Ex Parte DennenDownload PDFPatent Trial and Appeal BoardApr 27, 201613269814 (P.T.A.B. Apr. 27, 2016) Copy Citation UNITED STA TES p A TENT AND TRADEMARK OFFICE APPLICATION NO. FILING DATE 13/269,814 96051 7590 Uniloc USA Inc. Legacy Town Center 7160 Dallas Parkway Suite 380 Plano, TX 75024 10/10/2011 04/29/2016 FIRST NAMED INVENTOR Michael W. Dennen UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www .uspto.gov ATTORNEY DOCKET NO. CONFIRMATION NO. UN-NP-FT-117 9236 EXAMINER PIZARRO CRESPO, MARCOS D ART UNIT PAPER NUMBER 2814 NOTIFICATION DATE DELIVERY MODE 04/29/2016 ELECTRONIC Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. Notice of the Office communication was sent electronically on above-indicated "Notification Date" to the following e-mail address( es): sean. burdick@unilocusa.com tkiatkulpiboone@unilocusa.com kris.pangan@unilocusa.com PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE BEFORE THE PATENT TRIAL AND APPEAL BOARD Ex parte MICHAEL W. DENNEN Appeal2014-001590 Application 13/269,814 Technology Center 2800 Before ADRIENE LEPIANE HANLON, CATHERINE Q. TIMM, and JAMES C. HOUSEL, Administrative Patent Judges. TIMM, Administrative Patent Judge. DECISION ON APPEAL 1 STATEMENT OF CASE Appellant2 appeals the Examiner's decision to reject claims 1, 3-11, and 13-20 under 35 U.S.C. § 103(a). Claims 1, 3, 6, 9-11, 13, 14, and 17- 1 In our opinion below, we refer to the Specification filed October 10, 2011 (Spec.), Final Office Action mailed January 30, 2013 (Final), the Appeal Brief filed July 6, 2013 (Appeal Br.), and the Examiner's Answer mailed September 10, 2013 (Ans.). 2 Appellant identifies the real party in interest as Uniloc USA, Inc. and Uniloc Luxembourg S.A. Appeal Br. 3. Appeal2014-001590 Application 13/269,814 20 stand rejected as obvious over Colombo3 in view ofMilligan. 4 To reject claims 4, 5, 7, 8, 15, and 16, the Examiner adds Hillman. 5 We have jurisdiction under 35 U.S.C. §§ 6(b) and 134(a). We AFFIRM. The claims are directed to methods of fabricating a field effect transistor gate including a metal nitride layer (see, e.g., claims 1, 13, and 19) and devices so fabricated (see, e.g., claims 11 and 18). According to the Specification, this type of gate was known in the art, and prior work has been devoted to producing a metal nitride gate over Si02 or Partially Nitrided Oxide (PNO). Spec. 1-2. Appellant states that the structure proposed in the literature "does not appear to have been realized with high reliability, low trapped charge and/or low dielectric leakage." Spec. 3 i-f 1. Appellant's method includes one or two steps of annealing performed at specific points in the method of forming the gate, which Appellant states reduce or eliminate the prior difficulties. Id. Appellant's claims are directed to the method including the annealing steps (see, e.g., claim 1 (two annealing steps) and claim 13 (one annealing step), or a step of reducing interaction between the gate insulating layer and the metal nitride layer (see, e.g., claim 19). 6 Claim 1 is illustrative of the two-step annealing method: 1. A method of fabricating an integrated circuit field effect transistor gate, the method comprising: 3 US 7,091,119 B2, issued August 15, 2006. 4 US 7,713,874 B2, issued May 11, 2010. 5 US 5,975,912, issued November 2, 1999. 6 According to the Specification, both annealing steps reduce the interaction between the gate insulating layer (Si02 or PNO) and the metal nitride layer. Spec. 3--4. Thus, the reducing step encompasses either step of annealing. 2 Appeal2014-001590 Application 13/269,814 fabricating a gate insulating layer on an integrated circuit substrate; fabricating a metal nitride layer on the gate insulating layer; annealing the metal nitride layer in a first nitridizing ambient; fabricating a cap on the metal nitride layer that has been annealed in the nitridizing ambient; etching the cap and the metal nitride layer that has been annealed in the first nitridizing ambient to expose sidewalls thereof; and annealing a sidewall of the metal nitride layer in a second nitridizing ambient. Claims Appendix, Appeal Br. 18 (emphasis added). Appellant does not argue any claim apart from the others, nor the secondary rejection apart from the primary rejection. Appeal Br. 13-17. However, the issues raised are different for each independent claim. Thus, we consider the issues as they relate to the rejection of claims 1, 13, and 19. OPINION Claim 1 Claim 1 requires both annealing steps. The first annealing step involves annealing the metal nitride layer formed on the gate insulating layer in a first nitridizing ambient. The second annealing step occurs after an etching step that exposes a metal nitride sidewall. The second annealing step anneals the sidewall in a second nitridizing ambient. The nitridizing ambient may be, ammonia (NH3) or other nitiriding gases. Spec. 3--4. 3 Appeal2014-001590 Application 13/269,814 The Examiner finds that Colombo teaches a method of forming a transistor gate including a metal nitride layer (TiN) that includes a step of annealing a sidewall of the TiN layer in a nitridizing ambient (the second annealing step of claim 1 ), but acknowledges that Colombo does not teach annealing the TiN in a first nitridizing ambient (the first annealing step of claim 1). Final 2-3. However, the Examiner concludes that including the first annealing step would have been obvious to the ordinary artisan based upon the teachings of Milligan. Final 3. Appellant contends that Colombo teaches against annealing because Colombo seeks to overcome a poly-silicon depletion problem by encapsulating the transistor gate with silicon nitride, which Appellant alleges promotes interaction between the poly-silicon layer and encapsulating nitride layer; an effect opposite from Appellant's annealing step. Appeal Br. 13-15. Appellant further contends that annealing Colombo's gate structure according to Milligan would render Colombo's structure unsuited for its intended purpose for a similar reason: Annealing would prevent interaction between the nitride sidewalls and the poly-silicon layer and cause poly- silicon depletion. Appeal Br. 16. For claim 1, Appellant's arguments are not persuasive for the reasons the Examiner provides in the Answer. Ans. 5-6. As found by the Examiner, Colombo discloses forming a TiN layer 312 by a deposition process 314, but Colombo does not provide any details of the deposition process. Ans. 5-6; Colombo, col. 6, 11. 57-62; Colombo, Fig. 5B. Milligan teaches a method of depositing a metal nitride layer by atomic layer deposition (ALD). Milligan, col. 1, 11. 7-10; col. 9, 1. 20-col. 13, 1. 8. Because Colombo does not provide the details of metal nitride deposition and Milligan discloses a suitable 4 Appeal2014-001590 Application 13/269,814 method, the evidence supports the Examiner's finding of a reason to use Milligan's deposition method. Milligan's ALD method includes a plasma annealing process in a nitridizing ambient. Milligan, col. 1, 11. 7-1 O; see also, e.g. col. 10, 11. 16- 17. One of the benefits of the plasma annealing process, according to Milligan, is to enable a controlled and conformal deposition of the metal nitride film. Milligan, col. 4, 11. 9-12. Thus, the evidence supports the Examiner's reason for combining the film deposition teachings of Milligan with the method of forming a gate having a TiN layer as taught by Colombo. Moreover, we find no disclosure in Colombo or other evidence of record supporting Appellant's argument that annealing would eliminate a desired interaction between the poly-silicon layer and metal nitride layer of Colombo's gate. In fact, Colombo's silicon nitride encapsulation layer 120 and nitride materials 126 (see Colombo, Fig. 3) serve to condition or repair the sidewalls that are damaged during etching (e.g., the encapsulation layers renitride the metal nitride layer damaged by etching), and protects against oxidation of the sidewall metal. Colombo, col. 5, 11. 28-38. Like Appellant, Colombo seeks to protect the metal nitride layer from loss of nitride and from oxidation. Compare Colombo, col. 5, 11. 28-3 8 with Spec. 3--4. Moreover, the Examiner has provided an unrebutted reason for making the combination ("to enable controlled and conformal deposition of the TiN thin films") that is supported by the evidence of record (Milligan, col. 4, 11. 8- 41 ). Final3. Claim 13 Claim 13 does not require the first annealing step recited in claim 1; it only includes the second annealing step, i.e., annealing the sidewall. The 5 Appeal2014-001590 Application 13/269,814 Examiner finds that Colombo teaches the sidewall annealing step (second annealing step). Ans. 5. Thus, Appellant's arguments do not identify a reversible error in the Examiner's rejection of claim 13. Claim 19 Claim 19 contains no explicit annealing steps, but recites "reducing interaction between the gate insulating layer and the metal nitride layer." Appellant's Specification discloses that annealing the sidewall reduces the claimed interaction. Spec. 3--4. Because Appellant has not identified a reversible error in the Examiner's finding that Colombo discloses annealing the sidewall, Appellant has not identified a reversible error in the Examiner's rejection of claim 19. CONCLUSION We sustain the Examiner's rejections. DECISION The Examiner's decision is affirmed. TIME PERIOD FOR RESPONSE No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § 1.136(a)(l ). AFFIRMED 6 Copy with citationCopy as parenthetical citation