recited in claim 16 is independently or separately patentable from claim 1. See MPEP § 2144.03(C) (Rev. 08.2017, Jan. 2018) ("To adequately traverse such a [noticed] finding, an applicant must specifically point out the supposed errors in the examiner's action, which would include stating why the noticed fact is not considered to be common knowledge or well-known in the art.) (Emphasis added). Indeed, the 11 Appeal2018-007500 Application 13/142,025 Appellants do not assert that the noticed information is their contribution to the art or their discovery. Moreover, the Appellants' request for an Examiner's affidavit or evidence on appeal after closing of prosecution was untimely because the Examiner cannot add additional evidence into the record without reopening prosecution. Because the Appellants' request was untimely, we are constrained to take the officially noticed information as undisputed fact. Cf In re Ahlert, 424 F.2d 1088, 1091 (CCPA 1970) ("Where the appellant has failed to challenge a fact judicially noticed and it is clear that he has been amply apprised of such finding so as to have the opportunity to make such challenge, the board's finding will be considered conclusive by this court."). As a mere request to supply evidence in and of itself is insufficient to identify any reversible error in the Examiner's position, which has been consistent throughout the prosecution since January 25, 2013, we sustain the rejection of claim 16. 5. Claim 23 Claim 23 recites: "The multilayer optical film according to claim 1, wherein the layer pair has an optical thickness that is about half of a wavelength of interest, wherein the wavelength of interest is from 250 to 400 nm or from 350 to 800 nm" (Appeal Br. 17). The Appellants argue that Wheatley has not been shown to disclose or suggest the specified layer pair thickness and that, instead, the "layer pairs of Wheatley appear to require a minimum of optical thickness of at least 450 nm" (Appeal Br. 10-11 (citing, e.g., Wheatley, col. 3, 11. 10-14)). This argument is not persuasive. As the Examiner points out (Final Act. 11-12), Wheatley teaches: "For example, first order visible reflections 12 Appeal2018-007500 Application 13/142,025 of violet (0.38 micrometer [380 nm] wavelength) to red (0.68 micrometer [680 nm] wavelength) can be obtained with layer optical thicknesses between about 0.075---0.25 micrometers [75-250 nm]" (Wheatley, col. 9, 11. 17-20). In addition, as the Examiner finds (Ans. 10), Wheatley teaches that "it is not necessary for all of the layers in the reflective polymeric bodies ... to have optical thicknesses of0.45 micrometers [450 nm] or greater or 0.09 micrometers [90 nm] or less" ( emphasis added) and that "useful reflective bodies and articles may be made even with such wide variations as long as a substantial majority of the layers have an optical thickness of not more than 0.09 micrometers [90 nm] or not less than 0.45 micrometers [ 450 nm]" (id., col. 10, 11. 6-9, 16-20). Therefore, Wheatley's thickness ranges overlap the ranges recited in claim 23, and thus a prima facie case of obviousness exists. In re Peterson, 315 F.3d 1325, 1329 (Fed. Cir. 2003) ("Aprimafacie case of obviousness typically exists when the ranges of a claimed composition overlap the ranges disclosed in the prior art."). Because the prima facie case has not been successfully rebutted, we uphold the rejection of claim 23. Rejection B. Claim 14, which depends from claim 12, 7 recites that "the multilayer optical film is disposed between at least two panes of glass" (id. at 15). Claim 22 recites: "The multilayer optical film according to claim 1, wherein the first optical layer and the second optical layer have the same thickness" (id. at 1 7). 7 Claim 12 recites: "An article comprising the multilayer optical film according to claim 1" (Appeal Br. 15). 13 Appeal2018-007500 Application 13/142,025 Regarding claim 14, the Examiner finds that Condo teaches multilayer optical bodies disposed between two panes of glass (Final Act. 13 ( citing Condo, Figs. 1, 2, 12, 14; col. 7, 11. 11-13)). The Examiner concludes: Therefore, it would have been obvious to a person having ordinary skill in the art at the time the invention was made to modify the multilayer optical film of Wheatley-Fukushi combination by the multilayer optical bodies of Condo for the purpose of providing a multilayer light-reflecting optical bodies that reflect light over a range of wavelengths and are suited to applications such as UV reflective films used, for example, to protect other films and objects from UV radiation .... (Id. at 13-14). Regarding claim 22, the Examiner finds that Condo teaches a multilayer optical body in which the first optical layer and the second optical layer have the same thickness (Final Act. 14 ). The Examiner concludes that, therefore, the claimed subject matter would have been obvious over the collective teachings in the prior art (id.). Regarding claim 14, the Appellants argue that it is unclear "why one of ordinary skill in the art in possession of Wheatley, which appears to encompass ultra violet radiation, would tum to Condo" (Appeal Br. 12). Regarding claim 22, the Appellants argue that Wheatley and Fukushi teach away from Condo because "Condo teaches two optical layers that are each a quarter of a wavelength thick or having different optical thickness, as long as the sum of the optical thicknesses is half of a wavelength ( or a multiple thereof)," whereas Wheatley states that "'a thin film can be described as a film thinner than one wavelength of light at which the film will be applied'" (id. (internal citations omitted)). We disagree with the Appellants. Condo teaches that the "optical body can be used as an IR film, to, for example, reflect solar energy from, 14 Appeal2018-007500 Application 13/142,025 for example, windows of building and automobiles" (Condo, col, 7, 11. 11- 13; Figs. 1, 2). Wheatley teaches that "light" in the context of its disclosure encompasses not only visible light but also electromagnetic radiation in both the infrared and ultraviolet regions of the light spectrum (Wheatley, col. 3, 11. 3---6). Therefore, as far as claim 14 is concerned, we do not view Wheatley' s disclosure as teaching away from Condo. As for claim 22, we agree with the Examiner that Condo and Wheatley are not in tension. Wheatley teaches that "a thin film can be described as a film thinner than one wavelength of light at which the film will be applied" (Wheatley, col. 8, 11. 51-55), whereas Condo teaches that "[t]he optical layers 12, 14 can each be a quarter wavelength thick or the optical layers 12, 14 can have different optical thicknesses, as long as the sum of the optical thicknesses is half of a wavelength ( or a multiple thereof)" (Condo, col. 6, 11. 32-36). Again, we do not find that these disclosures to be in tension with each other or otherwise teach away from each other. For these reasons, we sustain Rejection B. IV. SUMMARY Rejections A and Bare sustained. Therefore, the Examiner's final decision to reject claims 1, 5-10, 12, 14--18, 22, 23, 27, and 28 is affirmed. No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § 1.136(a). AFFIRMED 15 Copy with citationCopy as parenthetical citation