Ex Parte Endo et alDownload PDFPatent Trial and Appeal BoardOct 29, 201813503476 (P.T.A.B. Oct. 29, 2018) Copy Citation UNITED STA TES p A TENT AND TRADEMARK OFFICE APPLICATION NO. FILING DATE 13/503,476 04/23/2012 7055 7590 10/31/2018 GREENBLUM & BERNSTEIN, P.L.C. 1950 ROLAND CLARKE PLACE RESTON, VA 20191 FIRST NAMED INVENTOR Toshihiro Endo UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www .uspto.gov ATTORNEY DOCKET NO. CONFIRMATION NO. P48836 9726 EXAMINER FAISON, VERONICAF ART UNIT PAPER NUMBER 1731 NOTIFICATION DATE DELIVERY MODE 10/31/2018 ELECTRONIC Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. Notice of the Office communication was sent electronically on above-indicated "Notification Date" to the following e-mail address(es): gbpatent@gbpatent.com greenblum.bernsteinplc@gmail.com PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE BEFORE THE PATENT TRIAL AND APPEAL BOARD Ex parte TOSHIHIRO ENDO, MASAKATSU ARAI, KENJI YAMADA, KATSUMI KURIYAMA, ATSUSHI TANAKA, KAZUYA KAWAKAMI, SHIN-ICHIRO SHIMURA, SHOTARO KON, YOSHIAKI MATSUZAWA, and KOHJI NOMURA Appeal2018-000738 Application 13/503,476 1 Technology Center 1700 Before ADRIENE LEPIANE HANLON, BRIAND. RANGE, and MERRELL C. CASHION, JR., Administrative Patent Judges. HANLON, Administrative Patent Judge. DECISION ON APPEAL A. STATEMENT OF THE CASE The Appellants filed an appeal under 35 U.S.C. § 134(a) from an Examiner's decision finally rejecting claims 1 and 2, which are all of the pending claims. We have jurisdiction under 35 U.S.C. § 6(b ). We REVERSE and enter new grounds of rejection under 37 C.F.R. § 41.50(b). 1 The real party in interest is said to be RISO KAGAKU CORPORATION. Supplemental Appeal Brief dated March 28, 2017 ("App. Br."), at 3. Appeal2018-000738 Application 13/503,476 The claimed subject matter is directed to an oil-based inkjet ink comprising a pigment, a dispersant, and a water-insoluble organic solvent, wherein a calcium content in the ink is 8 ppm or less and a magnesium content in the ink is 3 ppm or less. According to the Appellants, when an oil-based inkjet ink is used for a long time, solids will accumulate in the vicinity of the nozzles of the inkjet head, hindering normal ejection of the ink. Spec. 2, 11. 1-3. The Appellants disclose: Conventionally, causes of this ink clogging are believed to be thickening of the ink or agglomeration of the pigment due to condensation of the ink in the nozzles, generation of a significant amount of coarse particles during dispersion, agglomeration caused by temporal change due to poor stability of the dispersed pigment, etc. Spec. 2, 11. 4--9. The Appellants are said to have found through intensive study that the main cause of the agglomeration of solid in the vicinity of the nozzles is actually a water-soluble metal salt, although the ink is an oil-based ink, and components dissolved in a slight amount of water contained in raw materials of the ink ( a pigment, a resin, a solvent and other additives) accumulate in the vicinity of a member that contacts the ink, i.e., the nozzles, as solids along with evaporation of the moisture. Spec. 2, 1. 20-3, 1. 4. Among the components forming an ink, a pigment, in particular, is said to contain a significant amount of calcium and magnesium ( collectively referred to as "polyvalent metals"). Spec. 4, 1. 21-5, 1. 1. The Appellants disclose that various methods are used to reduce the polyvalent metal content in the ink. Spec. 5, 11. 11- 12. Preferred examples are said to include washing raw materials of the ink, such 2 Appeal2018-000738 Application 13/503,476 as the pigment, with ion-exchanged water2 or contacting the prepared ink with a substance, such as an ion-exchange resin, that can remove the polyvalent metals from the ink. Spec. 5, 11. 12-15; id. at 6, 11. 6-7. Independent claim 1 is reproduced below from the Claims Appendix to the Supplemental Appeal Brief. 3 1. An oil-based inkjet ink comprising at least a pigment, a dispersant and an organic solvent, wherein a calcium content in the ink is 8 ppm or less, and a magnesium content in the ink is 3 ppm or less, and the organic solvent is water-insoluble. App. Br. 17. The Examiner maintains the following grounds of rejection on appeal: (1) claims 1 and 2 under 35 U.S.C. § I03(a) as obvious over JP 064; 4 (2) claims 1 and 2 under 35 U.S.C. § I03(a) as obvious over Endo; 5 and (3) claims 1 and 2 under 35 U.S.C. § I03(a) as obvious over WO 633. 6 B. DISCUSSION 1. Rejections ( I }----(3) The Examiner finds that JP 064 discloses an oily ink for ink-jet recording comprising a solvent composed mainly of an ester solvent and an alcohol solvent, a pigment dispersing agent, and a pigment. Ans. 3. 7 Likewise, the Examiner finds that Endo discloses a non-aqueous ink comprising a pigment, a dispersing agent, 2 See Spec. 16 ( comparing the rate of ejection failure in inks containing washed pigment with the rate of ejection failure in inks containing unwashed pigment). 3 According to the Appellants, the Supplemental Appeal Brief corrects the reference to "water-soluble" organic solvent in the original Appeal Brief dated March 9, 2017. App. Br. 1. 4 JP 2005-290064 dated October 20, 2005 ("JP 064"). 5 US 2009/0196994 Al, published August 6, 2009 ("Endo"). 6 WO 97/15633, published May 1, 1997 ("WO 633"). 7 Examiner's Answer dated September 8, 2017. 3 Appeal2018-000738 Application 13/503,476 and a water-insoluble solvent. Ans. 3--4; see also Endo ,r 2 (disclosing that non- aqueous inks include oil inks). The Examiner makes similar findings as to WO 633. Ans. 4--5. The Examiner finds that JP 064, Endo, and WO 633 are silent as to the calcium content and the magnesium content of the disclosed inks. Ans. 3, 4, 5. Nonetheless, the Examiner finds that Suzuki8 teaches that "it is preferable to remove organic and inorganic impurities of pigments for the prevention of clogging and kogation."9 Ans. 3, 4, 5 ( citing Suzuki, col. 8, 11. 57-65). Based on the teachings in Suzuki, the Examiner concludes that [I]t would be obvious to one of ordinary skill in the art to want an [sic] lower amount of calcium and magnesium within applicant's claimed range as it is known in the art that these elements cause clogging and kogation which is undesirable as it will affect the print quality of the ink composition. Ans. 3, 4, 5. Significantly, Suzuki is not included in the statement of any of the rejections on appeal. For that reason, the obviousness rejections on appeal are not sustained. See In re Hoch, 428 F.2d 1341, 1342 n.3 (CCPA 1970) ("Where a reference is relied on to support a rejection, whether or not in a 'minor capacity,' there would 8 US 6,051,645, issued April 18, 2000 ("Suzuki"). 9 The Examiner also relies on Suzuki to establish that the calcium and magnesium content of the inks disclosed in JP 064, Endo, and WO 633 is within the claimed range. Ans. 3, 4, 5. To the extent that the Examiner is relying on Suzuki to show that the inks disclosed in JP 064, Endo, and WO 633 inherently have the claimed calcium and magnesium content, the Examiner has not provided a sufficient factual basis to support a finding that calcium and magnesium have been removed from the pigments in the inks of JP 064, Endo, and/or WO 633, as disclosed in Suzuki. See App. Br. 10. 4 Appeal2018-000738 Application 13/503,476 appear to be no excuse for not positively including the reference in the statement of the rejection."). 2. New grounds of rejection Claim 1 is rejected under 35 U.S.C. § 103(a) as unpatentable over JP 064 10 in view of Suzuki and the Appellants' "Description of the Related Art." 11 Claims 1 and 2 are rejected under 35 U.S.C. § 103(a) as unpatentable over Endo and WO 633, both in view of Suzuki and the Appellants' "Description of the Related Art." We adopt the Examiner's factual findings with respect to JP 064, Endo, WO 633, and Suzuki. Ans. 3-5. Based on the teachings of Suzuki, we concur with the Examiner that it would have been obvious to one of ordinary skill in the art to lower the amount of calcium and magnesium in the oil-based inkjet inks of JP 064, Endo, and WO 633 to reduce clogging in the nozzles of an ink-jet head. See Suzuki, col. 8, 11. 57----62. The Appellants argue that Suzuki, in contrast to JP 064, Endo, and WO 633, discloses an aqueous ink. App. Br. 12. The Appellants argue that "[i]n aqueous inks, water is used as the main solvent and would be the main evaporating component." App. Br. 12. As water is evaporated in aqueous inks, the Appellants argue that "clogging occurs in the locations where the water evaporates ( such as a tip of a nozzle), due to scale buildup caused by the water-soluble salt of metal ions such as calcium ions and magnesium ions." 12 App. Br. 12. The Appellants argue 10 We rely on the translated Abstract of JP 064, which is of record in the instant Application. The Abstract of JP 064 does not identify the specific pigment(s) contained in the ink. Therefore, claim 2, which recites that "the pigment is copper phthalocyanine," (App. Br. 17), is not included in this rejection. 11 Spec. 1, 1. 8-2, 1. 19. 12 The Appellants direct our attention to page 162 of Inkjet Technology and Product Development Strategies to show that calcium causes scale buildup in 5 Appeal2018-000738 Application 13/503,476 that "[ n ]othing in the cited art suggests that the concerns of an aqueous solvent- based ink are the same as those for a non-aqueous solvent-based ink, and the examiner has provided no reasonable explanation for why these teachings would be combined." App. Br. 12. In the Appellants' Specification in the section entitled "Description of the Related Art," the Appellants disclose that at the time of the Appellants' invention it was known in the art that "when an oil-based inkjet is used for [a] long time, solids will accumulate in the vicinity of the nozzles of the inkjet head, and this hinders normal ejection of the ink and may result in defective images." Spec. 2, 11. 1--4; see also Ans. 14. The ink disclosed in Suzuki is said to prevent clogging in the leading end of a nozzle. Suzuki, col. 2, 11. 9-10. Suzuki discloses: It is preferable to remove organic and inorganic impurities from [the disclosed] pigments for the purpose of prevention of clogging, and kogation on a heater in thermal ink jet method. In particular, it is desired that the concentration of calcium, iron, silicon, magnesium, phosphorus, zinc and the like in ink is 5 ppm or less. Such removal can be conducted by washing with water, ultra filtration method, ion exchange treatment, adsorption by activated charcoal or zeolite, and the like. Suzuki, col. 8, 11. 57-65 ( emphasis added). Significantly, the Appellants do not direct us to any evidence establishing that the pigments used in Suzuki's inkjet inks are different from the pigments used locations where ink evaporates. App. Br. 12. According to the Appellants, a copy of at least page 162 of the document was provided to the Examiner during prosecution and is part of the written record. See Appellants' Response dated August 26, 2016, at 4 (indicating that a copy of page 162 of Inkjet Technology and Product Development Strategies is attached to the Response). However, we have been unable to locate the document in the Official Application file, and a copy of the document is not included in the Evidence Appendix to the Appeal Brief. 6 Appeal2018-000738 Application 13/503,476 in oil-based inkjet inks. See Suzuki, col. 7, 11. 61---63 (disclosing that "[a]s the pigment used as a coloring material in ink jet recording inks of the present invention, any of inorganic pigment and organic pigment can be used"). Thus, one of ordinary skill in the art would have found Suzuki's teachings useful in solving the known problem of clogged print head nozzles caused by oil-based inkjet inks. In an attempt to rebut the prima facie case of obviousness, the Appellants argue that "the presently claimed invention produces unexpectedly good results, as evidenced by the specification." App. Br. 14. For support, the Appellants direct our attention to "the demonstrated rate of ejection failure, as shown in Table 2," and more specifically the results of Examples 1 and 6 and Comparative Examples 1 and 3. App. Br. 14. To the extent that the Specification demonstrates that the claimed invention provides an improved rate of ejection failure, the Specification does not describe the results as "unexpected." See In re Freeman, 474 F.2d 1318, 1324 (CCPA 1973) (in order for a showing of "unexpected results" to be probative evidence of non-obviousness, the applicant must establish that the difference between the results obtained through the claimed invention and those of the prior art would not have been expected by one skilled in the art at the time of invention). Moreover, the Appellants' showing is not commensurate in scope with the claims, which encompass substantially more oil-based inkjet inks than Examples 1 and 6 in Table 2. See In re Tiffin, 448 F.2d 791, 792 (CCPA 1971) ("objective evidence of non-obviousness must be commensurate in scope with the claims which the evidence is offered to support"). On balance, a preponderance of the evidence weighs in favor of a conclusion of obviousness. 7 Appeal2018-000738 Application 13/503,476 C. DECISION The Examiner's decision to reject claims 1 and 2 under 35 U.S.C. § 103(a) as obvious over JP 064 is reversed. The Examiner's decision to reject claims 1 and 2 under 35 U.S.C. § 103(a) as obvious over Endo is reversed. The Examiner's decision to reject claims 1 and 2 under 35 U.S.C. § 103(a) as obvious over WO 633 is reversed. Claim 1 is rejected under 35 U.S.C. § I03(a) as unpatentable over JP 064 in view of Suzuki and the Appellants' "Description of the Related Art." Claims 1 and 2 are rejected under 35 U.S.C. § I03(a) as unpatentable over Endo in view of Suzuki and the Appellants' "Description of the Related Art." Claims 1 and 2 are rejected under 35 U.S.C. § I03(a) as unpatentable over WO 633 in view of Suzuki and the Appellants' "Description of the Related Art." This decision contains new grounds of rejection pursuant to 37 C.F.R. § 4I.50(b). That section provides that the Appellants, WITHIN TWO MONTHS FROM THE DATE OF THE DECISION, must exercise one of the following two options with respect to the new grounds of rejection to avoid termination of the appeal as to the rejected claims: ( 1) Reopen prosecution. Submit an appropriate amendment of the claims so rejected or new Evidence relating to the claims so rejected, or both, and have the matter reconsidered by the examiner, in which event the prosecution will be remanded to the examiner. ... (2) Request rehearing. Request that the proceeding be reheard under § 41.52 by the Board upon the same Record .... No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § 1.136(a)(l )(iv). REVERSED; 37 C.F.R. § 4I.50(b) 8 Copy with citationCopy as parenthetical citation