Ex Parte Pearson et alDownload PDFPatent Trial and Appeal BoardAug 14, 201713356004 (P.T.A.B. Aug. 14, 2017) Copy Citation United States Patent and Trademark Office UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O.Box 1450 Alexandria, Virginia 22313-1450 www.uspto.gov APPLICATION NO. FILING DATE FIRST NAMED INVENTOR ATTORNEY DOCKET NO. CONFIRMATION NO. 13/356,004 01/23/2012 Trevor Pearson 2156-685A 5620 34238 7590 08/16/2017 ARTHUR G. SCHAIER CARMODY TORRANCE SANDAK & HENNESSEY LLP 195 CHURCH STREET P.O. BOX 1950 NEW HAVEN, CT 06509-1950 EXAMINER PHASGE, ARUN S ART UNIT PAPER NUMBER 1756 NOTIFICATION DATE DELIVERY MODE 08/16/2017 ELECTRONIC Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. Notice of the Office communication was sent electronically on above-indicated "Notification Date" to the following e-mail address(es): patents @ carmodylaw.com PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE BEFORE THE PATENT TRIAL AND APPEAL BOARD Ex parte TREVOR PEARSON and CRAIG ROBINSON Appeal 2016-001723 Application 13/356,004 Technology Center 1700 Before KAREN M. HASTINGS, JENNIFER R. GUPTA, JANE E. INGLESE, Administrative Patent Judges. GUPTA, Administrative Patent Judge. DECISION ON APPEAL1 Appellants2 appeal under 35 U.S.C. § 134(a) from the Examiner’s decision rejecting, for at least the second time, claims 1—22.3 We have jurisdiction under 35 U.S.C. § 6(b). We affirm-in-part. 1 In this decision, we refer to the Specification filed January 23, 2012, the Non-Final Office Action mailed January 28, 2015 (“Non-Final Act.”), the Appeal Brief filed March 5, 2015 (“Appeal Br.”), the Examiner’s Answer mailed October 7, 2015 (“Ans.”), and the Reply Brief filed November 24, 2015 (“Reply Br.”). 2 Appellants identify the real party in interest as MacDermid Acumen, Inc. Appeal Br. 2. 3 We heard oral arguments from the Appellants’ representative on August 3, 2017. Appeal 2016-001723 Application 13/356,004 The subject matter on appeal relates to an etchant for plastic substrates, and methods of preparing a solution capable of etching a plastic substrate. Spec. 6,1. 18—7,1. 7. Claims 1 and 17, reproduced below from the Appendix of the Appeal Brief, are illustrative of the claims on appeal. 1. A method of preparing a solution capable of etching a platable plastic, the method comprising the steps of: providing an electrolyte comprising manganese(II) ions in a solution of about 9 to 15 molar sulfuric acid or phosphoric acid to an electrolytic cell; applying a current to the electrolytic cell, wherein the electrolytic cell comprises an anode and a cathode; and oxidizing the electrolyte to form manganese(III) ions, wherein the manganese(III) ions form a metastable sulfate or phosphate complex. 17. An electrolyte capable of etching a platable plastic, the electrolyte comprising manganese(III) ions in a solution of 9 to 15 molar sulfuric acid or phosphoric acid. Appeal Br. 14, 15. REJECTIONS The Examiner maintains the following rejections on appeal: Rejection 1: Claims 1—6 and 11—16 stand rejected under pre-AIA 35 U.S.C. § 103(a) as unpatentable over Schildmann, WO 2009/023628 A2, published February 19, 2009) (“Schildmann”); Rejection 2: Claims 9 and 10 stand rejected under pre-AIA 35 U.S.C. § 103(a) as unpatentable over Schildmann in view of Bourne (US 3,941,677, issued March 2, 1976) (“Bourne”); 2 Appeal 2016-001723 Application 13/356,004 Rejection 3: Claims 7 and 8 stand rejected under pre-AIA 35 U.S.C. § 103(a) as unpatentable over Schildmann in view Komatsu et al. (US 4,530,745, issued July 23, 1985) (“Komatsu”); and Rejection 4: Claims 17—22 stand rejected under pre-AIA 35 U.S.C. § 102(b) as anticipated by or, in the alternative, under pre-AIA 35 U.S.C. § 103(a) as obvious over Schildmann. DISCUSSION Rejections 1—3 Appellants argue for patentability of claims 1, 2-4, 6, 12, 14, and 16, subject to the first ground of rejection, as a group. Appeal Br. 5—11. Appellants do not present separate substantive arguments for the patentability of separately rejected claims 7—10, which depend from claim 1. Id. at 11. We choose independent claim 1 as representative of this group, and claims 2—4, 6—10, 12, 14, and 16, stand or fall with claim 1. See 37 C.F.R. § 41.37 (c)(l)(iv). Appellants present additional arguments for patentability of dependent claims 5, 11, 13, and 15. Id. at 5—11. We address these arguments below under separate subheadings. Claims 1—4, 6—10, 12, 14, and 16 The Examiner finds that Schildmann discloses or suggests providing an electrolyte comprising manganese (II) ions in a sulfuric acid solution having a concentration within the range recited in claim 1 to an electrolytic cell, applying a current to the cell, oxidizing the electrolyte to inherently form manganese (III) ions, and forming a metastable sulfate complex. Non- Final Act. 3 (citing Schildmann || 19-23, 25, 26, 29, 37). 3 Appeal 2016-001723 Application 13/356,004 Appellants argue that “Schildmann simply discloses huge ranges of potential current densities, such as 0.1 to 100 A/dm2,” and “[o]ne needs to assume the use of certain current densities where (i) the creation of Mn(III) metastable complexes was not the objective of Schilmann, and (ii) Schildmann gives no guidance as to what current densities to use to form such a complex.” Appeal Br. 5, 6. Appellants also argue that “a person of ordinary skill in the art at the time of the invention would not have recognized that a metastable Mn(III) complex would be formed using Schildmann’s methods.” Id. at 6. Appellants’ arguments are not persuasive of reversible error. The rejection of claim 1 is for obviousness, not anticipation. The test for obviousness is what the prior art would have suggested to one of ordinary skill in the art. In re Young, 927 F.2d 588, 591 (Fed. Cir. 1991). Here, the disclosure of Schildmann would have indicated to one of ordinary skill in the art that any current density within the ranges disclosed in the reference, including a current density of 0.1 to 0.4 A/dm2, is suitable for use in Schildmann’s oxidation cell. Schildmann 123. Appellants have not presented sufficient arguments or evidence that, if, for example, manganese sulfate MnS04 was used as the manganese salt in a solution of 9 to 15 molar sulfuric acid in Schildmann’s oxidation cell (Schildmann 119), and a current density of 0.1 to 0.4 A/dm2 was applied to the cell, the manganese (II) ions would not be converted to manganese (III) ions (Spec. 10,11. 23—24). In addition, it is not necessary that the prior art recognize that a metastable sulfate complex is formed using Schildmann’s methods. Cf. Schering Corp. v. Geneva Pharms., 339 F.3d 1373, 1377 (Fed.Cir.2003) (rejecting the contention that inherent anticipation requires recognition in the 4 Appeal 2016-001723 Application 13/356,004 prior art).4 Rather, the Examiner must provide a basis in fact and/or technical reasoning to reasonably support the determination that the allegedly inherent characteristic necessarily flows from the teachings of the applied prior art. Ex parte Levy, 17 USPQ2d 1461, 1464 (BPA1 1990). On this record, the Examiner establishes a reasonable basis for inherency and thereby evinces that Appellants’ and Schildmann’s method appear to be the same. Final Act. 3. Thus, the burden is properly shifted to Appellants to show that they are not. In re Best, 562 F.2d 1252, 1255 (CCPA 1977). Appellants have failed to show by a preponderance of the evidence that Schildmann’s method does not necessarily form Mn (111) ions, for example, by oxidizing Mn (11) in a solution of 9 to 15 molar sulfuric acid (Schildmann Tflf16, 19, 20), where the manganese (III) ions necessarily form a metastable sulfate complex in the strong sulfuric acid solution, as recited in claim 1. Appellants argue that Schildmann teaches away from the formation of manganese (III) ions because Schildmann teaches that Mn (III) compounds are insoluble and, if formed, must be destroyed. Appeal Br. 8 (citing Schildmann 132—34). Appellants’ argument is not persuasive of reversible error. Appellants have not directed us to any disclosure in Schildmann that teaches away from forming manganese (III) ions. Schildmann’s teaching that manganese (II) in phosphoric acid forms non-soluble Mn (III) phosphate compounds (see Schildmann || 32—34) does not teach away from forming manganese ions 4 Appellants’ discussion of “accidental anticipation” (Appeal Br. 6 (citing Eibel Process Co. v. Minnesota & Ontario Paper Co., 261 U.S. 45, 66 (1923), In re Marshall, 578 F.2d 301, 304 (CCPA 1978), and In re Felton, 484 F.2d 495, 499—500 (CCPA 1973)) is not pertinent because Schildmann was applied against claim 1 in an obviousness, not an anticipation, rejection. 5 Appeal 2016-001723 Application 13/356,004 generally. Further, Schildmann does not teach that those non-soluble compounds should be avoided. Rather, Schildmann teaches that if formed, the non-soluble compounds can be removed by the addition of a reducing agent or by boiling. Schildmann 134. Schlidmann also teaches that the formation of those unsoluble manganese (III) compounds are avoided when sulfuric acid is used. Schildmann 129. Appellants, however, have not directed us to any disclosure in Schildmann that discourages forming manganese (III) ions in sulfuric or phosphoric acid. Appellants argue that claim 1 is not obvious because the formation of a metastable manganese (III) complex is an unexpected result, which Appellants contend is supported by Appellants’ application and the Declaration under 37 C.F.R. § 1.132 executed by Steven Castaldi (“the Castaldi Declaration”). Appeal Br. 8. Appellants’ argument is not persuasive of reversible error in the rejection because the Castaldi Declaration simply argues against the Schildmann reference and what it discloses without providing sufficient evidence that the metastable sulfate or phosphate complex is unexpectedly formed. In sum, Appellants have not identified a reversible error in the Examiner’s obviousness rejection of claim 1 over Schildmann. Thus, we sustain the Examiner’s obviousness rejection of independent claim 1, and claims 2-4, 6—10, 12, 14, and 16, which depend directly or indirectly therefrom. 6 Appeal 2016-001723 Application 13/356,004 Claim 5 Claim 5 depends from claim 1 and requires that the solution capable of etching platable plastic “additionally comprises colloidal manganese dioxide.” Appellants’ argue that in the Non-Final Office Action mailed January 28, 2015 (the action appealed from), the Examiner fails to perform any analysis on claim 5 or purports to show where in Schildmann colloidal manganese dioxide is disclosed or suggested. Appeal Br 9. The Examiner responds in the Answer that Appellants’ Specification teaches that colloidal manganese dioxide “[forms] to some extent as a natural result of disproportionation of manganese (III) in solution.” Ans. 10 (citing Spec. 10,11. 16—17). The Examiner’s obviousness rejection of claim 5 over Schildmann appears to rely on inherency. “To establish inherency, the extrinsic evidence ‘must make clear that the missing descriptive matter is necessarily present in the thing described in the reference.’” In re Robertson, 169 F.3d 743, 745 (Fed. Cir. 1999) (quoting Cont’l Can Co. v. Monsanto Co., 948 F.2d 1264, 1268 (Fed.Cir.1991). “Inherency, however, may not be established by probabilities or possibilities. The mere fact that a certain thing may result from a given set of circumstances is not sufficient.” In re Oelrich, 666 F.2d 578, 581 (CCPA 1981) (quoting Hansgirg v. Kemmer, 102 F.2d 212, 214 (CCPA 1939). Appellants’ Specification teaches that colloidal manganese dioxide “may form” to some extent as a natural result of disproportionation of manganese (III) in solution.” Spec. 10,11. 16—17. Based on the disclosure in Appellants’ Specification, we cannot say that Schildmann necessarily or inherently teaches that its pickling solution includes colloidal 7 Appeal 2016-001723 Application 13/356,004 manganese dioxide. Accordingly, we cannot sustain the Examiner’s obviousness rejection of claim 5 over Schildmann. Claim 11 Claim 11 depends from claim 1 and requires that the current density of the anode in the electrolytic cell “is between about 0.1 to about 0.4 A/dm2.” Appellants’ admit that Schildmann discloses a very broad range of anode current density of 0.1 to 100 A/dm2. Schildmann 123. Appellants, however, argue the disclosed range includes a broad range of possibilities, and thus, it would not have been obvious to one of ordinary skill in the art to utilize a low and narrow range of 0.1 to 0.4 A/dm2, as recited in claim 11. Appeal Br. 10; Reply Br. 5 (citing Atofina v. Great Lakes Chemical Corp., 441 F.3d991 (Fed. Cir. 2006).5 Although the range of current densities disclosed in Schildmann is broad, it encompasses the current density range recited in claim 11. It is well-established that a prima facie case of obviousness exists when the claimed and prior art ranges overlap. In re Peterson, 315 F.3d 1325, 1329 (Fed.Cir. 2003). Therefore, Appellants’ argument is not persuasive of reversible error in the Examiner’s rejection. Accordingly, we sustain the Examiner’s obviousness rejection of claim 11 over Schildmann. 5 Claim 11 is only rejected as obvious over Schildmann. Non-Final Act. 3. Thus, Appellants reliance on Atofina is misplaced because it involves an anticipation rather than an obviousness rejection. 8 Appeal 2016-001723 Application 13/356,004 Claim 13 Claim 13 depends from claim 1 and requires that “the electrolyte does not contain any permanganate.” Appellants argue that the entire purpose of Schildmann is to form permanganate for use in etching (citing Schildmann || 14, 32), and the Examiner has not provided sufficient evidence on the record that Schildmann teaches or suggests a pickling solution without permanganate. Appeal Br. 10. The Examiner responds in the Answer that “the electrolyte” recited in claim 13 refers only to the starting material, which is free from the claimed permanganate (i.e. before electrolysis), and contends that Schildmann teaches that the starting materials do not contain permanganate. Ans. 11. Appellants respond in their Reply Brief that the Examiner’s interpretation of claim 13 is erroneous, and the proper interpretation of claim 13 excludes permanganate in the electrolyte throughout the method, not just in the starting materials of the electrolyte. Reply Br. 7. Appellants’ argument is persuasive of reversible error. Claim 13 requires that “the electrolyte does not contain any permanganate.” Claim 13 does not distinguish between the electrolyte before and after electrolysis. Thus, we agree with Appellants that the broadest reasonable interpretation of claim 13 requires the electrolyte both before and after electrolysis to be free of permanganate (Reply Br. 7; Spec. 11,11. 13—14).6 The Examiner has not pointed to sufficient disclosure in Schildmann that the electrolyte both 6 Appellants’ Specification simply discloses that it is generally preferable that “the electrolyte” not contain any permanganate ions. Spec. 11,11. 13— 14. 9 Appeal 2016-001723 Application 13/356,004 before and after electrolysis is free of permanganate. In fact, because Schildmann’s objective is to prepare a pickling solution that contains permanganate (Schildmann 114), Schildmann teaches away from an electrolyte after electrolysis that is free of permanganate. Accordingly, we cannot sustain the Examiner’s obviousness rejection of claim 13 over Schildmann. Claim 15 Claim 15 depends from claim 1 and requires that “the platable plastic is immersed in the metastable sulfate complex for about 20 to about 30 minutes.” Appellants argue that Schildmann’s only disclosure of the amount of time for immersion is 10 minutes (Schildmann || 36—38), and Schildmann does not disclose any times within the claimed range. Appeal Br. 11. The Examiner responds in the Answer that a disclosure of time for immersion of “10 minutes can be read to be about 20 minutes.” Ans. 11. We cannot agree with the Examiner that Schildmann’s disclosure of immersing plastic in a pickling solution for 10 minutes can be read as encompassing immersing plastic in a pickling solution for about 20 minutes. Thus, on this record, we cannot sustain the Examiner’s obviousness rejection of claim 15 over Schildmann. Rejection 4 The Examiner rejected each of claims 17—22 as anticipated by or, in the alternative, obvious over Schildmann. Non-Final Act. 2. Appellants’ arguments focus on representative claim 17, and dependent claims 20 and 21. Appeal Br. 11—13. Appellants do not present 10 Appeal 2016-001723 Application 13/356,004 separate substantive arguments for the patentability of claims 18, 19, and 22, which depend from claim 17. Id. Thus, claims 18, 19, and 22 will stand or fall with claim 17. See 37 C.F.R. § 41.37 (c)(l)(iv). Claims 17—19, and 22 The Examiner finds that Schildmann discloses or suggests an electrolyte capable of etching a platable plastic as recited in claim 17 comprising manganese (III) ions in a solution of 9 to 15 molar sulfuric acid or phosphoric acid. Non-Final Act. 2 (citing Schildmann || 19, 29); see also In re Preda, 401 F. 2d 825, 826 (CCPA 1968) (In determining whether a reference anticipates the subject matter recited in a claim, “it is proper to take into account not only specific teachings of the reference but also the inferences which one skilled in the art would reasonably be expected to draw therefrom.”). Appellants do not dispute the Examiner’s factual findings with respect to Schildmann describing an electrolyte capable of etching a platable plastic with the exception that Appellants contend that the Examiner’s anticipation and obvious rejections of claim 17 should be reversed because Schildmann does not inherently disclose or render obvious Mn (III) ions in an electrolyte solution. Appeal Br. 11—13. Appellants’ argument is not persuasive of reversible error in the Examiner’s anticipation or obviousness rejection of claim 17. As discussed above with respect to claim 1, the Examiner must provide a basis in fact and/or technical reasoning to reasonably support the determination that the allegedly inherent characteristic necessarily flows from the teachings of the applied prior art. Ex parte Levy, 17 USPQ2d at 1464. On this record, the Examiner establishes a reasonable basis for inherency and thereby evinces 11 Appeal 2016-001723 Application 13/356,004 that Appellants’ and Schildmann’s electrolyte appear to be the same. Non- Final Act. 2. Thus, the burden is properly shifted to Appellants to show that they are not. In re Best, 562 F.2d at 1255. Appellants have failed to show by a preponderance of the evidence that Schildmann’s pickling solution does not necessarily form Mn (III) ions, for example, by oxidizing Mn (II) in a solution of 9 to 15 molar sulfuric acid (Schildmann || 16, 19, 20), as recited in claim 17. Accordingly, we sustain the Examiner’s anticipation and obviousness rejections of claims 17, 18, and 22. Claim 20 Claim 20 depends from claim 17 and requires that “the electrolyte additionally comprises colloidal manganese dioxide.” Appellants’ argue Schildmann nowhere discloses colloidal manganese dioxide, and in the Non-Final Office Action mailed January 28, 2015 (the action appealed from), the Examiner, by failing to perform any analysis, has failed to make out a prima facie case. See Appeal Br. 12. The Examiner responds in the Answer that Appellants’ Specification teaches that colloidal manganese dioxide “[forms] to some extent as a natural result of disproportionation of manganese (III) in solution.” Ans. 10 (citing Spec. 10,11. 16—17). As with claim 5 discussed above with regard to Rejection 1, the Examiner relies on inherency in rejecting claim 20 over Schildmann. Appellants’ Specification teaches that colloidal manganese dioxide “may form to some extent as a natural result of disproportionation of manganese (III) in solution.” Spec. 10,11. 16—17. As discussed above, based on the disclosure in Appellants’ Specification, we cannot say that Schildmann necessarily or inherently teaches that its pickling solution includes colloidal 12 Appeal 2016-001723 Application 13/356,004 manganese dioxide. In re Oelrich, 666 F.2d at 581 (inherency may not be established by probabilities or possibilities). Accordingly, we cannot sustain the Examiner’s anticipation or obviousness rejection of claim 20 over Schildmann. Claim 21 Claim 21 depends from claim 17 and requires that “the electrolyte does not contain any permanganate.” Appellants argue that the entire purpose of Schildmann is to form permanganate for use in etching, and the Examiner has not provided sufficient evidence on the record that Schildmann teaches or suggests a pickling solution without permanganate. Appeal Br. 12. The Examiner responds in the Answer that the electrolyte refers only to the starting material, which is free from the claimed permanganate (i.e. before electrolysis), and contends that Schildmann teaches that the starting materials do not contain permanganate. See Ans. 11. Appellants respond in their Reply Brief that the Examiner’s interpretation of claim 21 is erroneous, and it is clear from the plain language of claim 21, which depends from claim 17, that the solution of claim 21 refers to a solution after electrolysis, i.e., after the starting Mn (II) ions are oxidized to Mn (III) ions by electricity. Reply Br. 8. Appellants’ argument is persuasive of reversible error. Claim 21 depends from claim 17, which is directed to an electrolyte capable of etching a platable plastic where the electrolyte comprises manganese (III) ions in a solution of sulfuric acid or phosphoric acid. We agree with Appellants that because the electrolyte of claim 17 comprises manganese (III) ions in solution, the broadest reasonable interpretation of claim 21 requires the 13 Appeal 2016-001723 Application 13/356,004 electrolyte after electrolysis, i.e., after the starting manganese (II) ions are oxidized to manganese (III) ions by electricity, to be free of any permanganate (Reply Br. 8). The Examiner has not pointed to sufficient disclosure in Schildmann that the electrolyte after electrolysis is free of permanganate. In fact, because Schildmann’s objective is to prepare a pickling solution that contains permanganate (Schildmann 114), Schildmann teaches away from an electrolyte after electrolysis that is free of permanganate. Accordingly, we cannot sustain the Examiner’s anticipation or obviousness rejection of claim 21 over Schildmann. DECISION For the above reasons, the rejection of claims 1—6 and 11—16 under pre-AIA 35 U.S.C. § 103(a) over Schildmann is affirmed as to claims 1—4, 6, 11, 12, 14, and 16, and reversed as to claims 5, 13, and 15. The rejection of claims 9 and 10 under pre-AIA 35 U.S.C. § 103(a) over Schildmann in view of Bourne, and the rejection of claims 7 and 8 under pre-AIA 35 U.S.C. § 103(a) over Schildmann in view of Komatsu are affirmed. The rejection of claims 17—22 under pre-AIA 35 U.S.C. § 102(b) is affirmed as to claims 17, 18, and 22, and reversed as to claims 20 and 21. The rejection of claims 17—22 under pre-AIA 35 U.S.C. § 103(a) over Schildmann is affirmed as to claims 17—19, and 22 and reversed as to claims 20 and 21. No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § 1.136(a). AFFIRMED-IN-PART 14 Copy with citationCopy as parenthetical citation