Ex Parte Benjamin et alDownload PDFPatent Trial and Appeal BoardSep 18, 201412436443 (P.T.A.B. Sep. 18, 2014) Copy Citation UNITED STATES PATENT AND TRADEMARK OFFICE ____________________ BEFORE THE PATENT TRIAL AND APPEAL BOARD ____________ Ex parte NEIL BENJAMIN and ROBERT STEGER ____________ Appeal 2012-000774 Application 12/436,443 Technology Center 3700 ____________ Before JAMES T. MOORE, CHARLES N. GREENHUT, and JILL D. HILL, Administrative Patent Judges. MOORE, Administrative Patent Judge. DECISION ON APPEAL The Appellants1 have appealed from the final rejection of claims 24– 37 and 40–47 under 35 U.S.C. §6(b). We have jurisdiction pursuant to 35 U.S.C. § 134. For the reasons stated hereinafter, we affirm-in-part the rejections of record. BACKGROUND The present invention relates to a chuck which holds a semiconductor wafer for processing in a plasma processor. Plasma processing generates 1 The real party in interest is Lam Research Corporation. Br. 1. App App heat, whic a fla below therm contr therm indep zone per s 38 an in th appe eal 2012-0 lication 12 which ma h may lea The chu t support, a the desir al insulat olled base al insulat A heater endently s which ca econd. Id Figu Claims 2 d 39 have e final offi al. Claim 00774 /436,443 y cause th d to defect ck include nd a heate ed temper or is dispo . The flat or. Spec. is associa controlled n change . Figure 5 re 5 is a cr 4–37 and been canc ce action a 1 is repres ermal grad s in the wa s a temper r. The tem ature of a sed over a support ho 7. ted with th heating el temperatur , reproduc oss-sectio 40–47 are eled. Cla nd their re entative a 2 ients in th fer. Spec ature-cont perature- work piec t least a po lds a wor e flat supp ements tha e at a rate ed below, nal view o pending in ims 24–37 jection is nd reprodu e wafer be . 3–4. rolled base controlled e being pro rtion of th k piece an ort and in t heat cor of at least is illustrat f an exemp the appli and 40–4 the subjec ced below ing proce , a therma base is ch cessed, an e tempera d is dispos cludes a p responding one degre ive. lary chuc cation. Cl 7 have bee t of the pr : ssed, l insulator illed d a ture- ed over th lurality of heating e Celsius k aims 1–23 n rejected esent , e , Appeal 2012-000774 Application 12/436,443 3 24. A method for controlling the spatial temperature across a semiconductor wafer during a multistep plasma etching process wherein wafer temperature is changed for the particular layer being etched comprising: maintaining a base at a constant temperature, said constant temperature being below the temperature of the substrate, said base having a layer of thermal insulation material mounted on top of said base; electrostatically clamping the substrate against a top face of a flat support having a plurality of spatial regions, said flat support mounted on top of said layer of thermal insulation material; plasma etching a layer on the wafer under conditions such that local concentration of reactants varies across the wafer; independently heating each spatial region of said flat support with a plurality of heaters mounted to an underside of said flat support so as to induce a radial temperature gradient which compensates for the local reactant concentration; and changing the temperature of at least one spatial region of said flat support during the multistep etching process at a rate of at least 1 °C per second. THE REJECTIONS Claims 24–37, 40–43, 46 and 47 stand rejected under 35 U.S.C. § 103(a) as being unpatentable over Arami.2 Claims 44 and 45 stand rejected under 35 U.S.C. § 103(a) as being unpatentable over Arami in view of Kuibira.3 2 U.S. 5,591,269, issued January 7, 1997. 3 U.S. 6,365,879 B1, issued April 2, 2002. Appeal 2012-000774 Application 12/436,443 4 DISCUSSION I. The Rejection of Claims 24–37, 40–43, 46 and 47 under 35 U.S.C. § 103(a) as being unpatentable over Arami The Examiner has found that Arami describes plasma etching of a semiconductor wafer. Ans. 4. More specifically, the Examiner has made a finding that Arami describes controlling of the temperature across the wafer by changing the temperature with a base for maintaining a temperature below the temperature of the wafer. The Examiner has found that the base of Arami includes cooling water and a thermal layer mounted on the top of the base providing a thermal impedance break. Id. The Examiner also found that Arami describes flat supports including electrodes to electrostatically clamp or chuck the wafer on the flat support. Id. The Examiner also has found that Arami describes a plurality of independent heaters in specific spatial regions inducing a radial temperature gradient by changing the temperatures in their respective heating spatial regions. Ans. 4–5. The Examiner finds that Arami describes that the heater elements are provided on the underside of the flat support, or alternatively embedded within the flat support. Ans. 5. The Examiner admits that Arami does not explicitly describe an etching process with a spatial region having a temperature change rate of at least 1° Celsius per second. Id. The Examiner finds that Arami describes a controller which controls the heaters to set desired temperatures when temperature sensors in the respective regions sense and input signals to the controller to effect temperature changes. By turning the heaters on and off, the flat support is Appeal 2012-000774 Application 12/436,443 5 independently heated in respective regions to desired temperatures to control the heat transfer medium. Id. As such, the Examiner concludes that it would have been obvious to one of ordinary skill in the art at the time the invention was made to adapt the controller of Arami to provide the etching process at the recited temperature change rate (or any other rate to provide the desired etching or heating process). The Examiner finds that this would have been a matter of a routine experimentation and lacks criticality. Id. The Examiner also concludes that it would have been obvious to one of ordinary skill at the time the invention was made to utilize the process for a subsequent etching process of multistep etching process to perform etching applications as desired by a user as a matter of a routine application. Id. With respect to the heat flux impinging on the wafer, the Examiner finds that heat flux would necessarily be present in the process of Arami, as in normal and usual operation plasma is generated. Ans. 5–6. Finally, the Examiner finds that the base of Arami is maintained at the recited range below the temperature of the substrate, as Arami describes a controller which controls the base by supplying cooling water to provide a cooling temperature that further maintains a desired temperature to the substrate. Ans. 6. The Examiner concludes that it would have been obvious to one of ordinary skill in the art at the time the invention was made to adapt the cooling temperature within the recited range (or any other suitable range that would further enhance the rate of cooling of the heated substrate to maintain the desired heating temperature). Id. Figure 18 of Arami is reproduced below: App App eal 2012-0 lication 12 Figure In challe A reversed features fails to a Further, Examina A across a undesira paragrap plasma e 00774 /436,443 18 is a com th nge, the A s explaine because: recited in ddress the the Exami tion Guid s noted ab wafer und ble varian h [0031]). tching and bined cro e plasma ppellants d below, th (1) Arami independe problem s ner fails to elines. ove, local er certain ce of the la Arami fa thus cann 6 ss-sectiona etching de urge that: e obvious fails to sug nt Claims olved by t articulate concentrat etching co teral etch ils to discl ot sugges l and sche vice of Ar ness reject gest all o 24 and 31 he claimed findings r ion of reac nditions, a rate (spec ose any as t the claim matic view ami ion should f the claim and (2) A invention equired by tants can nd can lea ification at pects of ed step of of be rami . the vary d to Appeal 2012-000774 Application 12/436,443 7 plasma etching a layer on a wafer under conditions such that local concentration of reactants varies across the wafer (Claim 24). Applicants discovered that the local concentration of reactants can be compensated for by altering the wafer support zone temperatures to induce a radial temperature gradient (specification at paragraph [0031]. Arami seeks to achieve uniform temperature and thus cannot suggest the claimed step of independently heating each spatial region so as to induce a radial temperature gradient which compensates for local concentration of reactants varies across the wafer (Claims 24 and 31). App. Br. 12. These arguments are unpersuasive of error. We note that the very outset of the Arami specification states that the Arami process “relates to a vacuum processing apparatus for performing a process such as film formation, etching, or the like with respect to a target object in a vacuum.†Arami 1:6–9. While it is true that Arami does not describe plasma etching in great detail, a patent specification need not describe in detail that which is already well known to those of ordinary skill in the art. We do not find error with the Examiner applying the Arami apparatus to a plasma etching process generally. As regards the argument that Arami seeks uniform temperature, we find that the Appellants are reading the disclosure of Arami far too narrowly. Arami teaches precise control of spatial regions utilizing both cooling and heating with multiple heaters to customize a “plurality of desired regions on the surface of the mounting table that can be independently heated and insulated at desired temperatures.†Arami 16:65–67, see also 16:38–65. Appeal 2012-000774 Application 12/436,443 8 Moreover, the Examiner has correctly pointed out another instance of thermal gradient based upon a concentration boundary layer of gas. Arami 17:11–22 and 23–30. Finally, as acknowledged by the Appellants, Arami specifically sets up a gradient on a wafer to be treated. Id. at 18:3–12 (500, 450, and 400 degrees Celsius). The Appellants are correct that that specifically cited embodiment does not use plasma, but we read the specification as instructing one of ordinary skill in the art that etching is a viable use of the apparatus as well. The Appellants raise the argument that identification of the problem being solved must be taken into account. They assert that the problem— local concentration of reactants—can be compensated for by the solution— altering the wafer support zone temperatures to induce a radial temperature gradient. App. Br. 12. We do agree that sometimes identification of the problem to be solved can provide the basis of a patentable invention. However, the Arami reference in this instance recognizes the problems of thermal control in wafer processing, and effectively solves them. Arami uses a gradient for differing gas concentrations, a similar concept. Arami also suggests etching as a use for their apparatus. In this instance, we find the balance of evidence favors the Examiner’s conclusion that the claimed subject matter is unpatentable. Claims 30 and 37 are argued separately by the Appellants. Each requires changing temperature in one or more of the spatial regions by less than 10oC. Appeal 2012-000774 Application 12/436,443 9 The Final Rejection notes that it: would have been obvious to one of ordinary skill in the art to adapt the controller of Arami that can also provide the etching process at the recited rate or any other rates to adequately and sufficiently provide the desired etching or heating process as a matter of a routine experimentation and lacking criticality. Fin. Rej. 3 (emphasis added). The Appellants argue that the Final Rejection fails to address claims 30 and 37, and the Arami reference only discusses 50 degree intervals. As a consequence, they urge reversal is warranted. App. Br. 15. We disagree. While the Final Rejection did not discuss claims separately, the Examiner did conclude that any other rates would have been an obvious adaptation of the controller. Appellants have placed no persuasive argument or evidence in the record as to why the Examiner’s conclusion is in error. Claims 40 and 41 are argued separately by the Appellants as well. The claims each recite that heat flux impinging on the wafer from the plasma is “less than 2 W/cm2.†The Examiner made a finding that [w]ith respect to the heat flux impinging on the wafer, it is noted that such heat flux would also necessarily be performed in Arami as the Arami device is substantially [the] same as that of the applicant's described device in the specification and is carried out in the normal and usual operation as plasma is generated. Also see 2112.02. Fin. Rej. 3. According to the Appellants, Arami does not disclose processing a wafer wherein heat flux from the plasma is less than 2 W/cm2. It is urged Appeal 2012-000774 Application 12/436,443 10 that Arami is directed at heating a wafer to at least 400°C to perform CVD in a non-plasma environment. On the record before us, we are constrained to reverse this rejection for lack of evidence. The Examiner seems to be indicating that Arami’s apparatus, when used in a plasma etch, would inherently have this limitation of less than 2 W/cm2, but only because it is the same as the Appellants’ apparatus. However, we can not find in the record that this limitation was either admitted to be known in the art (e.g. in the Appellants’ Specification) or within the normal flux impingement from plasma (established by a reference or other evidence). We have only an assumption it would be the same as the Appellants’ method, without sufficient evidence to support that assumption. As a consequence, no prima facie case of unpatentability exists. Accordingly, the rejection of claims 40 and 41 is reversed. Claims 46 and 47 are also argued separately. Each recites that the base is maintained at a temperature that is 10 to 50°C below the wafer temperature. The Final Rejection has this to say about the base temperature: With respect to the base that is maintained at the recited range below the temperature of the substrate, Arami teaches that a controller (119) which controls the base which supplies a cooling water to provide a cooling temperature that further maintains a desired temperature to the substrate, and it would have been obvious to one of ordinary skill in the art to adapt the cooling temperature within the recited range or any other suitable range that would further enhance the rate of cooling effects to the heated substrate to maintain the desired heating temperature. Fin. Rej. 4 (emphasis added). Appeal 2012-000774 Application 12/436,443 11 The Appellants urge that Arami heats the wafer to a temperature of 800°C (column 10, line 34) or at least 400°C (column 18, lines 3–12), thus teaching away from the method recited in claims 46 and 47. Additionally, they urge that the Final Rejection fails to specifically address claims 46 and 47. We again must disagree. While the Final Rejection did not discuss claims separately, the Examiner did make a finding that any other cooling temperature would have been an obvious adaptation of the controller of Arami. Appellants have placed no persuasive argument or evidence in the record as to why the Examiner’s conclusion is in error. II. The Rejection of Claims 44 and 45 under 35 U.S.C. § 103(a) as being unpatentable over Arami and Kuibira Claims 44 and 45 stand rejected under 35 U.S.C. § 103(a) as being unpatentable over Arami and Kuibira. The Examiner has found that Arami shows the method claimed except for the layer of thermal insulation having a thermal conductivity of .05 to .20 W. The Examiner relies upon the description in Kuibira to show a heater having a thermal insulator having a thermal conductivity of 10W/mk or less. The Examiner then concludes that it would have been obvious to one of ordinary skill in the art at the time the invention was made to provide Arami with a thermal insulator having the claimed thermal conductivity to improve the thermal insulation while preventing undesired heat loss. Fin. Rej. 4. The Appellants urge that Kuibira describes a wafer holder having a layer of ceramic [4] bonded to an ESC electrode 3, plasma generating electrode 2 and heater 1 such that the ceramic layer below the heater Appeal 2012-000774 Application 12/436,443 12 prevents “heat from escaping toward the portion under the heater (backside) and thus efficiently heat a wafer located on the wafer holding surface†App. Br. 16 (citing Kuibira 2:29–39, 48–56; 9:11–14). The Appellants urge that Kuibira’s wafer holder does not include a base maintained at a constant temperature, but instead seeks to prevent heat flow below the heater so that the wafer can be rapidly heated to temperatures of 700°C. Id. (citing Kuibira 3:4; 7:51–52; 8:18–19,41–42; 9:1–2). The Appellants conclude that that the addition of the heat insulator of Kuibira to Arami would prevent heat flow and thus lead away from the claimed “thermal impedance break†between the base and the flat support as recited in claims 43 and 44. The Examiner disagrees, finding that Kuibira shows substantially the same structure—having a thermal insulation between the base and the flat support (citing Kuibira Figures 1 and 2). Ans. 8. It appears to us that the evidence supports the Examiner’s position. The insulation layer in Figures 1 and 2 of Kuibira would have the same function in both Kuibira’s heater as well as the instantly claimed process. The Appellants have not provided persuasive evidence otherwise. Accordingly, we affirm this rejection. Appeal 2012-000774 Application 12/436,443 13 CONCLUSION Accordingly, we are persuaded of error on the Examiner’s part as regards claims 40 and 41. However, we are unpersuaded on all other grounds, and conclude that a preponderance of evidence in the record supports the rejections. DECISION The rejection of claims 24–37, 42, 43, 46 and 47 under 35 U.S.C. § 103(a) as being unpatentable over Arami is affirmed. The rejection of claims 40 and 41under 35 U.S.C. § 103(a) as being unpatentable over Arami is reversed. The rejection of claims 44 and 45 under 35 U.S.C. § 103(a) as being unpatentable over Arami in view of Kuibira is affirmed. AFFIRMED-IN-PART mls Copy with citationCopy as parenthetical citation